铝护套连续挤压包覆模腔中金属流动分析

本文对铝护套连续挤压包覆模腔进行分区,分别分析了模腔中汇合室、转角区和焊合室中金属的流动状态。通过分析模腔中各区域的金属流动过程,提出了铝护套连续挤压包覆实际生产中出现的弯折、卷曲及未焊合等缺陷的产生原因,为其解决提供了理论依据。     

电厂金属焊接技术中缺陷原因及具体措施分析

电厂金属焊接技术的质量,对整个电厂机组能否正常的运行起着极其重要的作用。大部分原因是电厂在进行金属焊接时,电厂金属焊接技术不成熟,无法满足实际的操作要求;时间上要求紧迫。另外,金属焊接的质量监理部门在监管是存在漏洞;机械设备在安装是存在隐患,都会造成电厂金属焊接的质量出现问题。而电厂金属焊接的质量会影响到整个电厂生产的安全与稳定。所以,要保证电厂金属焊接的质量是非常重要的。本文针对电厂金属金属焊接技术中存在的缺陷原因进行分析,并提出具体的可实施措施。     

有机-无机复合物[Zn(C10H8N2)3][HPMo12O40（VO）2]的合成、晶体结构及性能研究

通过水热法合成了一种新型的有机-无机复合物[Zn(C10H8N2)3][HPMo12O40(VO)2],用X-射线单晶衍射技术及红外光谱对其结构进行了表征,并探讨了该复合物在仲辛醇选择性氧化制己酸中的催化活性.实验结果表明,该复合物是由1个金属有机配离子[Zn(C10H8N2)3]2+和1个多金属氧酸阴离子[HPMo12O40(VO)2]2-构成的,二者之间通过静电引力结合,该复合物对仲辛醇氧化制己酸具有较高的催化活性.     

利用电感测量金属的线膨胀系数实验设计

根据线圈自感系数(L)随铁芯插入的深度变化而变化,从而可由线圈自感系数的变化知道铁芯长度的变化,进而由长度变化得到线膨胀系数.提出了一种新的测量金属线膨胀系数的方法,介绍了利用交流电桥来测量线圈的自感系数,进而测量金属线膨胀系数(α)的基本原理、实验方法和实验结果.     

影响建筑用塑料窗产品质量主要因素分析及预防控制措施

建筑用塑料窗因其具有良好的密封性能、保温性能、耐腐蚀性能和经济实用等优点,在建筑工程中被广泛应用。但由于建筑市场的无序竞争、原材料质量缺陷、生产过程中关键工序控制不严,出现了很多问题,针对影响产品质量的主要因素进行分析,并从监督管理和企业内部质量控制两个方面,提出了一些预防控制措施及建议。     

Hydrothermal synthesis,structures and properties of metal phosphonates based on m-xylylenediphosphonic acid

In this work, a series of new metal phosphonates were hydrothermally synthesized and structurally characterized based on m-xylylenediphosphonic acids （H4L）, including [M（H2L）（bpy）] （M = Mn 1, Co 2）, [MH2L）（phen）] （M = Co 3, Cu 4）, and [Cu2（H2L）2（bpy＂）2] 5 （bpy = 2,2＇-bipyfidine, phen = 1,10-phenanthroline, bpy＂ = 4,4＇-dimethyl-2,2＇- bipyridine）. X-ray diffraction indicated that compounds 1 and 2 were isomorphic. Complexes 3 and 4 were shown to crystallize in different space groups but had similar crystallographic units. In the complexes, H4L was seen to partially deprotonate to afford H2L^2-. The H2L^2- ligands in 1-4 functioned as tetradentate ligands with each phosphonate group adopting bidentate coordination mode with two M centers to generate a 2D layer. In addition, the H2L^2- anions in 5 functioned as tfidentate ligands with one phosphonate group adopting the bidentate mode and another phosphonate group adopting the monodentate mode, thus linking three Cu atoms to provide a 1D chain. The IR and thermal stabilities of these compounds were subsequently examined.     

Progress in the research of radical anion ligands and their complexes

Recent progress in the research of radical anion ligands and their complexes with metals were summarized in this review. Radical anions were sorted into several types including iminosemiquinonate and iminoquinonate radical, nitroxide radical, heterocycle radical etc. Structural characteristics and properties of the corresponding complexes were introduced. The complexes exhibited novel properties and possibility for applications in organic magnetic materials and transition metal catalysis.     

Progress of transition metal-catalyzed cross-coupling mediated by PyBroP

In the transition metal-catalyzed cross-coupling reactions, phenol and enol derivatives activated by phos- phorus groups are very important electrophiles. This kind of compounds has the advantages of easy preparation, great stability, and producing more benign phosphorus by-pro- ducts. The present work provides a comprehensive review of the advances made over the past several decades in this area. Cross-coupling reactions mediated by PyBroP are first surveyed, then two types of recently developed tran- sition metal-catalyzed reactions, i.e., Pd-catalyzed and Ni- catalyzed reactions, and the corresponding mechanisms are discussed. Finally, future directions are analyzed.     

金属热容量与温度关系的实验测定及理论研究

测量了铜、铁和铝在55~200℃范围内的热容量.基于爱因斯坦和德拜固体热容理论模型,利用Matlab软件对实验数据进行了模拟和处理,得到了3种金属的热容量与温度的关系曲线.结果发现,在实验误差允许范围内,实验结果与爱因斯坦理论和德拜理论都具有较好的一致性.     

谈霞浦后港疏港公路软基处理

由于我国幅员辽阔,地质形成特殊,公路沿线地基常常会有软土层,在该种地质结构上施工对公路路基修建的稳定性具有较大的影响,地基差异或沉降过大,直接影响到公路的正常使用功能。以霞浦后港疏港公路软基处理为例,采用砂垫层、塑料排水板、土工格栅、堆载预压的软基结合处理方法,以期可以提供参考借鉴经验。