纳米级铝阳极氧化膜的形成机理及结构调整

从纳米级阳极氧化铝(AAO)膜对应用的重要性入手，主要简述AAO膜的制备、形成机理、自结构特点及结构调整方法。     

锌对在PH不同的溶液中锑阳极成膜规律的影响

利用恒电位阳极极化电流与极化时间的关系、线性电位扫描法研究了锑锌合金在PH值不同的电解质溶液中于1.2V(30±0.1℃,vs.SCE)阳极成膜规律及膜相组成。讨论了锌掺入对在PH不同的溶液中锑阳极成膜规律的影响原因。     

GIS局部放电信号及内置传感器检测分析

气体绝缘组合电器(GIS)局部放电不仅激发横向电磁波(TEM),而且会激发横向电场波(TE)和横向磁场波(TM).利用电磁场中的并矢格林函数理论,推导出了GIS中PD信号在任意点激发瞬变电场的计算表达式,在计算GIS中PD激发的电场时,应考虑TEM波和检测频段内所有高次模波的贡献.在实验室GIS模拟装置上,设计了灵敏度及抗干扰能力优于外置传感器的内置传感器,并用天线模型对其进行了频率响应特性分析,最后直接用高参数数字存储示波器测量了由金属突出物缺陷产生的局部放电信号.     

渗硼金刚石薄膜电极用于有机废水降解的实验

为了研究渗硼金刚石薄膜电极电化学性能以及用于含有机污染物的废水处理的可行性,采用循环电解的方法,对含苯酚的废水进行了电化学氧化实验,同时与活性涂层钛阳极进行了对比实验研究,考察了阴极的可替代性,最后用两种电极对含苯胺的工业废水进行了对比实验。实验结果表明,金刚石电极不仅具有优越的电化学性能和优异的电化学指标,而且可以用于电化学废水处理;同时,用钛电极代替金刚石作阴极经济可行。     

用AAO模板及脉冲激光溅射制备量子点阵

 利用多孔阳极氧化铝(anodic aluminum oxide,AAO)作为模板,采用准分子脉冲激光溅射方法(pulsed laser deposition,PLD)成功制备了光荧光材料La_0.95Eu_0.05BaB₉O₁₆的量子点阵,用扫描电镜表征了AAO模板和制备的量子点阵,测量了靶材和量子点阵的光荧光谱.讨论了用此方法制备的量子点阵的结构和发光特性.证明此方法可为未来制备其它材料的量子点阵开辟了一条途径.     

超声速化学氧碘激光(SCOIL)性能计算的半气体动理学(SGK)模型

对超声速COIL的分析和计算, 提出了氧碘反应气流取连续介质近似, 同时计算碘激光能级粒子速度分布函数, 并用双参数摄动法求解粒子速度分布函数方程组的半气体动理学(SGK)模型, 得到与常用Voigt线型及低压极限饱和模型不同的增益饱和模型. 对预混合情况, 分析计算了不同化学反应系统、不同增益饱和模型以及诸可调参数(包括气流参数、激发态氧的产率、水含量、阈值增益、频移等)对功效的影响. 分析计算说明多个反应(包括21个)与选用单一共振反应的功效计算结果接近, 而增益饱和模型不同和可调参数的差别对功效、最佳阈值增益范围、功率提取长度均有显著的影响.     

Preparation and properties of antimony thin film anode materials

Metallic antimony thin films were deposited by magnetron sputtering and electrodeposition. Electrochemical properties of the thin film as anode materials for lithium-ion batteries were investigated and compared with those of antimony powder. It was found that both magnetron sputtering and electrodeposition are easily controllable processes to deposit antimony films with flat charge/discharge potential plateaus. The electrochemical performances of antimony thin films, especially those prepared with magnetron sputtering, are better than those of antimony powder. The reversible capacities of the magnetron sputtered antimony thin film are above 400 mA h g^-1 in the first 15 cycles.     

气候变暖是人自作自受

2003年夏天是欧洲500年来最热的一个夏天,有成千上万人被这个夏天出现的"超级热浪"夺去了性命,森林大火则毁灭了欧洲大面积的林地。可是现在看来,这多半是人类自作自受。一项最新的气候学研究表明。由人类产生的温室气体导致再次出现"超级热浪"的可能性增加了一倍。科学家通过计算机模拟发现,如果把人们在过去     

GMAW 温度场计算及其焊接质量的特征建模

根据传热学、流体力学、物理冶金等理论，在熔化极气体保护焊(GMAW)的三维非稳态熔池的数学模型基础上建立了有限元模型，并使用通用有限元软件ANSYS对熔池温度场进行了计算．通过熔宽和熔深的测量值与ANSYS计算值进行比较，误差均控制在8％以内，表明使用ANSYS来计算GMAW温度场是可靠和可行的．结合智能诊断的基本理论，还建立了GMAW焊接质量的人工神经网络预测模型，并且采用软件MATLAB6．1对模型进行计算．结果表明，模型与实际过程符合较好，对于非线性的焊接过程，神经网络的适应性较强．     

Leaching Mechanism of Complicated Antimony-Lead Concentrate and Sulfur Formation in Slurry Electrolysis

Anodic reaction mechanism of complicated antimony-lead concentrate in slurry electrolysis was investigated by the anodic polarization curves determined under various conditions. The main reactions on the anode are the oxidations of FeCln^(2-n) . Though the oxidation of jamesonite particle on the anode can occur during the whole process, it is less. With the help of mineralogy studies and relevant tests, the leaching reaction mechanism of jameson[to and gudmundite during slurry electrolysis was ascertained. Because of the oxidation reaction of FeCl3 produced by antimony-lead concentrate itself, the non-oxidation complex acid dissolution of jameson[re, the oxidation complex acid dissolution of gudmundite, and the oxidation of air carried by stirring, the leaching ratio of antimony reaches about 35% when HCl-NH4Cl solution is used to leach antimony-lead concentrate directly. So when the theoretical electric quantity is given to oxidation of antimony in slurry electrolysis, all of antimony, lead and iron containing in antimony-lead concentrate, are leached. The formation of sulfur is through the directly redox reaction of Fe^3 and jameson[re. The S^2- in jamesonite is oxidized into S^0 , and forms the crystals of sulfur again on the spot. The redox reaction of Fe^3 and H2S formed by non-oxidative acid dissolution of jamesonite is less.