情感识别中脑电信号Lempel-Ziv复杂度的研究

在生理信号中,基于脑电信号的情感识别越来越引起研究者的重视。Lempel-Ziv复杂度测量是一种有效的非线性脑电信号分析方法,同时在情感脑—机接口系统中还可以用于进行情感的识别。文章在传统Lempel-Ziv复杂度算法的基础上,提出一种新的Lempel-Ziv复杂度算法,从而更好地进行基于脑电信号的情感识别。首先进行脑电信号的预处理,通过小波包变换来保留脑电信号的低频信号;然后利用非线性滤波器来移除脑电信号中的奇异值;进一步我们提出一种有效的自适应Lempel-Ziv复杂度算法来度量脑电信号的复杂度,并应用此特征值来识别情感。实验结果证明此方法可以从脑电信号中提取出更多有效的模式。同时,它还能够精确地检测到脑电信号的振荡情况,从而提取出不同情感状态下脑电信号中本质的非线性特性。     

酯交换法合成2,6-萘二甲酸乙二醇酯动力学研究

2,6-萘二甲酸二甲酯和乙二醇酯交换反应为探针反应,研究了催化剂种类及其用量、乙二醇/2,6-萘二甲酸二甲酯摩尔比对探针反应动力学影响。实验结果表明,2,6-萘二甲酸二甲酯和乙二醇酯交换反应不是单纯地遵循二级反应动力学。催化剂种类、用量以及乙二醇/2,6-萘二甲酸二甲酯摩尔比均对探针反应动力学方程有影响。     

壳聚糖对Pb2+吸附性能研究

以壳聚糖为吸附剂,考察溶液pH值、Pb2+初始浓度等条件对壳聚糖吸附性能的影响,研究不同温度下壳聚糖对Pb2+的吸附等温线、热力学和动力学行为,并研究表观活化能.结果表明,当pH为5~6时,壳聚糖对Pb2+的吸附能力达到最大值;随着Pb2+初始浓度增加,平衡吸附量随之增加并达到最大值,此后基本不变;当温度在298~313 K变化时,平衡吸附量随Pb2+平衡浓度增大而增大,达到最大值后基本不变,吸附行为符合Langmuir方程;不同温度下的△G均小于零,且温度越高,△G越小,△H大于零,温度越高越有利于吸附;随着吸附时间延长,初始阶段吸附速率较快,此后逐渐下降,吸附动力学行为符合拟二级速率模型,吸附表观活化能为18.658 kJ/mol.     

水环境中农药的水解研究分析

残留在水环境中的农药受到各种生物和非生物因素的影响,会发生复杂的蓄积和降解行为。通过对国内外关于水环境中农药的水解的影响因素和降解机理研究进行总结和归纳,综述了农药的水解动力学规律及水解机理,给出了综合性结论,即农药的水解机理主要是亲核取代反应历程。在一定的温度和pH值条件下,农药的水解遵从一级反应动力学规律,水环境的pH值决定了农药水解的反应速率。     

Study of the aerostatic and aerodynamic stability of super long-span cable-stayed bridges

With the increase of span length, the bridge tends to be more flexible, and the wind stability be- comes an important problem for the design and construction of super long-span cable-stayed bridges. By taking a super long-span cable-stayed bridge with a main span of 1 400 m as example, the aerostatic and aerodynamic stability of the bridge are investigated by three-dimensional nonlinear aerostatic and aerodynamic stability analy- sis, and the results are compared with those of a suspension bridge with a main span of 1 385 m, and from the aspect of wind stability, the feasibility of using cable-stayed bridge in super long-span bridge with a main span above l 000 m is discussed. In addition, the influences of design parameters including the depth and width of the girder, the tower structure, the tower height-to-span ratio, the side-to-main span ratio, the auxiliary piers in the side span and the anchorage system of stay cables, etc on the aerostatic and aerodynamic stability of su- per long-span cable-stayed bridges are investigated numerically; the key design parameters are pointed out, and also their reasonable values are proposed.     

热力学对化学反应速率的影响

结合具体的实例分析,较为系统探讨了热力学对化学反应速率的影响.明确将化学反应速率拆分成实际速率及动力学速率两个层次,较好地解释了化学平衡时实际速率等于0这一客观事实;论文认为反应亲合势A大于0是获取化学反应实际速率的前提.     

基于系统动力学模型的汽车发动机再制造经济性分析

将"产量-利润-效益"三者有机结合,运用系统动力学方法构建了汽车发动机再制造经济性分析模型.运用该模型选取某发动机再制造企业为实证案例,对其经济效益进行了动态仿真分析与模拟.通过分析得出以下结论:目前企业主要依靠三包汽车发动机盈利,大修机和报废机利润率较低,国家应进一步完善相关法律法规和补贴政策,提高废旧发动机的回收率以促进企业产生规模经济效应.     

Identification of proteinaceous binding media for the polychrome terracotta army of Emperor Qin Shihuang by MALDI-TOF-MS

A proteinaceous binding media for the polychrome terracotta army of Emperor Qin Shihuang has been identified using matrix-assisted laser desorption/ionization time-of-flight mass spectrometry(MALDI-TOF-MS).Methods for the preparation of the model samples and the elimination of interferences have been evaluated,as well as ageing processes.A method involving the complexation of EDTA in combination with dialysis was used to eliminate any interference in the polychrome layers taken from the historical samples.The model samples were aged by being buried in loess to replicate the ageing process of the historical samples as closely as possible.The optimum conditions for the extraction and subsequent enzymatic hydrolysis of the extracted protein were investigated.Under the optimized conditions,the‘‘peptide mass fingerprints’’of the proteinaceous binding media from the historical and model samples were determined by MALDITOF-MS.The results revealed that animal glue was used as the binding media for the polychrome layers of Emperor Qin Shihuang’s terracotta army.It also shows that animal glue used as binding media has a long history in China.     

微小型变体飞行器建模与控制系统设计

研究了机翼可后掠变形的微小型变体飞行器动力学建模和飞行控制系统设计方法. 通过状态点选取、气动参数计算和数据拟合插值,建立了变体飞行器的动力学模型. 针对模型的特点,提出了一种以参数空间方法为基础的变体飞行器飞行控制系统设计方法,通过计算机辅助算法,设计了纵向通道控制系统. 仿真结果表明,所设计的公共固定增益控制器能够使得变体飞行器在不同飞行阶段始终具备要求的动态特性,具有可行性和工程实用性.      

固定化优势菌降解2，6-二叔丁基酚的研究

用前期研究中获得的2,6-二叔丁基酚(简2,6-DTBP)降解菌(Aeromonas sp.),进行了对2,6-二叔丁基酚的降解性能等研究。结果表明菌株经固定化包埋后,降解底物2,6-DTBP的能力大大提高。在100.0mg/L的初始浓度下其降解率在十二天可达到81%。通过对固定化菌株的降解反应过程的动力学分析,其对底物的降解反应符合一级动力学特征,当2,6-DTBP初始浓度为100mg/L时,固定化菌种其动力学常数为0.1232,半衰期为5.63day。扫描电镜观察到菌种在海藻酸钙包埋载体中能良好地生长和繁殖。