Blue emission from hydrogen-containing a-Si：H／SiO2 multilayers and the investigation of its mechanism

A series of hydrogen-containing a-Si:H/SiO2 multilayers with different a-Si:H sublayer thickness were fabricated by layer-by-layer deposition and in situ plasma oxidation in a plasma-enhanced chemical vapor deposition system (PECVD). Optical induced blue emission from the samples was observed by the naked eye at room temperature, which has never been reported in the luminescence study of Si/SiO2 multilayers up to now. Both the photoluminescence (PL) peak and the absorption edge show a blue shift as the a-Si:H sublayer thickness decreases. The origin of the blue emission and the effect of hydrogen are discussed.     

PBG光子晶体光纤中空气导光条件的研究

应用平面波法分析了带隙效应导引光子晶体光纤(Photonicbandgapguidingfibers,PBG PCFs)中实现空气通道导光必须满足的条件,计算机仿真了蜂窝和三角形两种不同结构的PBG PCFs的空气导光性能。计算结果表明,要实现空气导光,空气孔直径与周期的比值d/Λ必须大于某一特定值:对于蜂窝结构该比值为0.84,而对于三角形结构该比值为0.59;在特定的d/Λ下,空气导光的波长范围随Λ可变。     

Raman crystal lasers in the visible and near-infrared

Raman lasers based on potassium gadolinium tungstate and lead tungstate crystals pumped by a≈120 ps Nd: YAG laser at 1.064/μm were developed. High reflection mirrors for the Stokes wavelength have been used to generate near-infrared and eye safe spectral region of 1.15 - 1.32/μm. Second harmonic generation of the generated Raman lasers was observed. Eifficient multiple Stokes and anti-Stokes picosecond generation in 64 crystals have been shown to exhibit stimulated Raman scattering on about 700 lines covering the whole visible and near-infrared spectrum. All stimulated Raman scattering (SRS) wavelengths in the visible and near-infrared spectrum are identified and attributed to the SRS-active vibration modes of these crystals.     

Selective formation of tetrahedral Pt nanocrystals from K2PtCl6／PVP

Tetrahedral platinum (Pt) nanocrystals (3-8 nm) are synthesized in high selectivity (ca. 80%) from hydrogen reduction of aqueous K2PtCI6 by using polyvinylpyr-rolidone (PVP: Mw≈360000) as a protector. Morphology (TEM) measurements of the metal colloids and UV-Vis absorption of the colloidal solution are employed to monitor the tetrahedron formation during the syntheses with varying K2PtCl6/PVP ratios. The results clearly show a two-stage process for the selective formation of tetrahedral nanocrystals. Rapid nucleation and crystal formation at the early stage result in round-like crystallites and the external facet evolution in thereafter slow crystal growth leads selectively to the formation of the tetrahedrons.     

基于等效介质二维光子晶体平面波展开法的理论研究

应用等效介质理论,提出了一种计算二维光子晶体的新平面波展开法,数值模拟了圆介质柱在空气中正方排列结构的能带,模拟结果与常规的平面波计算结果符合的很好。     

光子晶体加速结构的初步研究

用有限差分法计算了由金属棒按三角形晶格分布的二维光子晶体的带隙图,计算结果表明:当金属棒半径a和棒间距b比值小于0.2时,二维光子晶体只有一条带隙,即若引入缺陷,可约束主模、抑制高次模.采用Microwave Studio计算了该种光子晶体微波加速结构的场型分布,结果显示当a/b＜0.2,类TM01模在缺陷中传输,类TM11模(横向模)能传出光子晶体.另外计算了结构尺寸公差对行波单元谐振频率的影响,还模拟计算了带有测试探针的由3个PBG单元构成的谐振腔的S参数.     

晶体铟的德拜温度和格林乃森参量随温度变化规律研究

研究了原子相互作用势与晶体德拜温度的关系．考虑到原子作非简谐振动，得到了格林乃森参量随温度变化的规律．以晶体铟为例，探讨了晶体德拜温度随温度的变化规律，理论计算与实验基本符合．     

光子晶体光纤熔接机理的研究

光子晶体光纤（PCF,Photonic Cpystal Fiber）的熔接技术为PCF产品的应用和开发提供了条件。本文主要介绍了影响PCF熔接的主要因素，比较了传统电弧熔接方法和激光熔接方法的优缺点，阐述了激光熔接的基本原理和工作流程，为PCF激光熔接机的制作打下基础。     

一维有限光子晶体中的单个缺陷

在一维有限光子晶体中利用传输矩阵推导了其反射和透射系数,并讨论了单个缺陷位置对透射系数的影响,发现单个缺陷在晶体中不同位置具有相同的缺陷模频率,但其透射峰具有不同的高度,同时当缺陷在晶体中心时,其透射峰最高。     

Study on peptide-peptide interaction using high-performance affinity chromatography and quartz crystal microbalance biosensor

The specific interaction between sense and antisense peptides was studied by high-performance affinity chromatography （HPAC） and quartz crystal microbalance （QCM） biosensor. Fragment 1-14 of human interferon-β （hlFN-βwas chosen as sense peptide and its three antisense peptides （AS-IFN 1, AS-IFN 2, and AS-IFN 3） were designed according to the degeneracy of genetic codes. The affinity column was prepared with sense peptide as ligand and the affinity chromatographic behavior was evaluated. Glu-substituted antisense peptide （AS-IFN 3） showed the strongest binding to immobilized sense peptide at pH 7.5. A quartz crystal microbalance-flow injection analysis （QCM-FIA） system was introduced to investigate the recognition process in real-time. The equilibrium dissociation constants between sense peptide and AS-IFN 1, AS-IFN 2 and AS-IFN 3 measured 2.08×10^-4, 1.31×10^-4 and 2.22×10^-5 mol/L, respectively. The mechanism study indicated that the specific recognition between sense peptide and AS-IFN 3 was due to sequence-dependent and multi-modal affinity interaction.