镁合金表面热喷涂WC-10Co-4Cr粒子沉积及分布特性

为了探究高速空气燃料热喷涂（AC-HVAF）过程中喷涂粒子撞击基材后的沉积特性。采用AC-HVAF热喷涂技术在AZ80镁合金基体上沉积WC-10Co-4Cr硬质涂层。通过离散沉积实验获得薄层沉积粒子,探讨各种沉积形貌的种类、形成原因、结合机制及射流中粒子的径向和轴向分布。结果表明：在AC-HVAF粒子沉积过程中,嵌入型沉积为主要的沉积形貌,同时包含少量的破碎型与空腔型沉积粒子。在涂层的形成过程中,嵌入型沉积对涂层/基体结合性能起重要作用;空腔型沉积的小颗粒及破碎型沉积的大颗粒是造成沉积效率下降的主要原因。喷涂粒子主要集中在射流中心,越靠近射流边缘,空腔型沉积粒子越多,最终导致AC-HVAF粒子射流呈现出空间分布特征。     

由单片机AT89C51构成的定时控制系统

介绍了单片机ＡＴ８９Ｃ５１,给出了由ＡＴ８９Ｃ５１构成的定时控制系统,并将此系统与ＣＰＵ８０３１构成的单片机系统比较,具有结构简单、可靠性高的特点．     

用B样条曲线构造几何物体模型的方法

根据Ｂ样条曲线原理,提出了先用若干个截平面去切割几何物体,得到一组与几何物体轮廓线相交的点。根据这些点,再用Ｂ样条曲线去构造几何物体的近似轮廓线,从而得到几何物体模型。该方法方便、精确,便于在计算机几何造型系统中应用。     

Cu~(2+)与三磺基四苯基啿卟啉配位反应研究

利用吸收光谱法和直流极谱法研究了Cu~(2+)的还原状态、抗坏态、抗坏血酸浓度及溶解氧对Cu~(2+)与三磺基四苯基卟啉配位反应的影响。结果表明Cu~(2+)与三磺基四苯(?)基四苯基卟啉配位反应的可能机制为抗坏血酸首先将高价铜还原为亚铜,亚铜离子与配位剂生成对氧成对氧敏感的不稳定中间体Cu~(Ⅰ)——三磺基四:苯基卟啉配合物,立即又被溶解氧氧化为Cu(Ⅱ)——Ⅱ)——三磺基四苯基卟啉配合物。     

海芋凝集素的理化性质鉴定

采用葡聚糖凝胶１００（ＳｅｐｈａｄｅｘＧ－１００）从天南星科植物海芋（Ａｌｏｃａｓｉａｏｄｏｒａ（Ｒｏｘｂ）Ｃ．Ｋｏｃｈ）中分离出了一种凝集素（简称ＡＯＬ）．ＡＯＬ对兔血有较强的凝集效果,而对各类型人血的凝集活力较弱,在３种糖蛋白中,猪甲状腺球蛋白对ＡＯＬ的凝血活力抑制最强;ＡＯＬ对培养人外周血白细胞的转化率高达７９％,超过对照ＰＨＡ的转化率;用ＳｅｐｈａｄｅｘＧ－２００柱测得ＡＯＬ的相对分子质量为３１５００;用癌细胞体外培养的方法证明了ＡＯＬ对肺腺癌细胞株Ｐ１８具有较强的直接杀伤能力．此外还发现ＡＯＬ对温度（８０℃以下）、变性剂（盐酸胍和脲）有较高的稳定性,在ｐＨ６～１０的范围内相当稳定．     

C60溶液,孤立分子及薄膜形态电子态结构分析

系统地给出了Ｃ６０在固态薄膜及不同有机溶液形态下的常规吸收光谱和三同商吸收光谱,确定了各相关光学跃迁能量,并通过对可见区电子－－振动光谱结构的指认分析,给出了有机溶液形态下Ｃ６０的能隙,基于Ｍａｘｗｅｌｌ－Ｇａｒｎｅｔｔ有效介质模型理论,由不同有机溶剂形态下Ｃ６０电子态能级结构参数外推获得了Ｃ６０孤立分子的本征电子态能级结构参数,从而为详细了解和研究Ｃ６０分子不同形态下电子态结构的变化提供了较完整     

Leakage of mantle helium from the Liaodong Peninsula, China

The isotopic cumpositions of helium have been investigated in hot spring gases sampled from the Liaodong Peninsula. China. The³He/⁴He ratios range from 0.14 Ra (0.14 times the atmospheric³He/⁴He ratio of 1.40 × 10^-6 to 0.72 Ra.³He/⁴He versus⁴He/²⁰Ne ratios and He contents suggest that a small amount of mantle-derived helium reaches the earth’s surface. Helium iwtope ratios of the hot spring gases show a distribution pattern similar to the regional heat flow values, indicating that the positive thermal anomaly occurring in the rtrea is closely associated with the presence of mantle-derived helium. The observations described above provide some significant evidence that the molten magma originating from partial melting of the upper mantle may have intruded into the continental crust along the activity fault. The coupling of the presence of mantle He and heat flow anomalies to seismic activity in studied region seem to imply that there is an internal relationship between mantle degassing and seismic activity.     

SrGa2S4:Ce blue TFEL in new structure

SrGa₂S₄: Ce blue TFEL device with a novel structure was prepared by electron beam evaporation. The dielectric constant of insulator layer in this structure is far less than that in the conventional structure, so the hot-electrons can be accelerated in SiO₂ layers. The stable TFEL with good chromaticity was achieved and the basic characteristics were investigated.     

Photoconductivity of fullerene derivatives

Two fullerene derivatives (compounds 1 and 2) have been synthesized. Their redox properties have been measured by cyclic voltammetry. The photoconductivities of poly(N_vinylcarbazo_le) (PVK) doped with fullerene and with their derivatives have been studied to explore the possible relationship between the reductibility of fullerenes and the photoconductivity of fullerenes_doped PVK. The charge generation efficiencies of PVK doped with fullerene and with its derivatives have changed remarkably: the diversity of charge generation efficiency is obvious in different doping systems. The result indicates that there is charge transfer between fullerenes and PVK.     

Search for new antiphytovirucides

The lead compound of substituted 2-(4′-hydroxyphenyl)benzimidazoles were modified by phosphorylation sulfonation and carboxymethylation. The benzimidazoloamidophosphate (6) (7) have better activity against tobacco mosaic virus (TMV). The benzimidazolophenoxyacetic acid, phenoxysulfonic acid containing trifluoromethyl, and nitro group have 77%≈85% efficiency for wheat rust disease. Supported by the National Natural Science Foundation of China and National Laboratory of Elemento Organic Chemistry Nankai University Qu Fanqi: born in 1952, Associate professor