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981.
ZENGXiaomei SHIXiaobing SHENYungang 《科学通报(英文版)》2004,49(3):258-262
The ε subunit of the chloroplast ATP synthase and the truncated ε mutants which lack some amino acid residues from the N-terminus or C-terminus were overexpressed in E. coil When the ε subunit or the truncated ε proteins was added to the spinach chloroplast suspension, both the intensity of the fast phase of millisecond delayed light emission (ms-DLE) and the cyclic and noncyclic photophosphorylation activity of chloroplast were enhanced. With an increase in the number of residues deleted from the N-terminus, the enhancement effect of the N-terminal truncated proteins decreased gradually. For the C-terminal truncated proteins, the enhancement effect increased gradually with an increase in the number of residues deleted from the C-terminus. Besides, the ATP synthesis activity of ε-deficient membrane reconstituted with the ε subunit or the truncated ε proteins was compared. The ATP synthesis activity of reconstituted membrane with the N-terminal truncated proteins decreased gradually as the number of residues deleted from the N-terminus increased. For the C-terminal truncated proteins, the ATP synthesis activity of reconstituted membrane increased gradually with an increase in the number of residues deleted from the C-terminus, but was still lower than that of the wild type ε protein. These results suggested that: (a) the N-terminal domain of the ε subunit of the chloroplast ATP synthase could affect the ATP synthesis activity of ATP synthase by regulating the efficiency of blocking proton leakage of ε subunit; and (b) the C-terminal domain of the ε subunit of the chloroplast ATP synthase had a subtle function in modulating the ATP synthesis ability of ATP synthase. 相似文献
982.
ZHUDa MAZhongyuan MEIJiaxin HANPeigao HUANGXinfan CHENKenji 《科学通报(英文版)》2004,49(18):1906-1910
A series of hydrogen-containing a-Si:H/SiO2 multilayers with different a-Si:H sublayer thickness were fabricated by layer-by-layer deposition and in situ plasma oxidation in a plasma-enhanced chemical vapor deposition system (PECVD). Optical induced blue emission from the samples was observed by the naked eye at room temperature, which has never been reported in the luminescence study of Si/SiO2 multilayers up to now. Both the photoluminescence (PL) peak and the absorption edge show a blue shift as the a-Si:H sublayer thickness decreases. The origin of the blue emission and the effect of hydrogen are discussed. 相似文献
983.
LI Fashen WANG Tao REN Liyuan & SUN Jianrong Key Laboratory for Magnetism Magnetic Materials of the Ministry of Education Lanzhou University Lanzhou China 《科学通报(英文版)》2004,49(14):1532-1535
It is important to find some developing high-density magnetic recording materials in magnetic recording field with the development of information and technique, in which vertical magnetic recording is a very important way and has received considerable attention[1—3]. The vertical magnetic recording materials require high squareness, suitable coercivity, and small size of storage element[4]. Someone used nanoporous anodic aluminum oxide as templates to fabricate uniform arrays of multi magneti… 相似文献
984.
超级电容器电极材料纳米α-MnO2的制备及性能研究 总被引:6,自引:1,他引:5
用溶胶-凝胶法和沉淀法制备了具有纳米结构的α-MnO2,分别对其进行X-射线衍射(XRD),扫描电镜(SEM),循环伏安(CV)等测试,结果发现溶胶-凝胶法所合成的材料是由粒径为60nm的微粒组成,沉淀法所合成的材料粒径在80nm范围,并研究了不同配比的α-MnO2和活性炭组成的复合电极在各种浓度的电解液中的循环伏安性能,发现当电极中α-MnO2质量百分含量为40%-60%时,在0.5mol/L Na2SO4,2.0mol/L(NH4)2SO4,1.0mol/L,KCl溶液中的比电容较高,其中在2.0mol/L(NH4)2SO4溶液中的比电容最高可达108.26F/g. 相似文献
985.
JIANGYanxia CHENWei LIAOHonggang JINLanying SUNShigang 《科学通报(英文版)》2004,49(15):1581-1585
Dispersed Pd nanoparticles (Pdn) have been synthesized by reducing H2PdCI4 with ethanol, and stabilized using poly(vinylpyrrolidone) (PVP). The Pdn is applied to the glassy carbon substrate to form a thin film, and then the potential cyclic scanning at 50 mV.s^-1 from -0.25 to 1.25 V was carried out for about 30 min to form the aggregations of Pdn (Pdn^ag). FTIR spectroscopy of both transmission and reflection modes was employed to study CO adsorption on Pdn and Pdn^ag in both solidlliquid and solidlgas interfaces. It has been revealed that CO adsorption on Pdn film yields two IRbands near 1964 and 1906 cm-1, which are assigned to IR absorption of CO bonded on asymmetric and symmetric bridge sites, respectively. In contrast to the IR properties of CO adsorbed on Pdn, only species of CO bonded on asymmetric bridge sites was determined on Pdn^ag, and the direction of the IR band near 1963 cm^-1 is completely inverted. The full width at half-maximum (FWHM) of the COB^as band near 1964 cm^-1 is measured to be 14 cm^-1 on Pdn film, while it is 24 cm^-1 on Pdn^ag film. The results of the present study demonstrated that the inverting of the IR band direction is a general phenomenon that is closely related to the interaction between nanoparticles in aggregation of Pdn. 相似文献
986.
987.
介绍纳米晶软磁合金的各向异性理论及FINEMET、NANOPERM、HITPERM等3种典型纳米晶软磁材料的研究进展,对于高温条件下使用的Fe Co基纳米晶软磁合金进行了讨论及展望. 相似文献
988.
本文提出应用具有灵敏度高、分辨率好、峰高易于准确测量等特点的汞膜电极阳极溶出半微 分电析法进行各种纯水和一些常见支持电解质中痕量重金属杂质的测定方法,并探索通过巯基棉 等分离方法对试剂进行提纯的效果. 实验表明:对于水样只要加入几滴盐酸,使其pH=2.5左右即可进行测定,对于一些纯试剂 可直接进行测定,不必加入其他支持电解质,避免沾污。测定方法十分简便。 利用巯基棉除去一些试剂中痕量铜铅等杂质,进行试剂提纯,方法简便,效果良好。 相似文献
989.
为了研究淬火速度及Mn掺杂对纳米复合Nd-Fe-B磁性材料微结构的影响,利用XAFS技术对不同淬火速度的Nd9Fe84.5B6Mn0.5样品及退火和未退火的Nd9Fe84.5B6Mn0.5(x-0.5和1.0)样品,进行了Fe原子局域结构的分析。结果表明,纳为复合Nd9Fe84.5B6Mn0.5噘性材料随着淬火速度的增另,Fe原子的最近邻配位距离单上,而配位无序度的变化较为复杂。退火前,掺杂微量Mn原子进入磁体的Nd2Fe14B主相晶体结构,掺杂量不同对主相局域结构的影响有明显差异。退火后,Mn原子退出磁体的主相结构,进入晶界或产生富集,没有发现掺杂量不同对主相局域 结构的影响,但对整个磁体的磁性仍然有不同的影响。 相似文献
990.
用纳米技术诊断与治疗恶性肿瘤的进展 总被引:1,自引:0,他引:1
利用纳米技术进行恶性肿瘤早期诊断和治疗是目前国际生物技术领域中最前沿的研究课题,迄今实验室细胞模型(in vitro)研究和临床前动物模型(in vivo)研究已取得了重大进展.纳米生物技术将成为继放疗、化疗和手术治疗后治疗基因疾病的更有效的方法.纳米生物技术涵盖纳米材料科学,构成纳米药物载体平台的纳米材料与药物或基因结合的组装技术以及随后与靶向物质结合的组装技术.目前,实现了纳米生物传感器在肿瘤细胞上的表达,纳米基因药物能够抑制肿瘤细胞的增殖、诱导肿瘤细胞凋亡,但在临床治疗之前为了确保安全、有效,首先应该研制出针对癌细胞表面配位子特意性更强的靶向物质,以减少对正常组织的损害;此外,还需提高纳米材料药物的装载量和稳定性,并研制出适宜的纳米材料以及相应的制备技术. 相似文献