运用惰性点方法反算沥青路面结构地基模量

在水泥混凝土路面中存在的路面弯沉盆惰性点,可以用于反算水泥混凝土路面结构模量.为此论证了惰性点在沥青路面弯沉盆中的存在性,并利用惰性点方法开发出一套反算沥青路面结构地基模量的程序.首先论证典型的沥青路面3层体系可以简化为2层体系,在此2层体系中存在惰性点.然后,通过回归分析方法得出了路面结构信息与惰性点参数的相关关系.最后通过此关系,可以在实测弯沉盆中找到惰性点,并求解地基模量.     

阳极氧化电压对纳米孔阵列阳极氧化铝膜形貌的影响

阳极氧化铝是将金属铝进行阳极氧化处理后，在其表面上形成的一层氧化膜，可对金属铝起到装饰和保护的作用．20世纪末人们发现，铝在适当的阳极氧化条件下可以制得具有纳米孔阵列的阳极氧化铝膜．随着纳米科学的蓬勃发展，纳米孔阵列阳极氧化铝膜由于其具有大的比表面积、高纵横比、大小均     

纳米级铝阳极氧化膜的形成机理及结构调整

从纳米级阳极氧化铝(AAO)膜对应用的重要性入手，主要简述AAO膜的制备、形成机理、自结构特点及结构调整方法。     

锌对在PH不同的溶液中锑阳极成膜规律的影响

利用恒电位阳极极化电流与极化时间的关系、线性电位扫描法研究了锑锌合金在PH值不同的电解质溶液中于1.2V(30±0.1℃,vs.SCE)阳极成膜规律及膜相组成。讨论了锌掺入对在PH不同的溶液中锑阳极成膜规律的影响原因。     

渗硼金刚石薄膜电极用于有机废水降解的实验

为了研究渗硼金刚石薄膜电极电化学性能以及用于含有机污染物的废水处理的可行性,采用循环电解的方法,对含苯酚的废水进行了电化学氧化实验,同时与活性涂层钛阳极进行了对比实验研究,考察了阴极的可替代性,最后用两种电极对含苯胺的工业废水进行了对比实验。实验结果表明,金刚石电极不仅具有优越的电化学性能和优异的电化学指标,而且可以用于电化学废水处理;同时,用钛电极代替金刚石作阴极经济可行。     

用AAO模板及脉冲激光溅射制备量子点阵

 利用多孔阳极氧化铝(anodic aluminum oxide,AAO)作为模板,采用准分子脉冲激光溅射方法(pulsed laser deposition,PLD)成功制备了光荧光材料La_0.95Eu_0.05BaB₉O₁₆的量子点阵,用扫描电镜表征了AAO模板和制备的量子点阵,测量了靶材和量子点阵的光荧光谱.讨论了用此方法制备的量子点阵的结构和发光特性.证明此方法可为未来制备其它材料的量子点阵开辟了一条途径.     

Preparation and properties of antimony thin film anode materials

Metallic antimony thin films were deposited by magnetron sputtering and electrodeposition. Electrochemical properties of the thin film as anode materials for lithium-ion batteries were investigated and compared with those of antimony powder. It was found that both magnetron sputtering and electrodeposition are easily controllable processes to deposit antimony films with flat charge/discharge potential plateaus. The electrochemical performances of antimony thin films, especially those prepared with magnetron sputtering, are better than those of antimony powder. The reversible capacities of the magnetron sputtered antimony thin film are above 400 mA h g^-1 in the first 15 cycles.     

Leaching Mechanism of Complicated Antimony-Lead Concentrate and Sulfur Formation in Slurry Electrolysis

Anodic reaction mechanism of complicated antimony-lead concentrate in slurry electrolysis was investigated by the anodic polarization curves determined under various conditions. The main reactions on the anode are the oxidations of FeCln^(2-n) . Though the oxidation of jamesonite particle on the anode can occur during the whole process, it is less. With the help of mineralogy studies and relevant tests, the leaching reaction mechanism of jameson[to and gudmundite during slurry electrolysis was ascertained. Because of the oxidation reaction of FeCl3 produced by antimony-lead concentrate itself, the non-oxidation complex acid dissolution of jameson[re, the oxidation complex acid dissolution of gudmundite, and the oxidation of air carried by stirring, the leaching ratio of antimony reaches about 35% when HCl-NH4Cl solution is used to leach antimony-lead concentrate directly. So when the theoretical electric quantity is given to oxidation of antimony in slurry electrolysis, all of antimony, lead and iron containing in antimony-lead concentrate, are leached. The formation of sulfur is through the directly redox reaction of Fe^3 and jameson[re. The S^2- in jamesonite is oxidized into S^0 , and forms the crystals of sulfur again on the spot. The redox reaction of Fe^3 and H2S formed by non-oxidative acid dissolution of jamesonite is less.     

铝电解用Fe-Ni-Co-Al-2O3金属陶瓷惰性阳极

研制了一种新型铝电解金属陶瓷惰性阳极，阳极基体由Fe-Ni-CoAl2O3构成。在石墨坩埚中，960℃温度下，电解质中的氧化铝质量分数为60%，摩尔比为26；阳极电流密度为10 A/cm2，阳极尺寸大小为120 mm×80 mm×15 mm，石墨阴极尺寸大小为120 mm×40 mm×20 mm，通入的直流电为100～300 A，电解时间各为10 h；实验所得的电解铝产品纯度达到98%以上，杂质主要为Fe，Ni，Co；电解后的阳极外观尺寸无明显变化，阳极气体中氧气质量分数达到98%～99%。阳极的反电动势为245 V，比理论分解电压仅高出025 V证明该阳极为惰性阳极，在电解槽中进行的是Al2O3的分解反应。     

保温时间对17Ni/(10NiO-NiFe_2O_4)金属陶瓷性能的影响

采用热压烧结工艺制备铝电解用17Ni/(10NiO-NiFe2O4)金属陶瓷惰性阳极材料,研究保温时间对其致密度、力学性能、导电性能以及断口形貌的影响。研究结果表明:保温时间对17Ni/(10NiO-NiFe2O4)金属陶瓷材料的致密度、硬度以及导电性能影响不大,但对材料的抗弯强度与抗热震性有一定影响,当保温时间由10 min延长到40 min时,金属陶瓷材料的抗弯强度从84.61 MPa提高到125.89 MPa,抗热震性也提高10.22%,但保温时间过长反而使抗弯强度和抗热震性降低。此外,当保温时间为20 min时,金属陶瓷材料的综合性能力学性能及导电性最好。