NEPE固体推进剂能量水平的分析

借助电子计算机计算与分析了NEPE固体推进剂的能量水平,研究和比较了组分的含量与不同配比对推进剂配方标准理论比冲I_(ss)~°值的规律性影响.结果表明:I_(ss)~°值随配方中HMX,AP,Al三组分总含量的增加而增大,当含量达到70％以后比冲值变化的曲线上升趋于平缓;对于混合硝酸酯含能增塑剂,W_(NG)/W_(BTTN)比值的变更对I_(ss)~°的影响随配方中固体填料含量的不同而异,当含量值在73％以下,所加入的两种硝酸酯组分质量比值的变化对I_(ss)~°值的影响较大;硝酸酯用量与聚合物用量之比值(W_(PL)/W_(PO))的改变对I_(ss)~°的影响随固体含量的增大而减小,当固体含量超过70％,W_(PT)/W_PO值已达2.8的配方,再继续提高含能增塑剂的用量比例,所能获得的比冲增值很小;配方中小组分功能助剂的用量对推进剂I_(ss)~°值的影响较大。     

中草药淫羊霍中脂肪酸的测定

利用气相色谱FID检测器,测定中草药淫羊藿中脂肪酸的含量.BF_3-MeoH法快速酯化,并在混合填充柱上分离获得棕榈酸,硬脂酸,油酸和亚油酸的流出谱图,它们的含量分别是16.90、19.05、20.95和122.19mg/g淫羊藿.棕榈酸和硬胎酸的平均回收率分别为100.3%和100.4%,平均变异系数为2.88%.     

相转移催化合成乙酸苄酯香料

用氯化苄和乙酸钠为原料，以相转移催化法合成乙酸苄酯香料。提出了最佳工艺条件和反应过程中催化剂、过剩反应物料循环利用的可行性。结果表明，转化率高达９９％，选择性为９８％～１００％；产品收率在９０％～９５％．工艺过程简单，副反应很少，是乙酸苄酯生产的一条高产、优质、低成本的有效途径。     

Involvement of D-amino acid oxidase in elimination of D-serine in mouse brain

The physiological role of D-amino acid oxidase (EC 1. 4. 3. 3) in mouse brain is described. The presence of D-enantiomers of neutral common amino acids was surveyed in the brain. D-serine was shown to be present at high concentration only in regions where the enzyme activity was low. In normal mice whose D-amino acid oxidase activity was much higher in the cerebellum than in the cerebrum, free D-serine content was apparently lower in the cerebellum than in the cerebrum. In mice of a mutant strain lacking D-amino acid-oxidase activity, the free D-serine level was remarkably high both in the cerebrum and cerebellum. The results suggest that the enzyme is involved in the elimination of free D-serine in the cerebellum.     

Neuropeptides of the silkworm,Bombyx mori

Six neuropeptides of the silkworm,Bombyx mori, have been isolated and chemically characterized during the past 10 years. They are bombyxin, prothoracicotropic hormone, pheromone-biosynthesis-activating neuropeptide/melanization-and-reddish-coloration hormone, diapause hormone, eclosion hormone, and adipokinetic hormone. Recent progress in research on these neuropeptides is described.     

Evidence for the induction and release of pancreatic folylpolyglutamate hydrolase by the ingestion of folyl polyglutamates in the rat

Pteroyl polyglutamate hydrolase (folyl conjugase), which hydrolyses the dietary polyglutamyl folates into simple forms prior to absorption, has been shown to be induced in rat pancreas in response to dietary polyglutamyl folates but not by ingestion of synthetic unconjugated folates. Folate absorption, as measured by the rise in serum folate levels after ingestion, of dietary conjugated folates is impaired in pancreatectomised animals whereas absorption of synthetic simple folate is not. A severe build-up of folyl conjugase is observed in the lumen of control but not in pancreatectomised animals after dietary folate ingestion. These results taken together would suggest that dietary folates are hydrolysed to monoglutamyl forms suitable for absorption in the lumen; the hydrolysis is catalysed by a luminal folyl conjugase of pancreatic origin induced by dietary conjugated folates.     

Keggin结构和Dawson结构稀土杂多配合物热稳定性研究

首次合成了十种具有Keggin结构的硅钨钒四元稀土杂多配合物和七种具有Dawson结构的磷钼钒稀土杂多配合物;并利用TG、DTA、IR光谱和x射线粉末衍射等手段研究了两系列稀土杂多配合物的热稳定性;总结并解释了近年来文献报道的Keggin结构和Dawson结构的稀土杂多配合物的热稳定性的变化规律。     

从间硝基苯甲酸直接合成间二甲胺基苯甲酸

使用含有微量钯的钯铁复合催化剂,在室温下将间硝基苯甲酸的还原和烷基化还原合为一步,合成了间二甲胺基苯甲酸,产率为95.8%。     

含硫(氮)二茂铁衍生物的合成与表征

正戊醛、异戊醛、对氯苯甲醛、胡椒醛、环已酮与二茂铁在浓H_2SO_4(-10℃)中缩合,产物用碳酸氢钠水溶液水解,水解产物在F_3CCO_2H催化下发生巯基化反应,合成了五种含硫二茂铁衍生物,(C_5H_5)Fe(C_5H_4CR′R~2SCH_2CO_2H)(I,R′=H,R~2=n-C_4H_9;Ⅱ,R′=H,R~2=i-C_4H_9;Ⅲ,R′=H,R~2=C_6H_4Cl-4;Ⅳ,R′=H,R~2=C_6H_3O_2CH_2-3.4;V,R′R~2=-(CH_2)-_5);再由Ⅲ和V与氨和羟胺反应,合成两种含氮二茂铁化合物,(C_5H_5)Fe(C_5H_4CH(NH_2)(C_6H_4Cl-4))(Ⅵ)和(C_5H_5)Fe(C_5H_4C(NH)H)(CH_2)_5)(Ⅶ)。