平面汞膜电极恒电位阳极溶出极限电流方程式的推导和实验验证

本文推导出膜电极恒电位阳极溶出极限电流方程式,以平面厚汞膜电极对该式进行了实验验证。实验结果与理论式基本相符。     

新型全固态铁离子敏感电极研究

采用稀土电极材料六硼化镧制备了一种新的全固态铁离子敏感电极。研究了该敏感电极在常见介质中对Ｆｅ３＋的响应行为。结果表明，该铁离子敏感电极在１．５ｍｏｌ／ＬＨ３ＰＯ４介质中的线性响应范围、检测下限和响应斜率分别为１．０×１０－５～１．０×１０－１ｍｏｌ／ＬＦｅ３＋，６．０×１０－６ｍｏｌ／ＬＦｅ３＋和６０ｍＶ／ｐＣ，且具有较好的选择性。     

Studies of Several Systems with Air Electrode Electro-Synthesizing H2O2 on the Spot for Degrading Aniline in Aqueous

A gas diffusion electrode (air electrode) with a high current efficiency of electro-synthesizing H2O2 using O2 in air was prepared. The several systems with air electrode as cathode of electro-synthesizing H2O2 on the reaction spot for degrading aniline in aqueous--electro-Fenton system, photo-excitation electro-H2O2 system and photo-electro-Fenton system, were developed. The rates of decomposition of H2O2 and mineralization of aniline were experimentally measured respectively under different conditions, and the results indicated there has an excellent parallel relation between decomposition rate of H2O2 and mineralization rate of aniline. Especially, photo-electro-Fenton system, where H2O2 is decomposed the fastest, is the best system of oxidizing and degrading organic toxicants. Compared photo-electro-Fenton system with photo-Fenton system, important role is revealed in the interface of air electrode. In this paper, the mineralization mechanism of aniline in the photo-electro-Fenton system was also discussed.     

L-半胱胺酸自组膜修饰电极的制备及其电化学行为的研究

将L-半胱胺酸修饰到金电极表面,通过循环伏安法、阻抗法进行表征。在pH低时,高频部分的半圆的半径较pH高时的要大,其原因可能跟探针离子与L-半胱胺酸的静电作用有关。     

负极添加剂CoO对储氢合金电极性能的影响

负极添加剂CoO在储氢金合金颗粒表面形成的Co膜有助于抑制合金粉的表面氧化和成分的偏析，进而减少电解液的损耗，因而有助于储氢合金负极和电池性能的提高。本文从电池内阻和容量衰减角度考察了CoO对电池循环寿命的影响。并以溶解——沉积理论为基础，利用循环伏安研究分析了CoO对储氢合金的保护机理。     

发射光谱定量分析光学玻璃中As、Pb、Hg、Cu元素

本方法对光学玻璃进行直接光谱定量分析,实验采用直接固体试样、垂直电极、光流电弧摄谱,标样与试样基本成份一致,消除了干扰。方法快速,准确,灵敏,简便,并同时测定多项元素。     

广谱型C60修饰电极电位传感器的研究

吸附型Ｃ６０修饰玻碳电极可作为一种广谱响应的电位传感器，对十余种无机及有机季铵盐阳离子，其电位－浓度对数值呈一定的线性关系，该电极制备方便、响应速度快，稳定性好。本文还从电极表面Ｃ６０晶型结构出发，对电极的响应机理进行了初步探讨。