硅或钛取代AlPO-11分子筛的合成及表征

介绍了硅，钛取代A1PO-11分子筛SAPO-11、TAPO-11的合成方法，采用X射线衍射（XRD）、扫描电子显微镜（SEM）、热重-差热、氮气吸脱附等手段对合成的分子筛进行了表征，考察了晶化温度和原料比对分子筛合成的影响。结果表明，硅，钛取代A1PO-11分子筛能生成AEL结构的TAPO-11分子筛；SAPO-11与A1PO-11分子筛表观形貌相差不大，而TAPO-11分子筛表观形貌则与A1PO-11分子筛有很大不同；硅，钛取代后分子筛的孔道半径及其孔容有所改变；3种分子筛都具有较好的热稳定性。     

Anti-nociceptive role of neuropeptide Y in the nucleus accumbens in rats with inflammation, an effect modulated by mu- and kappa-opioid receptors

Recent study in our laboratory showed that neuropeptide Y (NPY) plays an antinociceptive role in the nucleus accumbens (NAc) in intact rats. The present study was performed to further investigate the effect of NPY in nociceptive modulation in the NAc of rats with inflammation, and the possible interaction between NPY and the opioid systems. Experimental inflammation was induced by subcutaneous injection of carrageenan into the left hindpaw of rats. Intra-NAc administration of NPY induced a dose-dependent increase of hindpaw withdrawal latencies (HWLs) to thermal and mechanical stimulations in rats with inflammation. The anti-nociceptive effect of NPY was significantly blocked by subsequent intra-NAc injection of the Y1 receptor antagonist NPY28-36, suggesting an involvement of Y1 receptor in the NPY-induced anti-nociception. Furthermore, intra-NAc administration of the opioid antagonist naloxone significantly antagonized the increased HWLs induced by preceding intra-NAc injection of NPY, suggesting an involvement of the endogenous opioid system in the NPY-induced anti-nociception in the NAc during inflammation. Moreover, the NPY-induced anti-nociception was attenuated by following intra-NAc injection of the μ-opioid antagonist β-funaltrexamine (β-FNA), and κ-opioid antagonist nor-binaltorphimine (nor-BNI), but not by δ-opioid antagonist naltrindole, indicating that μ- and κ-opioid receptors, not δ-opioid receptor, are involved in the NPY-induced anti-nociception in the NAc in rats with inflammation.     

An approach to 3D NURBS modeling of complex fault network considering its historic tectonics

Fault disposal is a research area that presents difficulties in 3D geological modeling and visualization. In this paper, we propose an integrated approach to reconstructing a complex fault network (CFN). Based on the non-uniform rational B-spline (NURBS) techniques, fault surface was constructed, reflecting the regulation of its spatial tendency, and correlative surfaces were enclosed to form a fault body model. Based on these models and considering their historic tectonics, a method was put forward to settle the 3D modeling problem when the intersection of two faults in CFN induced the change of their relative positions. First, according to the relationships of intersection obtained from geological interpretation, we introduced the topological sort to determine the order of fault body construction and rebuilt fault bodies in terms of the order; then, with the disposal method of two intersectant faults in 3D modeling and applying the Boolean operation, we investigated the characteristic of faults at the intersectant part. An example of its application in hydropower engineering project was proposed. Its results show that this modeling approach can increase the computing efficiency while less computer memory is required, and it can also factually and objectively reproduce the CFN in the engineering region, which establishes a theoretical basis for 3D modeling and analysis of complex engineering geology.     

决策树的经典算法:ID3与C4.5

决策树各类算法,各有特点,其中J.R.Quinlan提出的ID3算法最具代表性,在国际上的影响也最大,C4.5算法就是在ID3算法基础上进行改进得到的.通过对两种算法详细描述,阐明了决策树算法步骤及其主要思想.     

TiO2过渡层对BiFeO3薄膜微结构和铁电磁性质的影响

研究了TiO2过渡层对BiFeO3薄膜微结构和铁电磁性质的影响.采用溶胶-凝胶法分别在Si（100）和Pt（111）/Ti/SiO2/Si（100）衬底上制备了BiFeO3薄膜.通过加入约10 nm厚度的TiO2过渡层,在两种衬底上均制备出了纯相BiFeO3薄膜,而未加过渡层的薄膜均有杂相存在.与未加TiO2过渡层相比较,BiFeO3/TiO2薄膜表面颗粒大小更加均匀、致密、平整.在室温10kHz下沉积在Pt/Ti/SiO2/Si衬底上的薄膜的损耗从0.094下降到0.028;而薄膜的介电常数变化不大,分别为177和161.在室温下同时测得了薄膜的电滞回线和磁滞回线.BiFeO3/TiO2薄膜的饱和磁化强度为16.8 emu/cm3,在600kV/cm电场下,剩余极化强度为9.8μC/cm2.研究表明,TiO2过渡层能够有效地抑制Bi FeO3薄膜杂相的生成,提高薄膜的表面平整度以及耐压性.     

基于三叉树的城市雨水管网优化设计

在城市雨水管网的优化设计中,采用了图论中树形结构的理论来描述雨水管网.提出用n叉树(n=3)的形式来处理雨水管网的网络结构,把管段当作树的结点进行研究;利用树的遍历中的后序法来进行水力计算;在优化计算时采取了枚举标准管径法来选取管径,可以提高运算速度.笔者用Delphi语言编制了雨水管网优化程序,用天津某小区的雨水管网对此程序进行了实例考核.     

1：10000数字线画图生产流程的探讨

以张家界市桑植县1:1万数字线画图(DLC)的生产为例,探讨了在中小型项目中应用Geoway数据加工平台进行DLC生产的加工流程、质量控制等问题,取得了一定的经验,为测绘部门和相关工作者提供参考。     

高温纯铁熔体中外加氧化铝纳米粉的研究

在工业纯铁熔体中加入纳米Al2O3颗粒,熔炼后得到铸锭试样. 用扫描电镜(SEM)及能谱(EDS)研究了铸锭金相试样中夹杂物的存在状态及成分. 采用非水溶液电解法分离、收集铸锭中的非金属夹杂物,用SEM及EDS分析了夹杂物的形貌、大小和元素组成. 结果表明,外加的纳米Al2O3颗粒能够在纯铁熔体中稳定存在,并与杂质元素所生成的夹杂物发生复合,复合夹杂物的尺寸为5～10 μm. 纳米Al2O3颗粒一般存在于复合夹杂物的内部. 未发现纳米Al2O3团聚烧结成大于10 μm颗粒的现象. 从热力学和颗粒运动行为方面进一步分析了纳米Al2O3在纯铁熔体中的稳定性和团聚烧结成大颗粒的可能性.     

基于A*算法的远程导弹三维航迹规划算法

提出了一种基于A*算法的三维航迹规划方法.该方法将远程导弹的运动学模型离散化,利用导弹过载作为控制量,并结合约束条件,直接对三维空间进行最优航迹搜索.航迹规划过程不仅结合了导弹的本身机动特性,并且充分利用地形信息进行地形回避和威胁回避.仿真实验表明,该方法能够直接规划出三维空间中满足导弹过载约束的最优航迹.     

H4SiW12O40-PAn催化剂催化合成4-甲基-2-苯基-1,3-二氧戊烷

目的自制H4SiW12O40(硅钨酸)-PAn(聚苯胺)环境友好催化剂并进行有机物合成应用研究。方法通过FT-IR,XRD和TG/DTA手段对自制催化剂进行表征,以苯甲醛和1,2-丙二醇为原料合成4-甲基-2-苯基-1,3-二氧戊烷,探讨H4SiW12O40-PAn催化剂对缩醛反应的催化活性,较系统地研究了原料量比,催化剂用量,反应时间诸因素对产品收率的影响。结果在n(苯甲醛)/n(1,2-丙二醇)=1/2.0,催化剂用量为反应物料总质量的0.5%,环己烷为带水剂,反应时间45 min的优化条件下,4-甲基-2-苯基-1,3-二氧戊烷的收率可达87.4%。结论实验结果表明,H4SiW12O40-PAn是合成苯甲醛1,2-丙二醇缩醛的良好催化剂。