新型环氧类扩链剂合成

通过悬浮聚合的方法,将苯乙烯与甲基丙烯酸缩水甘油酯共聚,制备了一种新型的环氧类扩链剂.通过红外光谱法确定了产品的分子结构,热分析结果表明苯乙烯-甲基丙烯酸缩水甘油酯具有较好的热稳定性.环氧当量测定及粘度测定结果表明新型环氧类扩链剂应用性能与巴斯夫公司市售的环氧类扩链剂4360S以及4370S基本相同,但在经济性方面明显优于以上两种产品,表明所制备的环氧类扩链剂具有良好的市场前景及市场竞争力.     

某旧住宅楼阳台新修塑料地漏时防渗漏处理

介绍了在旧混凝土-新混凝土-塑料地漏的接合面和塑料地漏附近的楼板面涂敷环氧胶粘剂的方法来防止某旧住宅楼阳台新修塑料地漏时出现渗漏.实践表明:该法简便,易于工程实践,效果良好.     

水溶性环氧底漆的工艺及推广应用

通过ＭＩＬ－Ｐ－８５５８２Ｂ水溶性环氧底漆在Ｓ－９２尾斜梁铝合金、复合材料零部件上的应用，介绍了水深性环氧底漆的工艺及推广应用。     

Adhesion of PBO Fiber in Epoxy Composites

The high mechanical and thermal performance of poly p-phenylene- 2, 6-benzobisoxazole ( PBO ) fiber provides great potential applications as reinforcement fibers for composites. A composite of PBO fiber and epoxy resin has excellent electrical insulation properties, therefore, it is considered to be the best choice for the reinforcement in high magnetic field coils for pulsed magnetic fields up to 100 T.However, poor adhesion between PBO fiber and matrix is found because of the chemically inactive and/or relatively smooth surface of the reinforcement fiber preventing efficient chemical bonding in the interface, which is a challenging issue to improve mechanical properties. Here, we report the surface modification of PBO fibers by ultraviolet (UV)irradiation, O2 and NH3 plasma, as well as acidic treatments. The interfacial adhesion strength values of all the treatments show the similar level as determined for aramid fibers by pull-out tests, a significant impact on fibermatrix-adhesion was not achieved. The surface free energy and roughness are increased for both sized and extracted fibers after plasma treatments together with maleic anhydride grafting. The sized fiber shows marginal improvement in adhesion strength and no change in fiber tensile strength because of the barrier effect of the finish.For the extracted fiber, different surface treatments either show no apparent effect or cause reduction in adhesion strength. Atomic force microscopy (AFM) topography analysis of the fracture surfaces proved adhesive failure at the fiber surface. The fiber surface roughness is increased and more surface flaws are induced, which could result in coarse interface structures when the treated fiber surface has no adequate wetting and functional groups. The adhesion failure is further confirmed by similar adhesion strength and compression shear strength values when the fiber was embedded in various epoxy resins with different temperature behavior. The tensile strength of fiber is sensitive to surface treatment conditions as revealed by a bimodal Weibull statistical distribution analysis. Considerable strength reduction occurred, particularly for cases of acidic and plasma treatments, while UV irradiation shows the better ability to retain fiber strength.     

船板涂层耐空蚀研究

因舰船船板水下表面蚀损严重,影响了作战寿命及效率,从实际需要及理论探讨,均要求对船板涂层耐空蚀作详细研究,为此,在高速水洞中选择了几种涂层做耐空蚀实验,用麻点率来衡量涂层的耐空蚀能力,选择出了耐空蚀性较好的涂层.     

风电机叶片复合材料涂层必要性浅析

通过讨论垂直轴式风电机的工作环境和叶片金属材料的分析,并通过对比没有涂层材料和有涂层材料的不同情况下,叶片在各种环境条件下工作得到的实验结果,得到在实际工况下对风电机叶片进行涂层是必要的。     

玻璃鳞片胶泥在煤气管道中的应用

介绍了呋喃树脂、环氧改性糠醇树脂的性能、反应机理，以及玻璃鳞片的规格与用量，惰性填科等对涂膜耐化学性、施工性的影响。通过试验研制出玻璃鳞片胶泥，成功地应用于首钢搬迁工程的煤气管道中，有效地保护了管道，提高了使用寿命。     

静水压下胶粘涂层的吸湿应力研究

根据半无限体的轴对称模型，对静水压下的胶粘涂层因填充粒子与胶层基体间吸湿性能的差别而引起的吸湿应力进行了研究，以达到饱和吸湿浓度的抗水力磨蚀胶粘涂层为例，对吸湿应力作了数值计算，并进行了结果分析     

激光层裂技术测量涂层与基体结合强度研究

激光层裂法测量涂层结合强度是近年来新发展的一种方法，文中介绍了该方法检测的基本原理与实验方法，并对该测量方法的几个关键技术，即应力波生成与传播的数学模型、约束怪与能量吸收层对应力波形的影响、应力波形的测量与临界值的判定，进行评述，并讨论了该技术的研究进展。     

Al—AA原位电化学聚合涂层研究

采用恒电地在铝阴极上原位电化学聚合丙烯酸形成聚合涂层，研究了电聚合电位于以持电解质及单体浓度等对成膜的影响，考察了电流密度随电聚合时间的变化趋势。