风险厌恶下第三方物流供应商选择的拍卖机制

以往在研究第三方物流供应商的选择问题时,通常假设第三方物流供应商(3PLS)对第四方物流集成商(4PLI)持风险中性态度,而这与现实是不符的.为了使研究更加贴近实际,考虑第三方物流供应商有风险态度的情况下,第四方物流集成商通过多属性逆向拍卖方式对第三方物流供应商进行选择.通过案例设计和进行相关实验,发现通过条件风险价值(conditional value at risk,CVaR)的风险度量方法对风险态度进行度量,很好地将风险因素融合到了多属性逆向拍卖中,打破了传统的第四方物流集成商选择时风险中性的假设,并且将风险度量中常用的CVaR方法融合到了供应商选择中,具有一定创新性.通过对不同风险厌恶程度以及风险中性的情况进行对比,结果表明,当3PLS为风险中性时对4PLI是最有利的,当3PLS为风险厌恶时,风险厌恶程度越小对4PLI越有利.     

A novel Fe/HNT visible light-driven heterogeneous photocatalyst: Development as a semiconductor and photocatalytic application

Fe/HNT (Iron/Halloysite-nanotube) heterogeneous semiconductor catalysts operating effectively under visible light were developed by using FeCl₃, FeSO₄ and Fe(OH)₃ sludge precipitated after electro-Fenton process and named as Fe/HNT-I, Fe/HNT-II and Fe/HNT-III, respectively. Chemical configuration and particle morphology of the catalysts were characterized with XRD, SEM-EDS and UV–vis DRS. Effect of the developed Fe/HNT photocatalysts was investigated for the degradation of Reactive Orange 16 (RO16) textile dye under visible light. The photocatalytic decolorization of RO16 was 95.6%, 99.3% and 96.6%, respectively. It was found that the photocatalytic performance of Fe/HNT-III catalyst under visible light was effective compared to Fe/HNT-I and Fe/HNT-II. The iron ratio in the catalyst's structure (Fe:HNT ratio 0.25, 0.5 and 0.75 (w/w)) and pH value (4, 7 and 9) in production phase were also changed to investigate the photocatalytic effect of Fe/HNT-III. An Fe:HNT ratio of 0.25 and a pH of 4 were determined as the optimum conditions for catalyst production. Optimum H₂O₂ dosage value was also investigated for photocatalytic oxidation process and determined to be 10 ?mM. Finally, the optimum conditions were further used for the degradation of Terbinafine hydrochloride (TerHCl) active drug and the treatment of wastewater from the textile and pharmaceutical industries.     

Effect of Zr addition on the stability of precipitated Laves phase and mechanical properties of Fe–Cr–Al-based alloys at high temperatures

The effect of a small amount of Zr addition on the temperature-dependent stability of Laves phase particles and mechanical properties of Fe-13.5Cr-4.73Al-2.07Mo-(0.34–0.5)Nb-(0.65–0.98)Ta-(0–0.33)Zr (wt. %) ferritic alloys was investigated in the present study. The designed alloy ingots were hot-rolled, aged at 1073 ?K for 24 ?h, and then re-treated at 1273 ?K, 1323 ?K, 1373 ?K, and 1473 ?K for 1 ?h, respectively. It was found that the Zr addition could not only stabilize the Fe₂M Laves phase (M ?= ?Mo,Nb,Ta,Zr) to a much higher temperature, but also induce the formation of stable Fe₂₃Zr₆ phase. The high-temperature (HT) microstructural stability of the alloys significantly was improved, as evidenced by the fact that a certain amount (0.66–1.19%) of precipitates (Fe₂M, Fe₂₃Zr₆, and core(Fe₂₃Zr₆)-shell(Fe₂M)-structured particles) with an appropriate size (～1.0 ?μm) uniformly distributed in the ferritic matrix even after being re-treated at 1473 ?K. Particularly, the formation of core-shell-structured particles at HTs was studied from the viewpoint of both solid solubility and diffusion coefficient of M in the matrix. All these aged alloys exhibited prominent mechanical properties at both room and elevated temperatures, showing high yield strength with σ_YS ?= ?490–560 ?MPa at room-temperature and σ_YS ?= ?80–85 ?MPa at 1073 ?K. The strengthening effect was further discussed in light of various strengthening mechanisms, and the calculated strength are in good agreement with the experimental results.     

聚三嗪亚胺的合成及从水溶液中吸附铀

利用熔盐法合成了聚三嗪亚胺(polytriazineimide,PTI),并用来吸附水中的U(VI)。在常温下,PTI对铀的最大饱和吸附量达到了135.5 mg/g,与g-C₃N₄相比,是g-C₃N₄饱和吸附量的54.2倍。通过对动力学与吸附等温线模型的探究,发现PTI对U(VI)的吸附符合准一级动力学模型,说明PTI吸附U(VI)属于物理吸附。同时,Langmuir吸附等温线模型能更好地拟合PTI对U(VI)的吸附过程,说明U(VI)在PTI上属于单层吸附。通过对吸附铀后的材料进行XPS表征,发现铀在吸附后的价态没有改变,仍为U(VI)。     

化学氧化-沉淀法对某酸性矿山废水中铁的资源化回收处理工艺

采用化学氧化-沉淀法处理某Fe²⁺浓度为800 mg/L的高酸度矿山废水,通过研究不同碱性试剂的添加对调节pH和对铁去除效果的影响以及曝气氧化时间、絮凝剂添加量等方面对废水中铁氧化沉淀效率的探究。结果表明:当使用质量分数为20%的石灰乳调节废水pH至8.0,曝气氧化2 h时,废水中铁的去除率达到99.99%,其废水上清液中TFe的残余质量浓度为0.8 mg/L。再向处理后的废水中加入0.5 mL/L质量浓度为0.1%聚丙烯酰胺使含铁沉淀絮凝沉降,过滤沉淀并烘干后得到铁品位约为40%的沉淀渣,可以作为制备聚合硫酸亚铁的原料。再将沉淀渣在管式炉中700 ℃条件下焙烧30 min得到铁品位约为60%产品,可以作为炼铁的原材料。     

多道次摩擦搅拌处理和镁添加对Al 1050合金的微观结构和拉伸性能的影响

研究了多道次搅拌摩擦加工 (FSP) 和镁粉添加对 Al 1050 合金不同微观结构部分的影响,包括搅拌区 (SZ)、热影响区 (HAZ) 和热机械影响区 (TMAZ)等。对微观结构分析结果表明,随着 FSP 道次的增加,非复合样品和复合样品中 SZ 的晶粒尺寸减小,而非复合样品中 TMAZ 和 HAZ 的晶粒尺寸增加。此外,镁粉的加入导致了大程度的晶粒细化,增加 FSP 道次的数量导致原位复合样品中 Al–Mg 金属间化合物的分布更均匀。拉伸试验结果表明,与母材和复合材料样品相比,经过四道 FSP 的非复合材料样品表现出更高的伸长率和韧性断裂。然而,与母材和非复合样品相比,该样品表现出脆性断裂和更高的拉伸强度。与经过 FSP 的母材和非复合材料样品相比,复合材料样品的制造显着提高了硬度。     

新型微电解填料对2, 4-二硝基苯酚废水降解的电化学特性

以一种基于双金属体系的新型三元微电解填料为研究对象,通过循环伏安法和紫外光谱扫描对其降解2,4-二硝基苯酚废水机理进行了初步探究。通过对2,4-二硝基苯酚溶液进行循环伏安法测定,模拟铁碳微电解填料对2,4-二硝基苯酚溶液的电化学催化降解过程。研究pH、温度、DO、电导率等试验因素下在2,4-二硝基苯酚降解过程中对循环伏安曲线的影响。结果表明:新型铁碳微电解填料对2,4-二硝基苯酚的降解过程包含电化学催化还原作用。     

A4分子的定性分子轨道处理

本文用定性分子轨道理论和碎片轨道法构造了氢原子簇Ｈ４和代表性元素磷的四原子簇合物Ｐ４的分子轨道。可得分子轨道的形状和相对能级次序与定理计算结果一致。     

LiCr0.10Mn1.90O4粒径分布对倍率放电性能的影响

以不同粒径LiCr0.10Mn1.90O4为活性物制备电极，与对电极锂片装配成模拟电池后进行电化学性能研究。结果表明，随着LiCr0.10Mn1.90O4O粒径的增大，锂离子传输困难与JahnTeller畸变导致其倍率充放电性能逐渐下降。兼顾到活性物的填充性能，选择粒径大约10μm的活性物较为适宜。     

C+3和C+4分子离子的结构与性质研究

用密度泛函B3LYP／6-311g*方法计算得到C3^ 分子离子的稳定构型为角形C2v结构，C4^ 分子离子有6种可能构型，即Cs,D∞h，C2v，C∞v，C2h，D2h结构。同时，计算表明C4^ (D4h)和C4^ (Td)不能稳定存在。