铝对Fe—25Cr合金在H2S—H2混合气氛中高温硫化腐蚀的作用

研究了５％Ａｌ，１０％Ａｌ对Ｆｅ－２５Ｃｒ合金在Ｈ２Ｓ－Ｈ２平衡混合氛中７００～９００℃下高温硫化腐蚀行为。发现加Ａｌ能显著降低Ｆｅ－２５Ｃｒ合金的硫化速度并改变其硫化层的形貌、成分及结果。加Ａｌ合金的硫化动力学的孕育期后遵从抛物线规律。综合反应动力学、硫化层结构和成分分析。提出了Ｆｅ－Ｃｒ－Ａｌ合金的硫化机理。     

自生长Al2O3—Al复合材料的制造及形成机理研究

熔融态铝合金表面的Al_2O_3膜在一定工艺条件下可被破坏,由于毛细管作用,内部的金属液将沿着膜上的破缺处上升至表面并产生新的非致密氧化膜。该过程具有自组织特征,一定时间后可在液态合金表面形成一定厚度的自生长Al_2O_3-Al复合材料。材料中Al_2O_3含量可在20％-80％的范围内变化而其性能,尤其是硬度和抗拉强度可有较大提高。     

钢-铝固液相复合板界面层厚度建模

采用人工神经网络方法建立了钢－铝固液相复合中助焊剂质量分数,铝液温度,模具温度,压力与界面层厚度间的关系型,并结合最大剪切强度的复合工艺参数得出了钢－铝固液相压力复合的最佳界面界厚度的１０．０μｍ。     

煤矸石热活化和胶凝化过程中硅铝的配位

为了煤矸石综合利用,用红外谱图和固体核磁共振,研究煤矸石热处理及胶凝化过程中S i和A l的配位变化。研究表明,在煤矸石热活化和水泥制备过程中六配位的铝逐渐转变为四配位的铝。活化煤矸石胶凝化过程中,六配位的铝也逐渐转变为四配位铝,形成铝硅酸盐。水泥胶凝过程中,四配位铝逐渐转变为六配位的铝。通过热活化手段增加煤矸石中四配位铝含量可以提高煤矸石胶凝性能。     

一种制备不锈钢内衬复合钢管的新工艺

介绍了一种制备不锈钢内衬复合钢管的新型工艺－－ＳＨＳ－离心技术，讨论了所制备的复合管材的组织和不锈钢层的性能，这种不锈钢复合管的内外层可实现冶金结合。ＳＨＳ不锈负抗腐蚀性能优于相应的常规不锈钢，该工艺具有节能、高效、设备简单等优点。     

自激活自倍频Nd_xY_(1-x)Al_3(BO_3)_4复合功能晶体生长及光学特性

本文报导了自激活自倍频 Nd_xY_(1-x)Al_3(BO_3) _4复合功能晶体的生长,测量了该晶体的双折射率,计算了位相正配角和测定了该晶体的非线性系数。首次获得了该晶体从1. 06μm 到0. 53μm 受激发射和自倍频的激光运转。     

Interaction of catechins with aluminum in vitro

Tea is one of the most popular beverages, consumed by over two thirds of the world's population; but the aluminum accumulation property of tea plant is becoming the focus of many researches because of aluminum's known adverse effect on human health. Investigation of the interactions of catechins with Al(3+) showed that during the interaction of catechins with Al(3+), the UV-vis spectrum of catechins was changed. Absorption of EGCG at 274 nm decreased and increased at 322 nm; EC and C's at 278 nm changed little. The ratio of Al(3+) to EGCG was 1:1 in pH 5.0 buffer solution; in pH 6.2 buffer solution, the ratio in the Al-EGCG complex was 1:1. Interestingly, while the ratio reached to over 2, after the complex of Al-EGCG started polymerization, the ratio in the polymer was 2:1. In pH 6.2 buffer solution, the complex behavior of C with Al(3+) was the same as that of EGCG, with a little difference for EC. When the ratio of Al(3+) to EC was <1, the complex in ratio was 1:2, but, the complex polymerized when the ratio of Al(3+) to EC was >1. It was found that the ratio of Al(3+) to EC in the polymer was 1:1. Polymerization of Al-catechin complexes might reduce aluminum absorption in the intestine. Kow value was also employed to study the properties of aluminum species in tea infusion (at gastric and intestine pH condition) and the effect of catechins and tea polyphenols on Kow in buffer solution. Results showed that Kow value rose much higher at the intestine pH than at the gastric pH. Tea polyphenols and catechins could greatly reduce aluminum Kow value in acetic buffer, indicating that these compounds may reduce aluminum absorption during tea intake.     

HPAM／AlCit交联聚合物溶液微孔膜过滤行为研究

分别采用孔径为1．2μm醋酸纤维素树脂核微孔滤膜及2μm混合纤维素树脂热压滤膜,考察了HPAM／AlGit交联聚合物溶液在恒压并流微过滤条件下的微孔膜过滤行为。结果表明,随反应时间的延长,该交联聚合物溶液中交联聚合物线团的数目逐渐增加,对于核微孔滤膜,其封堵作用遵循表面过滤机理,侧重反映封堵过程中交联聚合物线团的粒子特性;而对于网络型热压滤膜,过滤实验中交联聚合物线团对滤膜的封堵作用逐步由深度过滤过渡到表面过滤,侧重反映交联聚合物线团封堵非均—孔径滤膜所具有的非均匀封堵特征,即遵循大孔到中孔到小孔的封堵过程。     

球墨铸铁热浸镀铝的抗氧化性

为了延长铸铁工件的使用寿命,采用熔剂法将墨铸铁热浸镀铝,对镀层截面进行了形貌观察(SEM)、能谱分析(EDS)和衍射分析(XRD),测试了镀层的抗氧化性.结果表明,镀层由表面富铝层及扩散层构成,富铝层包含降温形成的针状FeAl3相,扩散层由FeAl3,Fe2Al5 物相组成,其形态呈舌状,并嵌入基体;氧化时镀层全部转变为扩散层,并能保持非常缓慢的退化速度,使球墨铸铁的抗氧化性显著提高.