基于IEEE1588的光纤通信同步系统

为了提高同步系统的时间精度,本文基于IEEE1588以及FPGA协议设计了带有透明时钟(TC)的交换机系统。该系统只用在MAC层对数据报进行处理,减少了数据报在交换机中的驻留时间,消除了由边界时钟(BC)引起的环路控制的影响,提升了系统的性能。     

有机物/TiO2电荷转移复合物的形成及其在可见光下的催化活性

以TiO2（Degussa P25）为光催化剂,可见光为激发光源,分别对甲醇/TiO2、甲醛/TiO2、甲酸/TiO2体系中光催化还原Cr6+的情况进行了研究. 结果表明,有机醇和羧酸能与TiO2形成电荷转移复合物. 这种复合物能够吸收400 nm以上的可见光,并通过LMCT（ligand-to-metal charge transfer）机制引发光催化还原反应. 不同的有机物/TiO2体系中,Cr6+的光催化还原反应表现出极大的差异,这种差别与有机物的结构密切相关. 当体系中不存在有机物时,可见光下TiO2几乎不能将Cr6+还原;当加入甲酸,经光照80 min后,Cr6+的还原率即可达100%;而在甲醛/TiO2和甲醇/TiO2体系中,光照6 h后,Cr6+的还原率分别可达93.63%和22.69%. 体系的pH对Cr6+的光催化还原反应有显著影响. 有机物/TiO2体系中,光催化还原Cr6+的反应符合一级动力学规律.     

Simulation of mode conversion at the magnetopause

Two-dimensional(2-D)and three-dimensional(3-D)hybrid simulations are carried out for mode conversion from fast mode compressional wave to kinetic Alfvn waves(KAWs)at the inhomogeneous magnetopause boundary.For cases in which the incident fast wave propagates in the xz plane,with the magnetopause normal along x and the background magnetic field pointing along z,the 2-D (xz)simulation shows that KAWs with large wave number kxρi～1 are generated near the Alfve′n resonance surface,whereρi is the ion Larmor radius.Several nonlinear wave properties are manifest in the mode conversion process.Harmonics of the driver frequency are generated.As a result of nonlinear wave interaction,the mode conversion region and its spectral width are broadened.In the 3-D simulation,after this first stage of the mode conversion to KAWs with large kx,a subsequent generation of KAW modes of finite ky is observed in the later stage,through a nonlinear parametric decay process.Since the nonlinear cascade to ky can lead to massive transport at the magnetopause,the simulation results provide an effective transport mechanism at the plasma boundaries in space as well as laboratory plasmas.     

Knockdown of <Emphasis Type="Italic">MRP4</Emphasis> by lentivirus-mediated siRNA improves sensitivity to adriamycin in adriamycin-resistant acute myeloid leukemia cells

Chemotherapy remains the standard treatment for acute myeloid leukemia;however,the emergence of drug resistance is a major hurdle in the successful treatment of leukemia.The expression of multidrug resistance-associated protein 4(MRP4)induces re- sistance in the adriamycin-resistant acute myeloid leukemia cell line,K562/ADR.The aim of this study was to investigate whether knockdown of MRP4 by lentivirus-mediated siRNA could improve the sensitivity of K562/ADR cells to adriamycin.Five lenti- virus-mediated short hairpin RNAs(lv-shRNAs-MRP4)were designed to trigger the gene silencing RNA interference(RNAi) pathway.The efficiency of lentivirus-mediated siRNA infection into K562/ADR cells was determined using fluorescence mi- croscopy to observe lentivirus-mediated GFP expression.MRP4 expression in infected K562/ADR cells was evaluated by real- time PCR and Western blot analysis.The MTS assay was used to measure cell viability and flow cytometry was used to measure apoptosis.The transfection efficiency of K562/ADR cells was over 80 percent.The gene silencing efficacy of lv-shRNA1-MRP4 was superior to the other constructs.Infection of K562/ADR cells with lv-shRNA1-MRP4 led to strong inhibition of MRP4 mRNA and protein expression.Combined treatment with lv-shRNA1-MRP4 and adriamycin decreased cell growth and increased apoptosis compared to treatment with lv-shRNA1-MRP4 or adriamycin alone.These data indicate that in K562/ADR cells MRP4 is involved in drug resistance mechanisms and that lentivirus-mediated knockdown of MRP4 may enhance sensitivity to adriamycin.     

5-溴-4-氯-3-吲哚基磷酸盐共振散射光谱法检测碱性磷酸酯酶

在pH8.0的Tris-HCl缓冲溶液及32mg/L PEG20000的存在下,碱性磷酸酯酶(ALP)催化底物5-溴-4-氯-3-吲哚基磷酸盐(BCIP)水解生成不溶性的蓝色BCIP二聚体微粒,该微粒在710nm波长处产生一个共振散射峰。在选定条件下,随着ALP活性增大,710nm波长处的共振散射峰强度线性增大,碱性磷酸酯酶浓度在0.078～1.25U/L与共振散射强度增大值ΔI呈良好线性关系,其回归方程为:ΔI=512.6C+17.8,检出限为9.6×10-3U/L。该法用于合成样品中碱性磷酸酯酶的测定,结果满意。     

Q235钢表面激光熔覆Cr_7C_3的性能研究

利用激光熔覆技术将摩尔比为91：9的Cr、C合金粉末制备于Q235钢表面。采用光学显微镜、x射线衍射仪、扫描电子显微镜和硬度分析仪分析熔覆层的显微组织结构及截面的显微硬度。试验结果表明,当激光功率为2500W和扫描速度为2.5mm/s时,熔覆层与基体的冶金结合较好,同时可获得无裂纹、无孔洞且表面平整的涂层。     

CseNaYC16：Sm3＋晶体的光学与磁学性质研究

掺杂三价稀土离子（Re3＋的Cs3NaYC16晶体,因具有优良的光学和磁学性质而得到了高度的重视。本文利用晶体场理论和自旋哈密顿理论分别对Cs2NaYCl6：Sm3＋晶体的光谱和电子顺磁共振谱（EPR）进行分析和计算。在叠加模型的基础上,通过对角化24x24能量矩阵研究cs2NaYCl6：Sm3＋时的能级、电子顺磁共振参数和超精细结构常数。计算结果与观测值能够较好的吻合并对结果进行讨论。     

厌氧氨氧化影响因素分析研究

厌氧氨氧化是目前最简捷、最经济的生物脱氮途径之一,受到极大的关注,但是厌氧氨氧化菌生长缓慢,环境条件要求高,综述了基质浓度、温度、pH值对厌氧氨氧化活性的影响,探讨适合厌氧氨氧化菌生长的有利条件,并对厌氧氨氧化的发展提出了建议。     

1-（4-硝基苯基）-3-（4-羟基-6-甲基-嘧啶）-三氮烯与锌的显色反应研究

根据报道合成了显色剂1-（4-硝基苯基）-3-（4-羟基-6-甲基-嘧啶）-三氮烯（NPHMPDT）,研究了该试剂与锌的显色反应。在OP的存在下,pH 10.0的Na2B4O7-NaOH缓冲溶液中,该试剂能与锌发生显色反应,锌与NPHMPDT形成摩尔比为1：4的配合物,在460 nm处有一最大正吸收,540 nm处有一最大负吸收。以460 nm为参比波长,540 nm为测量波长进行双波长测定,表观摩尔吸光系数为2.34×105L.mol-1.cm-1,锌0～480μg/L符合比尔定律。用拟定方法测定人发中的微量锌,结果满意。