纳米晶LaFeO3 薄膜的制备与不同气氛处理后的光电子能谱

利用sol\|gel工艺, 在硅衬底上制备了纳米晶LaFeO₃薄膜. 测试了在乙醇蒸气和NO₂气氛下处理后的光电子能谱(XPS), 结果表明, 纳米晶LaFeO₃ 薄膜吸附乙醇后, 表面吸附氧含量明显降低, 铁含量略有下降; 吸附氧化性气体NO₂后, 表面吸附氧和铁含量明显增高, 且存在三价铁离子向四价铁离子转化的趋势. 通过测试和分析表明, LaFeO₃ 的敏感机理不仅与表面吸附氧相关, 还与表面三价铁离子的变价有关.     

Crystallization kinetics of （Ni0.75 Fe0.25）78-xNbxSi10B12 （ x = 0, 5 ） amorphous alloys

Amorphous ribbons of （Ni0.75 Fe0.25 ） 78- x Nbx Silo B12 （x = 0, 5 ） were prepared by a single roller melt-spinning technique in air atmosphere. The crystallization kinetics of the alloys were investigated by means of continuous heating, and the activation energies of the alloys were calculated using Kissinger plot method and Ozawa plot method on the basis of differential thermal analysis data.     

左手材料的性质及研究动态

左手材料(也被称为负折射率材料)最早由前苏联科学家Veselago在20世纪60年代从理论上提出来的,是一种具有介电常数和磁导率同时为负值的材料,它具有诸如负相位速度,负折射率,理想成像,逆Doppler频移及反常的Cerenkon辐射等多种奇异的物理现象。本文主要论述左手材料的性质并分析左手材料全新应用前景,简要介绍左手材料近年来的研究动态及发展前景。     

Preparation and Characterization of Organic/Inorganic Hybrid Nanofibers

A new class of nanocomposites based on organic and inorganic species integrated at a nanoscale has obtained more attention these years. Organic-inorganic hybrids have both the advantages of organic materials, such as light weight, flexibility and good moldability, and inorganic materials, such as high strength, heat stability and chemical resistance. In this work, PVAc/TiO2 organicinorganic hybrid was prepared by sol-gel process. Eiectrospinning technique was used to fabricate PVAc/TiO2 hybrid nanofibers. The structures and properties of the hybrid nanofibers were characterized by Scanning Electron Microscopy （SEM）, Atomic Force Microscope （AFM）, Differential Scanning Calorimeter （DSC） and Fouriertransform infrared （FTIR） spectra. SEM and AFM were employed to study the topography of the hybrid nanofibers. The chemical structure of the hybrid nanofibers were examined by FTIR. The DSC scans revealed the second order transition temperature of the hybrid materials were higher than PVAc.     

Liquid Flow in Shaped Fiber Bundle

By computation and comparison of the critical spreading coefficient parameter, it was found that shaped fiber bundle is better for wetting. Liquid-air interface tension of liquid arising the shaped fiber bundle body is considered as one critical factor besides liquid viscosity, inertia force and liquid-fiber interface tension. Experimental result simulation demonstrated that the liquid-air interface tension is correlated with the geometric size of the liquid arising in body, Φ0 （x） and which is affected by the cross sectional shape of fiber and the radius of single fiber. The shaped fiber bundle model is/ntroduced to/nvestigate liquid flow in fiber assembly. The model is generated based on a random function for stochastic forming of fibers in bundle and it is necessary to combine this fundamental model with physical explanation for investigation of liquid flow in fiber assembly.     

4-溴-N,N-二(4-叔丁基苯基)-苯胺的合成及其光谱性能的研究

以对溴苯胺和对叔丁基苯甲酸为原料,经Hofmann降解、Sandmeyer和Ullmann反应等反应,合成得到了一种具有空穴传输性能的环金属配合物电致磷光中间:4-溴-N,N-二(4-叔丁基苯基)-苯胺,反应产率为43.5%,产物结构经核磁氢谱、质谱得到了表征.紫外吸收光谱和荧光光谱研究表明:该化合物具有强烈的紫外-可见吸收和荧光发射性能,其氯仿溶液的最大紫外吸收波长为306 nm,最大荧光发射波长是543 nm.但薄膜的最大荧光发射波长蓝移至458 nm.     

浅议高分子的表面化学组成生物特性

生物相容性是高分子材料在临床上用作医用装置的基本要求,改变高分子材料的表面化学组成是提高其生物相容性的重要途径。论述了构建表面化学组成改性高分子材料生物相容性的最新研究进展,并对改善高分子材料生物相容性的研究方法提出了一些看法     

土工合成材料在工程中的应用与发展前景

土工合成材料是极具有生命力的新型工程材料，是由聚丙稀、聚乙稀等为原材料经进一步加工而成的，其应用已经渗透到工程建设的各个角落。本文综述了国内外土工合成材料的发展，介绍了土工合成材料的类别、应用范围以及发展趋势和前景。     

夹芯保温复合墙体及其施工工艺的研究

多年来，建筑墙体一般采用单一材料砌筑，如采用粘土砖、混凝土砌块、加气混凝土等材料，着重考虑其承重功能。但是由于这些密度大的墙体材料的保温性能很差，其导热系数很高，不能满足建筑节能的要求，因此，往往采用承重材料（如砖、砌块等）与高效保温材料[如聚苯板、岩棉板、玻璃棉等]进行复合，这样的墙体即称作复合墙体．发达国家的新建建筑普通采用复合墙体，我国今后建筑要达到节能50％的标准，也必须采用复合墙体。     

如何防止砌体结构裂缝

1．裂缝的危害和防裂的迫切性 砌体属干脆性材料，裂缝的存在降低了墙体的质量，如整体性、耐久性和抗震性能，同时墙体的裂缝给居住者在感观上和心理上造成不良影响。特别是随着我国墙改、住房商品化的进展，人们对居住环境和建筑质量的要求不断提高，对建筑物墙体裂缝的控制的要求更为严格。由于建筑物的质量低劣，如墙体裂缝、渗漏等涉及的纠纷或官司也越来越多，建筑物的裂缝已成为住户评判建筑物安全的一个非常直观、敏感和首要的质量标准。因此加强砌体结构，特别是新材料砌体结构的抗裂措施，已成为工程量、国家行政主管部门，以及房屋开发商共同关注的课题。因为这涉及到新型墙体材料的顺利推广问题。