Synthesis and magnetic property of a nitroxide based on C60

The compounds containing stable nitroxide radicals possess magnetic properties for the free radical have net magnetic moment. Oxidization of the [60]fulleropyrolidine obtained from the reaction of C60 with diketone and 2-aminoisobutyric acid by m-chloroperoxybenzoic acid gives a new nitroxide integrated with C60. The stable nitroxide based on C60 is confirmed to be antiferro- magnetism with quantum design superconducting quantum interference device (SQUID).     

Pyroelectric spectrum in Pb(Zr,Sn,Ti)O3 antiferroelectric-ferroelectric ceramics

The pyroelectric effect of phase transition induced with temperature in Nb-modified Pb(Zr,Sn,Ti)O₃ antiferroelectric-ferroelectric ceramics is studied. Experimental results reveal that the phase transitions are accompanied with marked pyroelectric peaks, there exists the close relation between the type of phase transition and the shape of pyroelectric peak. Because of the variations of phase transition, various pyroelectric spectra result. The pyroelectric spectrum can display the polarization effect and some inferior phase transitions with temperature variations, such as antiferroelectric AFE_A-AFE_B or ferroelectric FE_L-FE_H transition, which are not detected by the conventional dielectric measurement.     

切槽机建模及其工作过程模拟

介绍 3D Studio MAX制作的一般过程 ,以 YD41 40型切槽机的 CAD为基础 ,利用该软件为切槽机建立模型 ,并对其工作过程进行动态模拟 .通过建模和动态仿真 ,检验和校正了切槽机 CAD设计中的一些不足     

具有液晶性的杯[4]芳烃衍生物的合成及性质研究

物理学家早就预言 ,如果能获得碗状分子 ,而这个“碗”中又放一个原子或原子团的话 ,必将能获得具有特殊光学特性的液晶材料[1] .而杯芳烃就可以构成这样的“碗” .杯芳烃因其特殊的疏水功能和选择性配合金属离子的特性 ,以及易于通过母体杯芳烃合成具有各种特性的杯芳烃衍生物而得到广泛应用[2～ 7] ,被称为第三代超分子 .根据杯芳烃及其衍生物具有对金属离子的选择性配合作用及发光的敏化作用 ,我们设计并合成了既有液晶性 ,又能配合金属离子和敏化金属离子发光的杯 [4 ]芳烃衍生物 (Ｅ) ,并对其性质进行了研究 ,取得了一些未见报1　实验1…     

新型多氟氮超酸镧系金属盐的Lewis 酸性研究

合成了若干新的多氟氮超酸的镧系金属盐，并用 IR，     

不对称取代方酸内鎓盐衍生物电子结构和光谱的理论研究

采用PM3系列方法对新合成的10个不对称取代方酸内盐进行了系统研究.计算得到它们的优化几何构型、电荷分布、IR谱及UV谱,并对光谱进行了理论确认.考察了组态数对理论UV谱的影响.结果表明它们都具有刚性平面结构:方酸环为缺电子中心:对前线轨道的能量分析说明这10个衍生物的一价负离子可以稳定存在,随着组态数目的增加,理论UV谱与实验结果的误差呈减小趋势.所有的光谱理论值和实验值的误差在10%左右.     

基于μC/OS-Ⅱ的烟尘浓度监测仪的设计与实现

介绍了基于μC/OS-Ⅱ的烟尘浓度监测仪的设计与实现,它将为环境保护部门提供可靠、及时的决策依据,实现对大气污染物排放的有效监测.     

Using Acoustic Emissions to Detect Damage in Three-Dimensional Braided Composites

Three-dimensioual(3D)braided composites with better properties have been used in some particular industries.Some have had obvious signs of crack when they are braided.Others have had catastrophic failures occuring without warning.A new methodology for the analysis of failure modes in composite materials by means of acoustic emission techniques has been developed.The occurrence of fiber-breakage during tensile loading tests has been observed by the acoustic emission technology.Using acoustic emission technology is investigated as a means of monitoring 3D braided composites structures,detecting damage,and predicting impending damage.Stone of the findings of the research project were presented.     

3G应用进入物联网时代

当前,我国已将物联网正式列为重点发展的战略新兴产业之一.而3G在中国经历了近两年的发展,并没有达到预期的红火,促使电信运营商争相在物联网发展上投入重兵,中国的3G应用即将进入物联网时代.     

基于Java3D的太阳系仿真的原理与实现

提出一种基于Java3D平台的太阳系仿真的方法,此方法以递归的形式构造天体运行轨道的同时采用全场景的逆向运动补偿的方式跟踪定位某个天体.实验结果表明,此算法的视觉效果很好.