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71.
3—己烯—1—醇及其酯类的合成和香气研究 总被引:7,自引:1,他引:6
介绍了叶醇(cis-3-己烯-1-醇)及其异构体的实用合成路线。由顺反混合(或全反式)3-己烯-1-醇制备了一系列羧酸酯,研究了这些化合物的结构与香气的关系,从中发现一些有实用价值的新香料。 相似文献
72.
Summary Metabolism of 26-hydroxycholesterol to 3-hydroxychol-5-en-24-oic acid and other C24-bile acids has been expected to occur by way of 3-hydroxycholest-5-en-26-oic acid in studies in vitro. 3-Hydroxycholest-5-en-26-oic acid was infused intravenously into bile fistula hamsters and the following C24-bile acids were identified: 3-hydroxychol-5-en-24-oic acid, lithocholic acid, chenodeoxycholic acid, and a small amount of cholic acid. 相似文献
73.
A. M. Fenyves M. Saxer K. Spanel-Borowski 《Cellular and molecular life sciences : CMLS》1994,50(2):99-104
Five cell types recently isolated from the bovine corpus luteum differed in their epithelioid morphology and their cytoskeleton, but shared common criteria of microvascular endothelial cells1,2. To give strong evidence for the separate entity, the growth rate of the 5 phenotypically different cells was studied. They were seeded at low density on day 0. Most of these cells were treated with 200 to 1000 U recombinant bovine interferon- (IFN-) for 3 days. The untreated remainder served as controls. Cell counts were made for all cultures on days 4, 7, 10 and 13. morphology: 13 d after treatment with IFN- senescent cells as well as intact cells occurred in cultures of cell types 1 to 4. Cultures of cell type 5 were apparently unchanged and resembled their untreated counterparts. Desminpositive cells in cultures of cell type 2 developed cell processes. Growth rate: In the absence of IFN-, the growth rate was high for cell types 3 and 4, moderate for cell type 1, and low for cell types 2 and 5. The presence of IFN- caused anti-proliferative effects. These were higher for cell types 3 and 4 than for cell types 1 and 2. IFN- could be cytotoxic on cell type 3. In contrast, the cytokine tended to support the cell growth of cell type 5. These findings substantiate the postulate that endothelial cells exhibiting separate morphology in culture also function differently. 相似文献
74.
B. Streit 《Cellular and molecular life sciences : CMLS》1995,51(5):425-436
The goal of this article is twofold: 1) It aims at providing an overview on some major results obtained from energy flow studies in individuals, populations, and communities, and 2) it will also focus on major mechanisms explaining community structures. The basis for any biological community to survive and establish a certain population density is on the one hand energy fixation by primary producers together with adequate nutrient supply and the transfer of energy between trophic levels (bottom-up effect). On the other hand, predator pressures may strongly control prey population densities one or more trophic levels below (top-down effect). Other interpopulation effects include competition, chemical interactions and evolutionary genetic processes, which further interact and result in the specific structuring of any community with respect to species composition and population sizes. 相似文献
75.
本文合成了苯甲酰三氟丙酮(L)和三苯基氧膦(TPPO)、联吡啶(Bipy)、邻菲罗啉(phen)、四甲基氢化铵(NMe4OH)与稀土Y、La、Eu、Tb离子的混合型配合物。测定配合物的H1NMR谱及质谱,并对测定结果进行了分析。 相似文献
76.
室温,氮气氛下,铜(Ⅱ)盐和双二苯基膦戊烷(dppp5)在溶液中通过还原取代反应合成了8种铜(Ⅰ)配合物(1.[Cu(dppp5)]2(BF4)2,2.[Cu2(dppp5)2(C8H3O2SF3)2],3.[Cu2(dppp5)3](CCl3COO)2,4.[CuBr(dppp5)]2,5.[Cu2(dppp5)Cl2],6.[Cu2(dppp5)3](CH3COO)2,7.[Cu(dppp5)(NO3)],8.[Cu2(dppp5)3](ClO4)2)。通过元素分析、红外光谱、热重、摩尔电导测定对其进行表征,表明这是一种行之有效的有机膦配合物的合成方法。 相似文献
77.
阳离子交换树脂催化合成1—萘乙酸甲酯的研究 总被引:6,自引:0,他引:6
本文研究了用强酸性阳离子交换树脂作催化剂,1—萘乙酸和甲醇直接酯化合成1—萘乙酸甲酯的反应。考察了催化剂用量,反应物料配比,反应时间等因素对产率的影响,通过正交实验,找到了较佳反应条件:当催化剂用量为反应液的3%,醇酸摩尔比为20~30,在回流温度下反应4小时,酯的收率>92%,纯度>99%。该法工艺简单,操作方便,无三废污染,适合工业化生产。 相似文献
78.
1,6—二磷酸果糖制备研究:Ⅰ.菌种的筛选及培养条件 总被引:3,自引:2,他引:1
介绍了1,6-二磷酸果糖产生菌的筛选和最佳培养条件的确定,在所筛选的菌种中9518、9519号菌株均具较高的产1,6-二磷酸果糖酶系活力。其最佳培养条件为:培养温度28℃,pH6.5。 相似文献
79.
Semiconductor(ZnxCd1−x
S) doped silica glasses were prepared by Sol-Gel process andin situ growth technique. The structure of the materials was characterized by X-ray diffraction technique, the particle size of semiconductor
crystallites from X-ray patterns was estimated less than 10 nm. From absorption spectra, it is obtained that the absorption
edges shifted to short wavelength direction when Zn contents increased, and the absorption edge can be adjusted from 2.46
eV to 2.96 eV by controlling Zn contents. The third-order nonlinear optical susceptibility was studied at 532 nm with 8 ns
pulse laser by degenerate four wave mixing (DFWM) technique. 相似文献
80.
Colony-stimulating factor-1 (CSF-1), which is necessary for cell proliferation and differentiation, regulates both immediate
and delayed early responses throughout G1 phase. The binding of CSF-1 to its receptor (CSF-1R) triggers phosphorylation of
the receptor and its intrinsic tyrosine kinase. The activated receptor binds directly to cytoplasmic effector proteins, which
induce multiple-signal transduction pathways. CSF-1 can induce the c-myc gene expression via Ras and Ets-related proteins.
The expression of c-fos/jun family genes is also targeted following the activation of Ras. CSF-1R activates STAT1 and STAT3
to participate in signaling, but JAKs do not appear to contribute to signaling by CSF-1R. CSF-1R activates PI3-kinase, and
PI3-ki can interact with downstream proteins by the MAPKK-related pathway independent of Ras/Raf. PC-PLC can enforce signaling
in response to CSF-1. Furthermore, the turnover and dephosphorylation by the phosphatase SHPTP1 of CSF-1R are the major mechanism
in the negative regulation of signaling by CSF-1R 相似文献