Angular dependent NEXAFS study of the molecular orientation of PTCDA multilayers on Au （111） surface

The molecular orientation of perylene-3,4,9,10-tetracarboxylic acid dianhydride (PTCDA) multilayers adsorbed on Au (111) surface has been investigated using angular dependent O K-edge near edge X-ray absorption fine structure (NEXAFS) spectroscopy. The significant angular dependence of important resonant structures (π* and σ*) reveals that PTCDA molecules adopt an ordered geometry on the substrate surface. The average tilt angle of the PTCDA molecular planes is 27°±10° from the Au (111) surface.     

Evaluation of humic acid removal by a flat submerged membrane photoreactor

A flat submerged membrane combined with a TiO 2 /UV photocatalytic reactor (FSMPR) was employed in batch mode to remove humic acid (HA). HA removal efficiency was characterized by UV 254 absorbance, UV-vis spectra, dissolved organic carbon (DOC) concentration, specific UV absorbance (SUVA), and trihalomethane formation potential (THMFP). The FSMPR process was effective in removing more than 86% of DOC and nearly 100% of UV 254 absorbance, while the THMFPs of samples were reduced to < 19 μ g/L after 150 min of treatment. In addition, changes in transmembrane pressure (TMP) with and without UV were evaluated; TiO 2 /UV was effective at controlling membrane fouling by HA. Analysis of the molecular weight (MW) distributions and three-dimensional excitation-emission matrix (EEM) fluorescence spectra of HAs revealed that the effectiveness in membrane fouling control is a result of changes in HA molecular characteristics. The TiO 2 /UV photocatalytic reactor caused the degradation of high MW, hydrophobic humic-like molecules to low MW, hydrophilic protein-like molecules, although this fraction was not completely removed during 150 min of treatment and was less responsible for membrane fouling.     

Changes in physical features of Glacier No. 1 of the Tianshan Mountains in response to climate change

This study analyzes the changes in glacier zones and snow composition of Glacier No.1 in the Tianshan Mountains of China since 1961,and their possible relations with climate.It is found that precipitation dominated the snow composition and that air temperature and precipitation controlled the distribution of glacier zones,but interannual change in precipitation had a relatively large effect on glacier zones and snow composition during 1963–1981 (P10) and 1963–1989 (P11).However,during 1982–2007 (P20) and 19...     

Preparation of three-dimensionally ordered macroporous perovskite materials

In this paper,we use La0.8Sr0.2MnO3 and La0.7Ca0.2Sr0.1MnO3 as examples to demonstrate a preparation method for threedimensionally ordered macroporous(3DOM) perovskite thermochromic materials.Polystyrene spheres with an average diameter of 220 nm were self-assembled into a three-dimensionally ordered colloidal crystal template.A mixed metal nitrate solution prepared using La(NO3) 3·6H2O,Ca(NO3) 2·4H2O,Sr(NO3) 2,Mn(CH3COO) 2·4H2O and an ethanol precursor was used to fill the interstitial voids of the polystyrene colloidal crystal templates.3DOM La0.8Sr0.2MnO3 and La0.7Ca0.2Sr0.1MnO3 materials were then obtained after the sphere templates were removed via drying and calcination.The results show that the framework of the 3DOM materials can have different thicknesses and pore shrinkage rates by varying the filling times.In addition,the Curie temperatures of the 3DOM and bulk La0.8Sr0.2MnO3 materials can be varied by altering the preparation method.     

K2O对氧化物原料合成Al8B4C7的影响

采用硼砂、金属铝和碳粉为原料一步合成Al8B4C7.在合成过程中掺入不同含量的K2O,研究杂质K2O对合成Al8B4C7的影响.将原料混合均匀,在200MPa的压力下压制成φ20mm×20mm的圆柱型试样,将干燥后的试样在不同温度下的流动氩气气氛中进行合成.利用化学分析、XRD和SEM等分析测试技术,研究了K2O含量以及烧结温度对反应合成材料物相组成和显微结构的影响.结果表明:尽管加入不同含量的K2O,但其高温烧结反应后,若K2O的质量分数在0.019%～0.028%之间,就不出现含K的新相.K2O的加入不利于Al8B4C7的合成,它可将Al8B4C7的开始生成温度提升至1 400℃,而且1 700℃时,Al8B4C7含量较不加入K2O时明显减少.添加K2O合成的Al8B4C7为1μm左右大小的无规则小颗粒.     

云南省L波段雷达运行监控平台的设计与实现

基于B/S(Browser/Server结构)模式开发的云南省L波段雷达运行监控平台,有效地实现了云南省5部L波段雷达的探空设备和探空数据的监控.整个平台由FTP计划任务、数据录入系统和L波段雷达运行监控系统3部分组成.运行情况表明,该平台的建立有助于全面掌握我省探测网系统设备的运行状况,保障高空探测网的稳定运行,提高了气象探空数据的数据质量.     

3GPP-LTE系统下行链路S-SCH检测算法的低复杂度实现

小区搜索是3GPP-LTE移动通信系统中的重要过程,研究了此过程中下行链路辅同步信道（S-SCH）的检测问题,指出了接收机在采用最大似然序列检测（MLSD）算法进行S-SCH检测时,具有较高的计算复杂度.给出了一种基于MLSD准则S-SCH检测算法的低复杂度实现方法,利用S-SCH序列的结构特点,缩小候选S-SCH序列...     

海洋有害赤潮调控功能菌的发现与研究

近年来,赤潮的微生物调控研究受到了科学界的高度重视,"以菌治藻"的赤潮调控理念格外引人注目.先从国内外抑/杀藻菌及其作用方式的研究进展进行论述,再结合本课题组近年来筛选获得的海洋抑/杀藻细菌,探讨该类菌质资源的发掘与利用,最后对该领域研究进行了展望.     

不同生活习性下原核生物基因组大小与GC含量的关系研究

 对原核生物基因组的研究显示,基因组GC含量与基因组大小和氧气偏好性等因素存在着一定的相关性。为了探索基因组大小与GC含量的相关性是否受原核生物生活习性的影响,选取了有代表性的411种原核生物（包括古细菌与真细菌）,分别从最适生长温度、氧气偏好性、运动特性、水生特性和寄生特性等因素进行分析,发现基因组大小与GC含量的相关性确实受这些因素的影响,而寄生原核生物中显示出最好的相关性。     

纳米CaCO3 对物理老化前后PC/PS性能的影响

 通过差示扫描量热法和动态力学分析对PC/PS/纳米CaCO3和PC/PS/包覆纳米CaCO3复合材料物理老化前后PS相的玻璃化转变、β松弛及动态力学性能进行了研究。结果表明：纳米CaCO3有利于PS相的分子链段松弛运动,PC/PS/纳米CaCO3复合材料PS相的Tg、损耗模量峰温和β松弛温度下降;包覆纳米CaCO3增加相界面间相互作用,PC/PS/包覆纳米CaCO3复合材料PS相的Tg、β松弛温度、储存模量和损耗模量峰温均较PC/PS/纳米CaCO3提高。随着物理老化时间的延长,PC/PS及复合材料PS相的Tg和β松弛温度提高,松弛热焓ΔH增加,其中,PC/PS/包覆纳米CaCO3的提高幅度较小。物理老化使得PC/PS/纳米CaCO3的存储模量提高。