Preparation of Zn-doped TiO2 nanotubes electrode and its application in pentachlorophenol photoelectrocatalytic degradation

Zn-doped titanium oxide （TiO2） nanotubes electrode was prepared on a titanium plate by direct anodic oxidation and immersing method in sequence. Field emission scanning electron microscopy （FESEM） showed that the Zn-doped TiO2 nanotubes were well aligned and organized into high density uniform arrays with diameter ranging from 50 to 90 nm. The length and the thickness were about 200 and 15 nm respectively. TiO2 anatase phase was identified by X-ray diffraction （XRD）. X-ray photoelectronspectroscopy （XPS） indicated that Zn ions were mainly located on the surface of TiO2 nanotubes in form of ZnO clusters. Compared with TiO2 nanotubes electrode, about 20 nm red shift in the spectrum of UV-vis absorption was observed. The degradation of pentachlorophenol （PCP） in aqueous solution under the same condition （initial concentration of PCP： 20 mg/L; concentration of Na2SO4：0.01 mol/L and pH： 7.03） was carried out using Zn-doped TiO2 nanotubes electrode and TiO2 nanotubes electrode. The degradation rates of PCP using Zn-doped TiO2 nanotubes electrode were found to be twice and 5.8 times as high as that using TiO2 nanotubes electrode by UV radiation （400 μw/cm^2） and visible light radiation （4500 μw/cm^2）, respectively. 73.5% of PCP was removed using Zn-doped TiO2 nanotubes electrode against 45.5% removed using TiO2 nanotubes electrode in 120 min under UV radiation. While under visible light radiation, the degradation efficiency of PCP was 18.4% using Zn-doped TiO2 nanotubes electrode against 3.2% using TiO2 nanotubes electrode in 120 min. The optimum concentration of Zn doping was found to be 0.909%. The PCP degradation efficiencies of the 10 repeated experiments by Zn-doped TiO2 nanotubes electrode were rather stable with the deviation within 3.0%.     

轻骨料混凝土综述

本文介绍了轻骨料混凝土的概念,以及根据砂的种类、骨料的堆积密度和颗粒强度、骨料的来源等的分类,论述了轻骨料混凝土所具有的轻质高强、保温性好、耐火性能好、抗震性能好、耐久性好、综合经济效益好等特点,阐述了轻骨料混凝土的研究和应用情况。     

磁场对耦合双量子盘中类氢杂质性质的影响

在有效质量近似下,采用简单的变分波函数,定量计算了无限深对称GaAs/AlGaAs耦合双量子盘在沿轴向不同强度磁场的作用下,类氢杂质体系的基态束缚能随量子盘的半径、中心垒厚、盘厚度的变化.发现,体系束缚能由空间限制作用和磁场限制作用共同决定:在空间限制比较弱时磁场强度对束缚能的影响变得更加明显,当空间限制强时磁场对束缚能的影响变得微弱.还发现,由于2个量子盘间的耦合作用使耦合双量子盘的结果比单量子盘结果偏小.在耦合双量子阱的极限条件下所得的结果与前人的结果符合得很好.     

双黑格斯二重态模型Ⅲ中的τ-→μ-K+K-衰变研究

τ轻子物理是粒子物理的研究热点之一.在标准模型中,轻子数是守恒的.而τ-→μ-K K-衰变属于轻子味破缺过程,在标准模型中是禁戒的.大气中微子振荡实验意味着存在轻子味破缺,这是标准模型无法解释的.     

Characterization of impurities in the bulk drug lisinopril by liquid chromatography/ion trap spectrometry

Two trace impurities in the bulk drug lisinopril were detected by means of high-performance liquid chromatography coupled with mass spectrometry （HPLC/MS） with a simple and sensitive method suitable for HPLC/MSn analysis. The fragmentation behavior of lisinopfil and the impurities was investigated, and two unknown impurities were elucidated as 2-（6-amino- l-（l-carboxyethylamino）- l-oxohexan-2-ylamino）-4-phenylbutanoic acid and 6-amino-2-（l-carboxy-3-phenylpropylamino）-hexanoic acid on the basis of the multi-stage mass spectrometry and exact mass evidence, The proposed structures of the two unknown impurities were further confirmed by nuclear magnetic resonance （NMR） experiments after preparative isolation.     

黄色荧光粉Sr3SiO5:Eu2+相转变机理简

高温固相法合成Sr3 SiO5：Eu2＋过程中,杂质相Sr2 SiO4：Eu2＋的存在会不同程度影响Sr3 SiO5：Eu2＋的光致发光性能及余辉性能。本文通过压片烧结和燃烧法两种方法制备Sr3 SiO5：Eu2＋,结合热重-差热分析和X射线衍射分析,研究了Sr3 SiO5：Eu2＋在合成过程中的相变化规律以及动力学过程。研究表明：原料与坩埚的接触处形成的界面以及原料在升温过程经过Sr2 SiO4：Eu2＋的合成温度区间是导致杂质相产生的主要原因。在升温过程中,当温度经过1200℃左右的温度区间时,由于原料与坩埚接触处可以看作是两组不同物质的分界面,Sr2 SiO4：Eu2＋的合成首先在该分界面处合成,而更多的原料需要扩散通过生成物层才能进一步反应;但随着温度的升高,原料随后进入Sr3 SiO5：Eu2＋的合成过程,从而导致了Sr2 SiO4：Eu2＋杂质相的生成。     

量子阱中不同支声子模对杂质态能量的影响

在量子阱材料中，同时考虑体声子和界面声子模对受主杂质态能级的影响，给出了受主杂质态基态结合能和不同支声子模对能量的贡献随阱宽变化的数值结果。结果表明，阱宽较大时，体声子模的作用比界面声子模的作用大，阱宽较小时，界面声子模的作用比体声子模的作用大，而整个电子－声子相互作用随阱宽的增大而减小。     

BTEX在非饱和土和地下水系统中迁移的试验研究

为了解污染物在土壤中迁移的规律,利用BTEX模拟轻非水相污染物质,采用土工离心试验技术对BTEX在非饱和土和地下水系统的迁移过程进行模拟。采用气相色谱分析试验中土样和水样的污染物质量分数,得到了BTEX的时空分布特征和长期迁移规律。试验结果表明,BTEX从泄漏点通过非饱和土层向下运移,在地下水位之上形成高质量分数区,并沿地下水面侧向迁移,部分溶解的BTEX在水体扩散。地下水的流动对BTEX的迁移有一定影响。     

型钢轻骨料混凝土梁抗剪承载力计算

针对斜剪破坏和剪切粘结破坏两种破坏模式,研究了型钢轻骨料混凝土梁抗剪承载力。考虑型钢和混凝土界面存在的粘结力,推导了剪切粘结破坏抗剪承载力计算公式。结合型钢混凝土结构技术规程中型钢普通混凝土梁斜截面抗剪承载力计算公式,提出了型钢轻骨料混凝土梁抗剪承载力预测模型。试验结果比较和验证表明,该预测模型不仅具有足够的精度,而且也适用于型钢普通混凝土梁。     

二甘双酰氮甲基苯胺(L)稀土高氯酸盐配合物的合成及表征

在非水介质中合成了5种轻稀土高氯酸盐与配体二甘双酰氮甲基苯胺形成的固体配合物,通式为[Ln(L)2(H2O)2](ClO4)3(Ln=La,Pr,Nd,Sm或Eu).用元素分析、摩尔电导、红外光谱、核磁共振和TG-DTA分析对这些配合物进行了表征.结果表明,在这些新配合物中,配体L表现为三齿配位行为.