铁氰化钴/铁复合膜修饰电极的制备及应用

采用电化学方法制备了铁氰化钴/铁(Fe/CoHCF)复合膜修饰电极,研究了该修饰电极的电化学性质及其电催化活性,实验表明该复合物不是铁氰化钴与普鲁士蓝(PB)的简单混合物,而是钴、铁共沉积形成的多核铁氰化物.该修饰电极对H2O2具有良好的电化学响应,安培法测定H2O2的线性范围为5.0×10 7～3.7×10 3mol.L 1,检测限(3sb,n=11)为2.0×10 7mol.L 1,灵敏度为44.5μA.(mmol.L 1)1.该法已用于模拟水样中H2O2含量的测定,结果满意.     

CdS,ZnO1-xSx电子结构和光学特性的第一性原理研究

 采用基于密度泛函理论(DFT)框架下广义梯度近似(GGA)的PBE平面波超软赝势方法,研究了闪锌矿型CdS和ZnO_1-xS_x(x=0,0.25,0.5,0.75,1)的电子结构和光学特性.计算并分析了闪锌矿型CdS和ZnO_1-xS_x的复介电函数、光电导率、吸收系数和损失函数.研究结果表明,闪锌矿型CdS和ZnO_1-xS_x(x=0,0.25,0.5,0.75,1)均为直接带隙半导体材料.ZnO中一定浓度的硫掺杂,导致带隙宽度变窄,而晶格常数随掺杂基本呈线性变化.就目前制备铜铟镓硒(CIGS)薄膜太阳能电池普遍使用CdS缓冲层而言,ZnO_1-xS_x具有与CdS类似的电子结构,但光学特性上高频特性有明显改善.这些特性对于改善电池吸收层表面性能和光吸收特性、制备高效CIGS薄膜太阳能电池非常有利.     

航空成像光谱的蚀变信息提取技术

 根据成像光谱仪CASI/SASI的影像特点,制定了高光谱影像的处理方法流程,介绍了各步骤的内容和需要注意的事项.阐述了噪声和坏波段去除、大气校正的过程,并提出了一些经验性的处理方法.在成像光谱岩石蚀变提取算法中,根据经验对已有方法进行了改进;在基于特定算法的矿物填图方法中,依据柯坪地区CASI影像中富含二价铁的辉绿岩脉的光谱特征,提出了富二价铁岩石提取算法.经过实地验证,富二价铁岩石的提取对铀矿勘探具有较好的指导作用.通过提取的信息结果与已经矿区或矿点的空间叠加分析发现,富二价铁岩石空间分布与铀异常点分布有很强的相关性.根据富二价铁与铀矿的空间分布规律,提出了断裂+富二价铁岩石的成矿模式.红色砂岩提供铀源,岩脉提取铀成为存储容器.富二价铁岩石提供铀沉淀催化剂的作用,且线性的富二价铁岩石分布区域对成矿更有利.通过富二价铁岩石的提取,在柯坪南部地区新发现了3条铀异常带.     

一种解决调频连续测距中测距模糊方法

通过对锯齿调频连续测距系统的差频信号分析可知,由于观测时间的随机性导致同一距离上对应两个不同的差频频率。对差频信号进行时域和频域分析发现,利用两次混频的方法能够解决这种测距模糊问题,使信号处理单元的输出信号频率和距离一一对应。利用仿真软件,得到信号处理过程中的时频关系曲线,验证了这种信号处理方法的有效性。     

基于R/S分析的城市可持续发展定量评价

根据城市可持续发展理论,利用R/S分析原理和方法,从城市的生产、生活和生态3个方面讨论了山西省太原市在2003～2007年期间的可持续发展的现状和发展潜力对未来一段时间的可持续发展的影响。为决策者提供科学可行的依据和方法。     

A gas chromatography/mass spectrometry method for the simultaneous analysis of 50 phenols in wastewater using deconvolution technology

Phenolic compounds exist widely in the influents and effluents of sewage treatment plants (STPs) and most are un-regulated. In this study, a gas chromatography-mass spectrometry (GC-MS) method for the simultaneous analysis of 50 phenolic compounds in wastewater was developed. Deconvolution technology was used to identify contaminants that are covered by co-extracted materials. A mass spectral library containing all 50 silylated phenolic compounds was first established and used for deconvolution. Twelve typical phenolic compounds were selected to optimize the sample preparation procedures. Solid-phase extraction using a C18 cartridge coupled with an HLB cartridge was used for pre-concentration and dichloromethane was used for elution. The solutes were derivatized and analyzed by GC-MS. The blank and matrix spike recoveries ranged from 57.46% to 136.4% and 47.87% to 114.8%, respectively. Method detection limits ranged from 3.64 to 97.64 ng L⁻¹. The relative standard deviations of all the recovery experiments were lower than 13.6%. The instrument limits of quantification ranged from 0.7 to 87.7 pg. The method has been applied to analyze the influents and effluents of 5 Chinese STPs. Except for regulated phenolic compounds (phenol and 2,4,6-trichlorophenol), three un-regulated phenolic compounds, including 2-chlorophenol, 2,5-dichlorophenol and 2,4-dichloro-3-ethyl-6-nitrophenol were identified in the effluent wastewater. The detected concentrations of un-regulated phenolic compounds could possibly cause environmental effects, indicating that immediate attention is required to prevent complications.     

Evaluation of humic acid removal by a flat submerged membrane photoreactor

A flat submerged membrane combined with a TiO 2 /UV photocatalytic reactor (FSMPR) was employed in batch mode to remove humic acid (HA). HA removal efficiency was characterized by UV 254 absorbance, UV-vis spectra, dissolved organic carbon (DOC) concentration, specific UV absorbance (SUVA), and trihalomethane formation potential (THMFP). The FSMPR process was effective in removing more than 86% of DOC and nearly 100% of UV 254 absorbance, while the THMFPs of samples were reduced to < 19 μ g/L after 150 min of treatment. In addition, changes in transmembrane pressure (TMP) with and without UV were evaluated; TiO 2 /UV was effective at controlling membrane fouling by HA. Analysis of the molecular weight (MW) distributions and three-dimensional excitation-emission matrix (EEM) fluorescence spectra of HAs revealed that the effectiveness in membrane fouling control is a result of changes in HA molecular characteristics. The TiO 2 /UV photocatalytic reactor caused the degradation of high MW, hydrophobic humic-like molecules to low MW, hydrophilic protein-like molecules, although this fraction was not completely removed during 150 min of treatment and was less responsible for membrane fouling.     

云南省L波段雷达运行监控平台的设计与实现

基于B/S(Browser/Server结构)模式开发的云南省L波段雷达运行监控平台,有效地实现了云南省5部L波段雷达的探空设备和探空数据的监控.整个平台由FTP计划任务、数据录入系统和L波段雷达运行监控系统3部分组成.运行情况表明,该平台的建立有助于全面掌握我省探测网系统设备的运行状况,保障高空探测网的稳定运行,提高了气象探空数据的数据质量.     

海洋有害赤潮调控功能菌的发现与研究

近年来,赤潮的微生物调控研究受到了科学界的高度重视,"以菌治藻"的赤潮调控理念格外引人注目.先从国内外抑/杀藻菌及其作用方式的研究进展进行论述,再结合本课题组近年来筛选获得的海洋抑/杀藻细菌,探讨该类菌质资源的发掘与利用,最后对该领域研究进行了展望.     

不同生活习性下原核生物基因组大小与GC含量的关系研究

 对原核生物基因组的研究显示,基因组GC含量与基因组大小和氧气偏好性等因素存在着一定的相关性。为了探索基因组大小与GC含量的相关性是否受原核生物生活习性的影响,选取了有代表性的411种原核生物（包括古细菌与真细菌）,分别从最适生长温度、氧气偏好性、运动特性、水生特性和寄生特性等因素进行分析,发现基因组大小与GC含量的相关性确实受这些因素的影响,而寄生原核生物中显示出最好的相关性。