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A novel method for preparing platinized counter electrode of nanocrystalline dye-sensitized solar cells 总被引:1,自引:0,他引:1
CHENJinmao MAYutao WANGGuiqiang WANGZhengping ZHOUXiaowen LINYuan LIXueping XIAOXurui 《科学通报(英文版)》2005,50(1):11-14
The platinized FTO glass counter electrode was prepared by employing techniques of colloid preparation, Langmuir-Blodgett film and serf-assembly. The present electrode had very low platinum loading, high catalytic activity for iodine/triiodide reduction reaction. Compared with the conventional counter electrodes used in nanocrystalline dye-sensitized solar cells, the present electrode had provided a much higher catalytic performance which was attributed to the structure of platinum nanoclusters distributed homogeneously on the electrode. 相似文献
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《自然科学进展(英文版)》2020,30(4):477-484
The heating process for CuAlNi nanoclusters with cuboctahedral structure was studied by molecular dynamics simulation with the embedded atom method. A diffusionless martensitic transformation from the cuboctahedral (CO) to the icosahedral (ICO) structure before the melting point was found in some CuAlNi nanoclusters. The effects of element composition and cluster size on the thermodynamic stability and structural transformation of trimetallic nanoclusters were investigated. The results show that the CO–ICO transformation temperature was size-dependent and occurred only for small clusters. It was also observed that the CO–ICO transformation temperature firstly dropped and then raised as Al concentration increased, which may be strongly related to the release of excess energy. Furthermore, the surface segregation phenomenon was also observed that the lower surface energy components, such as Al and Cu atoms, segregated to the surface of CuAlNi nanoclusters. The changes in the melting points of CuAlNi nanoclusters with different alloy compositions and cluster sizes were also studied. And furthermore, the physical basis of structural transition of CuAlNi nanoclusters was discussed. 相似文献