软土中薄硬夹层的夯扩桩工程实践

结合工程实践对夯扩桩在软土中薄硬夹层的应用进行了探讨,提出薄硬夹层作为桩端持力层的加固方法.     

流动注射化学发光增强法测定酪氨酸

在Na2CO3-NaHCO3介质中,酪氨酸对Luminol-K3Fe(CN)6化学发光体系有很强的增敏作用.据此建立了流动注射化学发光增强法测定酪氨酸的方法.发光信号的增强值(ΔI)与酪氨酸的浓度在5.0×10-5～4.0×10-7mol/L的范围内呈良好的线性关系,检出限为1×10-7mol/L(S/N=3),对于1.0×10-6mol/L的酪氨酸测定相对标准偏差为2.4%(N=11).该法用于测定医用氨基酸注射液中的酪氨酸,结果令人满意.     

Preparation and properties of the SmOx/Rh(100) model surface

The preparation of SmOx/Rh(100) and CO adsorption on this model surface have been investigated with Auger electron spectroscopy (AES), X-ray photoelectron spectroscopy (XPS) and temperature programmed desorption spectroscopy (TDS). The oxygen adsorption on the SmRh alloy surface leads to the aggregation of Sm on the surface. The thermal treatment of this oxidized surface induces the further agglomeration of SmOx on the Rh(100) surface. Compared with CO TDS on the clean Rh(100) surface, three additional CO desorption peaks can be observed at 176, 331 and 600 K on the SmOx/Rh(100) surface. The CO desorption peak at 176 K may originate from CO adsorbed on SmOx islands, while the appearance of the CO adsorption peaks at 331 and 600 K, depending on the oxidation state of Sm, is attributed to CO species located at the interface of SmOx/Rh(100).     

Shevrin问题的若干充要条件

利用偏序讨论了Ｉ＿３一半群的一些性质，并给出了Ｓｈｅｖｒｉｎ问题的若干充要条件。     

超微粒子－有机聚合物薄膜的研究

我们用离子团束－飞行时间质谱（ＩＣＢ－ＴｏＦＭＳ）系统制备了金（Ａｕ）超微粒子－聚乙烯（ＰＥ）薄膜和Ｃ＿（６０）－聚乙烯薄膜。用透射电子显微镜（ＴＥＭ）分析了所制备的样品。它们的结构是Ａｕ超徽粒子镶嵌在多晶的ＰＥ薄膜中，其中Ａｕ原子团呈球形，直径分布在２．０－５．０ｎｍ窄范围内，当沉积基底温度为９０℃时，Ａｕ原子团相互靠近，几乎连接起来，但仍保持原来大小。基底温度为１４０℃蒸积的Ｃ＿（６０）－ｐＥ薄膜具有晶态结构，其晶格常数为１．４５４ｎｍ。     

最小二乘解存在的充分必要条件

本文提出了当观测值的权矩阵为正定或半正定的前提下，其最小二乘解存在的充分必要条件为并以间接平差为例验证了该结论的正确性。     

化学气相沉积法制备光谱选择性碲膜

用化学气相沉积法制备碲薄膜,其步骤为：通过电化学方法制得碲化氢,碲化氢在室温下分解后在聚乙烯塑料箔上沉积得到碲薄膜.用傅里叶红外光谱仪、紫外/可见/近红外光谱仪、X射线衍射仪及扫描电镜表征碲薄膜的光学性能和结构.结果表明,化学气相沉积法在Mn-O覆盖的聚乙烯塑料箔上沉积得到的碲薄膜在大气窗口（8～13μm）光谱区域具有很高的透过率,同时能阻挡几乎所有的太阳光谱,表明碲薄膜是适用于辐射制冷装置的太阳光辐射屏蔽材料.     

基于3S技术的土地利用动态变化研究

3S技术是研究土地利用动态变化的重要技术手段，具有传统方法无法比拟的优越性。本文以秦皇岛市为例，定量分析了区域内土地利用动态变化。针对区域土地利用程度及生态环境可能产生的影响进行了简要的评价，揭示了研究区土地利用变化规律，为秦皇岛市实现生态环境目标提供决策依据。     

Liquid-Liquid Equilibrium for 1-Butanol-Water-KF and 1-Butanol-Water-K2CO3 Systems

KF or K2CO3 was added into the 1-butanol-water system and two phases were formed： water-rich phase （water phase） and 1-butanol-rich phase （1-butanol phase）. The liquid liquid equilibrium （LLE） data for 1-butanol-water-KF and 1-butanol-water-K2CO3 systems were measured at 25℃ and showed that 1-butanol phase contained negligible salt and water phase contained negligible 1-butanol when the concentrations of KF and K2CO3 in the water phase were equal to or higher than 27.11% and 31.68% , respectively. Thus water could be separated efficiently from 1-butanol-water by adding KF or K2CO3 into the system. A theoretical calculation of LLE data was calculated by using the Pitzer theory to get water activity in the water phase, and by the models, such as the Wilson, NRTL or the UNIQUAC for the 1-butanol phase. For 1-hutanol-water-KF system, the experimental data were found in good agreement with the calculated results by using Pitzer theory and Wilson equa tion, while for 1-butanol-water-K2CO3 system, the experimental data were found in good agreement with the calculated results by using Pitzer theory and UNIQUAC eauation.     

氯离子诱导的镍在硝酸溶液中的电流振荡

报道了氯了子诱导的镍在0．5mol.dm^-2硝酸溶液中活化－钝化过渡区电流振荡，在恒电位条件下，随着氯离子浓度的升高或者电极电位的降低，电流振荡由周期性振荡逐渐向非周期性振荡转变，根据实验结果，对该体系的电流振荡机理进行了讨论。