SCDF法对VPO催化剂物性的影响

以两种不同方法制备ＶＰＯ催化剂,分别采用超临界流体干燥法（ＳＣＦＤ）,常规见干燥法干燥。使用ＢＥＴ,ＸＲＤ等测试手段,考察了催化剂在４００℃下焙烧后的粒子比表面积的大小和晶相组成。实验结果表明：采用超临界流体法比采用常规干燥法所制得催化剂的比表面积明显增加,且对催化剂的晶相组成也有一定的影响。     

多孔CaO孔隙结构的分形描述

利用Menger海绵构造了多孔CaO的孔隙结构,讨论了Menger海绵孔隙率和比表面积随分维数的变化规律,分析了模拟CaO孔隙结构时对确定Menger海绵的参数m,n和i的要求。     

LaCoO3与LaFeO3结构与CO催化氧化性能比较研究

采用柠檬酸－乙醇络合溶胶－凝胶法合成了两个单一相钙钛矿型稀土复合氧化物LaCoO3和LaFeO3并对其进行了结构,电阻率,比表面积,表面氧特性和CO氧化催化活性比较研究,结果表明,它们有几乎相近的大比表面积,但它们的晶系不同,LaCoO3属三方晶系,LaFeO3属正交晶系,LaCoO3比LaFeO3高的吸附氧量和导电性及CO低温催化氧化活性,初步解释了它们的结构与性能的关系。     

星体的p-极曲率映象与p-仿射表面积

引进了星体的p-极曲率映象的概念,建立了p-极曲率映象不等式,并给出了一些特殊几何体的p-极曲率映象与其极体的p仿射表面积乘积的界.作为p-极曲率映象的一个应用,同时研究了p-混合仿射表面积的p-Minkowski型不等式的推广.     

Carbonation of low heat portland cement paste precured in water for different time

The carbonation technique was applied to accelerate the hydration of low heat portland cement (LHC). Before carbonation, the demoulded pastes were precured in water for 0, 2, 7, and 21 d, respectively. The results show that precuring time in water strongly influences the carbonation process. The phenolphthalein test indicates that the paste precured in water for a shorter time is more quickly carbonated than that for a longer time. The content of calcium hydroxide increases with increasing the precuring time in water, whereas, the amount of absorbed carbon dioxide changes contrarily. Scanning electron microscope (SEM) observation shows that portlandite always fills up big air bubbles in the paste during precuring in water, and the mercury intrusion porosimetry (MIP) results show that there are less large capillary pores in the paste precured in water for a longer time. It is found that the paste without precuring in water has more carbon dioxide absorption during curing in carbon dioxide atmosphere, and its total pore volume decreases remarkably with an increase in the carbonation time than that precured in water. X-ray diffraction (XRD) and Brunauer-Emmett-Teller (BET) surface area analyses indicate that the carbonate products are vaterite and calcite; C_xSH_y formed from carbonation has low BET surface area in comparison with that of C-S-H formed from curing in water.     

碱炭比对活性炭孔结构及电容特性的影响

以酚醛树脂为原料、KOH为活化剂制备双电层电容器用高比表面积活性炭．考察KOH与酚醛树脂炭的质量比对所制得的活}生炭的吸附性能、孔径分布和比电容的影响．实验结果表明,随着碱炭比的增大,所得活性炭的BET比表面积、总孔容积和中孔容积不断增大,碘吸附值和亚甲基蓝吸附值也不断增大,比电容则先增大后减小并在碱炭比为4时达到最大值74．2F／g．以这种高比表面积活性炭组装成的电容器具有良好的充放电性能和循环性能,既能在大电流下快速充放电也能在小电流下缓慢充放电。     

基于BIM与MR的楼层疏散仿真

针对目前楼层疏散仿真仅将楼层平面图进行路线标注，相对单一且不直观的问题，提出融合混合现实(mixed reality, MR)与建筑信息模型(building information modeling, BIM)的三维建筑的疏散仿真方法。规划分割BIM各构件并进行标注，将BIM信息经过基于层次包围盒的表面积启发式优化算法进行路径规划，借助开发引擎Unity3D将疏散仿真流程导入Microsoft Hololens2硬件平台。实验结果表明，相较于以往仅通过建筑平面图表达的疏散仿真，通过引入MR设备作为多源感知来源，将疏散仿真扩展到可交互的现实三维空间，能够使疏散引导过程更直观，仿真引导效率更高，体验性更强。     

柔性、高导电的石墨烯三维网络结构体材料

石墨烯（graphene）是由单层碳原子紧密堆积而成的二维蜂窝状晶体结构,具有优异的电学、力学、热学和光学等特性。例如,石墨烯具有超高载流子迁移率、高强度、很好的柔韧性和近20%的伸展率、10倍于铜的超高热导率、高达2 600 m2/g的比表面积,并且几近透明,在很宽的波段内光吸收只有2.3%。     

沸石咪唑骨架N2吸附的分子模拟与BET分析

采用分子模拟的方法模拟77 K下N2在沸石咪唑骨架材料(ZIFs)上的吸附等温线,并与实验结果比较,确定合适的力场参数,提供用BET方法分析ZIFs材料比表面积的吸附等温线.通过BET吸附方程中的参数c与单层吸附压力(P/P0)m之间的关系为(p/p0)m=((√c)+1)-1,确定应用BET方程分析时的压力区间.采用这样的方法计算5种ZIF材料的比表面积并与根据一致性原则(Rouquerol,2007)的结果进行比较,结果表明方法是可靠的,这说明采用合适的压力区间时,BET方法同样适用于分析微孔ZIF材料的比表面积.计算得到的5种ZIF材料比表面积均在1 000 m2/g以上,说明ZIF材料是一种具有高比表面积、有应用前景的吸附材料.     

Preparation and luminescence properties of YeO3：Er^3＋/TiO2 with high specific surface area

The three composites Y2O3 :Er3+ , Y2O3 :Er3+ /Yb 3+ andY2O3 :Er3+ /TiO2 were prepared using coprecipitation and sol-gel techniques. Their morphology, specific surface area, porosity, UV-vis. absorption spectra and fluorescence spectra were measured using SEM, TEM, surface analysis, UV-vis. absorption and photoluminescence spectrophotometry. SEM and TEM showed that samples prepared using coprecipitation were dispersed, while Y2O3 :Er3+ /TiO2 particles possessed a mesoporous surface and average diameter of ab...