PAN预氧化纤维的分段碳化工艺研究

本文通过对PAN预氧化纤维在碳化过程中的热裂解反应机理的分析,采用了以600℃为分界点的两段碳化工艺。对有关分段碳化的温度、碳化时间、张力及保护气氛等对最终碳纤维的力学性能的影响,作了较详细的研究。     

氨基酸嵌段聚醚氨酯的合成及其膜表面共价肝素化修饰

以Ｌ－赖氨酸甲酯和Ｌ－膀胱氨酸二甲酯分别作扩链剂进行嵌段聚醚氨酯的合成并将产物透明薄膜。为了进一步改进膜的抗凝血性，在膜的表面以胺共价键结合天然肝素进行修饰。实验结果表明所得膜表面在扫描电镜观察下呈凹凸不平的结构形态，其抗凝血性有显著提高，而膜仍保持优良弹性。测定了ＳＰＥＵ膜的其它性能。     

T902抗泡剂结构分析及性能研究

由高分子反应统计理论,结合~1H-NMR及(13)C-NMR方法,分析了T902抗泡剂的序列结构,获得了该三元无规共聚物分子的链段分布函数。系统研究了分子结构对消泡性能的影响,指出了改善抗泡剂配伍性能的正确途径。     

优化技术用于交错管道双环连接设计

对双环管连接交错管道问题,从几何分析到目标函数的建立,加上各种约束条件,通过计算机运算,非常迅速、有效地求得各项设计参数,从而满足工程的各种需要。     

基于价格机制的无线网自适应接纳控制算法

为了有效地控制对无线网资源的使用，针对自适应的多媒体应用带宽可以动态调整的特点以及价格对用户行为的影响，提出一种与价格机制相结合的自适应的接纳控制算法，该算法适合于无线网中具有多服务类、多优先级服务的情况，并根据网络当前状况动态地调整价格以缓解拥塞问题。该价格机制力求在有效性和易用性之间做出权衡。最后与未结合价格机制的自适应接纳控制算法进行性能对比表明，将价格机制与接纳控制结合起来，可以很大程度上改善无线网的性能。     

高速铁路整孔箱梁架设现浇翼缘可靠性论证

为解决桥隧相连路段箱梁运输无法通过隧道的问题，提出现浇箱梁翼缘的方案。并对其使用可靠性和安全性进行分析论证。     

Connecting Conditions and Constraint Equations in Applied Science

IntroductionIn applied science , e . g . machinery , vibrationmechanics , fluid mechanics , and management science , toobtain the opti mal solution of some issues , the objectfunction is usually shown since the abstract mathematicsmodel is set , and all kinds of boundary conditions andconnecting conditions or constraint conditions are putforward . Above these conditions are shown with the shapesof constraint equations . For example ,in machinery opti maldesign, to get the opti mal solution of …     

Correlation between geometrical parameters of electrical tree and corresponding partial discharge parameters in XLPE

This paper deals with the experimental study on the correlation between the geometrical parameters of electrical tree and corresponding partial discharge (PD) characteristic parameters in the course of electrical tree aging within cross linked polyethylene (XLPE) insulation. The electrical tree aging tests were performed on specimens removed from a section of 220 kV transmission cable. The PD macroscopic characteristic parameters were found to be significantly dependent on the corresponding geometrical parameters of electrical tree channels in the course of aging of XLPE, and different kind of electrical tree has different characteristics, and there is obvious correlation between the type of electrical tree and the pre-applied power-frequency stress. Beside, using regression analysis, the expression of the relation between them were obtained, and from which it can be seen that there is significant nonlinear correlation between geometrical parameters of electrical tree and corresponding PD characteristic parameters in the course of aging of XLPE. Therefore, the aging degree of XLPE can be effectively evaluated by recognizing the changing regularity of the PD rnacroscopic characteristic parameters.     

嵌段共聚水溶性高分子在空气/水界面吸附态的构象

对于用几种不同疏水／亲水单体比合成的聚(丙烯酸丁酯／丙烯酸)共聚物样品测定了其水溶液的表面张力,运用Gibbs吸附方程求得在样品溶液临界胶束浓度时样品在气／液界面的分子吸附面积,以此推测其吸附态构象。结果表明,亲水单体单元在共聚物中含量多时,样品分子趋于在水中溶解;疏水单体单元多时,样品分子趋于在表面吸附。其吸附态构象为分子链上相邻的数个丁酯侧基吸附于水面,形成“薄煎饼状”疏水微区。