Study on the Ion Association in PVdF-based Gel Polymer Electrolyte

IntroductionGel polymer electrolytes were originally described byFeuillade and Perche[1]and further characterized byAbraham and Alamgir[2 ,3], and formed by trapping liquidorganic solutions in a polymer matrix. Compared with solidpolymer electrolytes , gel polymer electrolytes can contactwith electrode tightly and have a room temperatureconductivity of above 10-3S·cm-1,so they are of practicalinterest for the development of new-design,advancedlithiumbatteries . A variety of polymers as poly…     

抗蚜威在不同类型土壤中的残留消解动态研究

通过气相色谱法测定抗蚜威在不同类型土壤中的残留消解动态,结果表明:抗蚜威在灰钙土、灌漠土和黑垆土中施药6～7 d后的消失率达到90%以上,其消解方程分别为Ct=5.2575e-0.3905t、Ct=6.9821e-0.3289t、Ct=4.5910e-0.3919t.半衰期为T1.7～2.1 d,在土壤中的残留量随着时间延长而递减,符合一级反应动力学方程.抗蚜威属于易降解氨基甲酸酯类农药,施用后不会对土壤和环境造成污染.     

二氢杨梅素印迹聚合物的表面行为

应用前沿分析技术测定了二氢杨梅素印迹聚合物块的实验吸附等温线，并用Langmuir方程、Bi-Langmuir方程和Freundlich方程进行拟合，从最佳拟合求得了印迹聚合物的表面位点分布、吸附常数和饱和吸附量.测定了不同温度和不同流动相组成时分子印迹聚合物固定相的吸附等温线.结果表明：双朗格缪尔模型和福伦登里西模型均能给出较好的拟合效果.当20 ℃、四氢呋喃为流动相时，从Bi-Langmuir方程的最佳拟合参数得到第1类键合位点的键合常数和饱和吸附量分别为0.39 mL·mg^-1和133.23 mg·mL^-1，第2类键合位点的键合常数和饱和吸附量分别是135.07 mL·mg^-1和0.071 mg·mL^-1.     

催化极谱法测定土壤中的痕量镉

采用单扫描极谱法测定土壤中镉含量,确立了1%碘化钾-1.5%酒石酸钾钠-2%三乙醇胺-0.6%盐酸-9%磷酸测定体系.在此测定体系中,镉在滴汞电极上于-0.71V(相对饱和甘汞电极)处产生一灵敏催化极谱波,镉浓度在0.2ng/ml～1μg/ml范围内与极谱峰电流有良好线性关系,检出限为0.1ng/ml.该方法用于土壤样品测定的RSD为0.6%～9.5%,加标回收率为90%～110%.该方法操作简便,用于土壤样品测定的结果满意.     

The glass transition temperature and microstructure of polyurethane/epoxy resin interpenetrating polymer networks nanocomposites

GLASS TRANSITION TEMPERATURE (TG) HAS BEEN EXTEN- SIVELY STUDIED FOR MANY POLYMERS SINCE IT IS ONE OF THE MOST FUNDAMENTAL FEATURES RELATIVE DIRECTLY TO POLYMER PROPERTIES. IN GENERAL, INORGANIC NANOFILLERS DO NOT DI- RECTLY CONTRIBUTE TO THE TG OF THE MA…     

The contribution of root respiration to soil CO2 efflux in Puccinellia tenuiflora dominated community in a semi-arid meadow steppe

Rising atmospheric CO2 and temperature are altering ecosystem carbon cycling. Grasslands play an important role in regional climate change and global carbon cycle. Below-ground processes play a key role in the grassland carbon cycle because they regulate …     

Synthesis and photocurrent response of porphyrin-containing conjugated polymers

In recent years conjugated polymers have attracted considerable attention because of their potential appli- cations in the fields of light emitting diodes, photo- voltaic devices, and sensors[1―7]. In the fabrication of semiconductor photovoltaic devices…     

Temporal-spatial dynamics of distribution patterns of microorganism relating to biological soil crusts in the Gurbantunggut Desert

Biological soil crusts serve as an important biological factor contributing to the sand fixation. This study was conducted to investigate the temporal-spatial variability of microorganism in crusts relating to locations, soil layers of sand dunes and seasons. At moss-dominated inter-dune areas, higher soil nutrient and water concentrations were likely to maintain the microbial activities. Bacteria showed the highest capabilities of settlement and growth in inter-dunes in both spring and autumn. Soil water content reached the highest value in soil crusts in the inter-dune areas, especially in spring. Variations of quantities of actinomyces and fungi basically showed the consistent trend in different locations of sand dunes. With the deepening of soil layers, vertical distribution of quantities of each microorganism group showed different characteristics because environmental factors fluctuated in both spring and autumn. Among different microorganism groups, bacteria were predominant, actinomyces the next and fungi the least in both spring and autumn in all soil layers （0-20 cm）. The proportion of bacteria and soil water content were higher in spring than those in autumn in all soil layers （0-20 cm）. No consistent trends were found in actinomyces and fungi. The results showed that the quantities of microorganisms were significantly positive correlated with organic matter content, soil water content, total N, total P, available P, available K, pH, electrical conductivity, total salt content,catalase, urease, phosphatase and alkaline phosphatase.     

聚合物改性沥青及其性能评价方法

阐述了近些年来研究、应用较多的几种改性沥青,以及影响改性沥青性能的一些基本因素,并对评价改性沥青的一些新方法进行了介绍.     

锂离子电池用无纺布支撑聚合物复合膜的制备

采用γ射线辐射接枝的方法在无纺布纤维表面接枝苯乙烯。将接枝改性后的无纺布浸渍于丁酮/PVDF-HFP/丁醇混合液中,真空干燥后制得多孔的无纺布支撑聚合物电解质复合膜。以其为隔膜组装了聚合物锂离子电池(LiMn2O4/无纺布聚合物复合膜/Li),进行充放电测试。研究结果表明,无纺布聚合物复合膜具有合适的厚度,一定的机械强度。辐射接枝提高了无纺布与聚合物混合液的结合力,在电池的充放电循环过程中不易发生短路,电池的容量和循环性能得到显著提高。