基于吸收分析的多属性反演技术及在油田开发中的应用

为了满足油藏开发阶段砂体内部油水识别的需求,提出了基于地层吸收分析的多属性反演流体识别技术。算法实现分三步:1利用基于广义S变换的瞬时子波吸收分析(GST_WEA)油气预测技术计算地震记录的高、低频吸收因子;2结合吸收因子和其它与流体相关的地震属性,以电阻率曲线为目标函数构建多元线性反演,利用多元逐步回归算法对包括吸收因子在内的多种地震属性进行流体敏感性排序;3进一步利用概率神经网络算法对优选的以吸收因子为主的地震属性进行多属性电阻率反演。通过模型分析验证了GST_WEA油气预测技术的抗噪性。实际应用效果表明吸收因子较其他地震属性具有更高的流体敏感性,通过多属性反演有效预测了砂体内部的含油优势区域。     

Space experimental studies of microgravity fluid science in China

Microgravity fluid physics is an important part of microgravity sciences, which consists of simple fluids of many new systems, gas-liquid two-phase flow and heat transfer, and complex fluid mechanics. In addition to the importance of itself in sciences and applications, microgravity fluid physics closely relates to microgravity combustion, space biotechnology and space materials science, and promotes the developments of interdisciplinary fields. Many space microgravity experiments have been performed on board the recoverable satellites and space ships of China and pushed the rapid development of microgravity sciences in China. In the present paper, space experimental studies and the main results of the microgravity fluid science in China in the last 10 years or so are introduced briefly.     

He-Ar isotopic system of fluid inclusions in pyrite from the molybdenum deposits in south margin of North China Block and its trace to metallogenetic and geodynamic background

The helium and argon isotopic compositions of the ore-forming fluids from the molybdenum deposits such as Jinduicheng, Donggou, Shijiawan, and Sandaozhuang, which are located in the East Qinling molybdenum belt in south margin of North China Block （SMCNB）, are reported in this paper. The origin and the evolution of the ore-forming fluids and their coupled-relationships with the intra-continental collision and orogenic process of Qinling Orogen in Mesozoic-Cenozoic have been discussed. The 3He/4He and 40Ar/36Ar values （3He/4He=1.38-3.64 Ra, and 40Ar/36Ar=295.68-346.39, respectively） of the fluid inclusions in pyrite from the molybdenum deposits in East Qinling suggest that, the ore-forming fluid system is mixed by two end members. One is the high temperature deep-derived fluid congenetic with the porphyries generated by crust-mantle mixing, and the other is the low-temperature meteoric water which is rich in crustal radiogenic He with the component of atmospheric Ar. From the Pb isotopic composition, and ore-bearing potential of the porphyry and the regional stratum, we can conclude that the ore-forming materials of the deposits in the East Qinling molybdenum belt are derived from the deep source by the mixing of lower crust and upper mantle. Therefore, the formation of the molybdenum deposits in SMNCB can be related to the crust-mantle interaction, which is accompanied by the intra-continental orogenic and extension process in the post-collision period of Qinling Orogen. The granitic porphyries which are related to Mo mineralization are not simple crust-remelting type granites or S type granites, but belong to syntexis-type or mantle-derived granites, hence their formation has a profound and regional geodynamic background.     

Field synergy principle of heat and mass transfer

Simultaneous heat and mass transfer widely exists in nature and engineering, and it is of vital importance to enhance heat and mass transfer efficiency. In this paper, field synergy equation of heat and mass transfer is derived from its energy equation. Results show that the total transferred heat （including the conducted heat and the heat transferred by mass diffusion through the heat transfer interface） is determined by the values of fluid velocity and enthalpy gradient as well as the value of synergy angle α of velocity vector and enthalpy gradient field. Decreasing the value of α enhances the heat and mass transfer. This means the higher the synergy of velocity vector and enthalpy gradient field, the higher the total transferred heat. By the synergy principle of heat and mass transfer, some methods may be developed to improve the heat and mass transfer efficiency.     

新型低温哨音超流体陀螺模型

针对应用超流体发展高精度新型陀螺的可行性,研究利用交流约瑟夫森效应的低温超流体陀螺原理和典型方案. 首先对陀螺的交流约瑟夫森效应、转动信息与交流约瑟夫森频率关系以及检测等环节建模,并进行系统仿真. 验证了陀螺敏感恒定角速度（地球自转）的过程,进一步研究变输入角速度跟踪、敏感面积及薄膜面积等结构参数对精度的影响. 仿真结果表明,应用交流约瑟夫森效应的低温超流体陀螺原理发展新型高精度陀螺仪是可行的.     

络合萃取对煤制气洗涤废水中酚的回收

用磷酸三丁酯(TBP)和煤油组成溶剂萃取体系有机相,对煤制气洗涤过程中产生的高浓度含酚废水进行了萃取和反萃处理研究.探讨了影响苯酚萃取的因素如废水pH和TBP体积分数,考察了反萃剂氢氧化钠溶液质量分数对反萃效果的影响;同时,对萃取和反萃过程中有机相的重复使用问题进行了研究.实验结果表明,当废水的pH=3～6时,一级萃取率可达90%以上,CODCr去除率达到80%以上;二级萃取率达到40%左右,苯酚总的萃取率达到95%以上;当氢氧化钠溶液质量分数为4%～10%时,反萃率可达80%以上;TBP-煤油有机相可在萃取和反萃的过程中多次重复使用.     

颗粒流本构关系的实验研究

基于"拟流体"的思想,给出了测量颗粒流本构关系的实验方法.在颗粒斜槽流实验中,通过颗粒的抛物线运动计算流层速度分布,根据非牛顿流体理论求得颗粒流黏性的本构关系;建立了颗粒斜槽流的数学模型,流层的速度为指数分布,流量为斜槽倾角和流层厚度的函数.以小麦颗粒为例,实验结果与用"拟流体"方法所得的预测值进行比较,相对误差在13%以内.     

微胶囊流体脉动热管的热输送特性

本文采用外径为2.5mm,内径为1.3mm的铜管,做成四环脉动热管,在不同工质（3％的FS-39E型微胶囊流体、乙醇、水、）、不同充液率（40％～80％）的条件下进行对比实验,探讨了工质和充液率对脉动热管热输送性能的影响。结果发现：与乙醇、水对比,微胶囊流体具有较宽的工作范围,尤其在高充液率的条件下,表现出良好的启动性能和热输送性能。     

络合萃取法提取6 硝基 1 2 重氮氧萘 4 磺酸

用络合萃取法对6-硝生产母液中的6-硝基-1,2-重氮氧萘-4-磺酸进行了萃取研究.在室温下,以体积分数30%的三辛胺(N-235)氯仿溶液为萃取剂,萃取荆与母液体积比1:1,萃取60Min,萃取可率达96.1%;以质量分数12%的NaOH溶液为反萃取剂反萃有机相,有机相与NaOH溶液体积比2:1,反萃取60 Min,反萃取率可达94.3%.     

聚联苯乙烯和石墨化碳黑固相萃取用于污水中雌激素的定量分析

研究了聚联苯乙烯(SDB)和石墨化碳黑(GCB)固相萃取用于样品前处理对污水样中雌二醇(E2)和乙炔基雌二醇(EE2)的酶联免疫吸附检测(ELISA)定量分析可靠性的影响.采用GCB固相萃取可对E2和EE2进行分步洗提,相比SDB固相萃取在污水厂原水样中E2和EE2的加标回收率分别从181.4%和122.6%降至113.3%和109.4%,相对标准偏差均降至10.0%以下;在污水厂尾水样中E2的加标回收率则分别从144.2%降至93.5%,而EE2无明显变化,相对标准偏差均从接近10.0%降至8.0%以下.利用液相色谱-飞行时间质谱联用对污水厂原水样的平行分析的结果表明采用GCB固相萃取可比采用SDB固相萃取降低38%的E2检测假阳性和15%的EE2检测假阳性.