Analysis of Pyrolysates for Phenol Formaldehyde Resin by Py-GC/MS

Pyrolysis of phenol formaldehyde resin has been investigated by Pyrolysis Gas Chromatography-Mass Spectroscopy at the different temperatures from 500℃ to 750℃. Its composition of pyrclysates has been analyzed. Several compounds, especially benzene, toluene, p-xylene could only be formed above 500-550℃. Howerver, peak intensities for some pbend derivatives were decreased at the higher temperature. During pyrolysis, for thermo-setting phenol formaldehyde resins, polymeric chain scissions take place as a successive removal of the monomer units from the polymeric chain. The chain scissions are followed by secondary reactions, which leads to a variety of compounds. Addition reactions can also take place among the double-bond compounds during pyrolysis.     

某矿冲积层下不同产状煤层开采过程中的涌水特点

在某矿巨厚含水冲积层下,有三种不同产状的煤层。在开采过程中,它们的涌水特点也各不相同:急倾斜煤层,导水裂隙带发育比较快也比较高,涌水量变化曲线比较陡。缓倾斜煤层,导水裂隙带发育比较慢比较低,涌水量变化曲线比较缓。因此,不同产状的煤层,其防水煤(岩)柱的大小应不相同。另外,通过试验,还证明了合理的采用间歇性开采方法,可显著地减少矿坑涌水量。     

THE TRANSFER BEHAVIOUR OF SOME CATIONS AT WATER／NITROBENZENE INTERFACE BY SEMIDIFFERENTIAL CYCLIC VOLTAMMETRY

The transfer of Sr~(2+) and Ba~(2+) ion, facilitated by 18-Crown-6 present in the aqueous phase, and of succinylcholine ion at w/nb interface were investigated by semi-differential cyclic voltammetry. A good polarographic curve of succinylcholine ion dissolved in water was obtained in the system of 0.01 mol/l LiCl (w)——0.01 mol/l TBATPB (nb). The peak current is directly proportional to the concentration of SC~(2+) ion. It can be used for the determination of SC and the detection limit is 1.05×10~(-5) mol/l.The apparent D~w and D~(nb) have been estimated. The transfer of Sr~(2+) and of Ba~(2+) at the interface are facilitated by 18-Crown-6 present in the aqueous phase and the peak current is directly proportional to the concentration of 18-Crown-6 in water. This method can be used for the determination of the complexing agent and for the stability constant of the complex formed in the aqueous phase.All the experimental results are in keeping with the theoretical.     

小波多尺度分解及其在SAR图象目标检测中的应用

合成孔径雷达图象的目标检测是最重要的任务之一.目前用于目标检测的现有方法速度较慢、准确率较低、精度较差.作者提出小波分解的方法用于目标检测.同尺度目标检测采用二维离散二进小波分解方法,提高检测速度.不同尺度的目标检测采用多尺度二维离散小波分解方法,提高检测准确率.图象匹配采用灰度归一化的灰度相关匹配方法,提高匹配精度.实验证明,采用该法进行目标检测能获得较好的效果.     

物探技术在矿井防治水中的应用

在介绍高密度电阻率法原理的基础上,通过实例分析了该物探方法在煤矿防治水特别是导水断层和采空水积水的探测效果,提出该方法在预测预报矿区含水层、导水断层及采空区积水等方面具有良好的效果。     

水－仲丁醇－碳4三元体系8MPa时的液液平衡

在国内首次建立的一套温度高达３５０℃，压力直至２０ＭＰａ的高压液液相平衡测定装置上，测定了水－仲丁醇－碳４三元体系在８ＭＰａ和４０３．１５，４２３．１５，４４３．１５Ｋ时液液相平衡数据。采用修改的Ｒ－Ｋ方程对此数据进行了理论关联。关联结果与实验数据一致。     

吊舱式推进装置水动力性能试验研究

对吊舱式推进装置进行了多方案的模型试验研究，考察了串列式吊舱推进装置前后桨的负荷匹配及初始相位角的影响。空泡水筒敞水试验结果表明，无论双桨串列式或单桨拖、推式吊舱推进装置，由于吊舱影响使螺旋桨效率均比常规桨有所提高；但若计及吊舱阻力则吊舱推进装置的系统效率有所下降。可以预见，吊舱式推进装置因其众多的优越性而具有广阔的发展前景。     

广义De Bruijn图分解问题的一些结果

广义DeBruijn图是最近提出的一种具有良好性质的网络拓扑结构，文中对这类图的分解问题作了初步的分析，构造了一类基本模块，并得出了一些关于模块效率的数值结果。