Special IR properties of palladium nanoparticles and their aggregations in CO molecular probe infrared spectroscopy

Dispersed Pd nanoparticles (Pdn) have been synthesized by reducing H2PdCI4 with ethanol, and stabilized using poly(vinylpyrrolidone) (PVP). The Pdn is applied to the glassy carbon substrate to form a thin film, and then the potential cyclic scanning at 50 mV.s^-1 from -0.25 to 1.25 V was carried out for about 30 min to form the aggregations of Pdn (Pdn^ag). FTIR spectroscopy of both transmission and reflection modes was employed to study CO adsorption on Pdn and Pdn^ag in both solidlliquid and solidlgas interfaces. It has been revealed that CO adsorption on Pdn film yields two IRbands near 1964 and 1906 cm-1, which are assigned to IR absorption of CO bonded on asymmetric and symmetric bridge sites, respectively. In contrast to the IR properties of CO adsorbed on Pdn, only species of CO bonded on asymmetric bridge sites was determined on Pdn^ag, and the direction of the IR band near 1963 cm^-1 is completely inverted. The full width at half-maximum (FWHM) of the COB^as band near 1964 cm^-1 is measured to be 14 cm^-1 on Pdn film, while it is 24 cm^-1 on Pdn^ag film. The results of the present study demonstrated that the inverting of the IR band direction is a general phenomenon that is closely related to the interaction between nanoparticles in aggregation of Pdn.     

浅析形容词和"点儿"的搭配

将以形容词(A)与"点儿"组合成六种结构并以此作为分析对象,按A与"点儿"句法关 系的不同,对其进行分类说明、讨论,以明晰它们在语义上的特点和差别,以及各种格式中A的不同; 进一步归纳A在进入这几种格式时所应具备的条件。     

Science Letters：Synergetic effects for p-nitrophenol abatement using a combined activated carbon adsorption-electrooxidation process

A novel fluidized electrochemical reactor that integrated advanced electrochemical oxidation with activated carbon (AC) fluidization in a single cell was developed to model pollutant p-nitrophenol (PNP) abatement. AC fluidization could enhance COD removal by 22%-30%. In such a combined process, synergetic effects on PNP and COD removal was found, with their removal rate being enhanced by 137.8% and 97.8%, respectively. AC could be electrochemically regenerated and reused, indicating the combined process would be promising for treatment of biorefractory organic pollutants.     

嵌段共聚水溶性高分子在空气/水界面吸附态的构象

对于用几种不同疏水／亲水单体比合成的聚(丙烯酸丁酯／丙烯酸)共聚物样品测定了其水溶液的表面张力,运用Gibbs吸附方程求得在样品溶液临界胶束浓度时样品在气／液界面的分子吸附面积,以此推测其吸附态构象。结果表明,亲水单体单元在共聚物中含量多时,样品分子趋于在水中溶解;疏水单体单元多时,样品分子趋于在表面吸附。其吸附态构象为分子链上相邻的数个丁酯侧基吸附于水面,形成“薄煎饼状”疏水微区。     

对资本"物"的基础辨证

随着资本生产的发展,资本形态也呈现多样化趋势,资本生产中的"物"似乎越来越显得无足轻 重。但是,无论如何,"物"在资本生产中的基础地位是不会改变的,其它任何形态的资本都以"物"为基础或以 "物"为最终归宿;资本生产的历史也是从"物"开始的,离开物而谈资本不仅是不现实的,更为重要的是,空洞无 物的资本生产是根本不存在的。重视物态资本在生产中的基础地位和作用,是研究资本问题的逻辑起点,它不 应该被贬低而受到忽视。     

腐败问题的可拓分析

本首先简要介绍了已有的对腐败问题的研究,接着介绍了新兴科学--可拓学,并用其来解释了腐败产生的原因,最后,通过建立“腐败与反腐败”问题的物元分析模型提出了解决腐败问题的若干策略。     

氧化铝上吸附平衡与动力学的分形特性

在实验测定氧化铝吸附氮气的平衡和动力学过程的基础上,由平衡数据得到分形维数,对动力学结果分别用欧氏几何和分形几何的动力学模型进行处理,比较两种方法得到的扩散系数之间的判别。结果表明：粉状氧化铝的分形维数为2．12;采用分形动力学模型得到的扩散系数同欧氏几何扩散模型的结果不同一样,扩散系数不随浓度的变化而改变;而欧氏几何扩散模型中的扩散系数随浓度变化发生改变,且变化符合Darken关系。     

海水鱼类单殖吸虫的研究Ⅷ寄生于Xia虎鱼鳃上指环虫两新种及一中国新记录

我们在整理采于广西和海南的单殖吸虫标本时 ,发现寄生于虎鱼鳃上的指环虫两新种 .并确认二翼指环虫ＤａｃｔｙｌｏｇｙｒｕｓｂｉａｌａｔｕｓＷｕ ,Ｗａｎｇ＆Ｊｉａｎｇ ,1 988为棘虎伪指环虫ＰｓｅｕｄｏｄａｃｔｙｌｏｇｙｒｕｓｈａｚｅＯｇａｗａ ,1 984的同物异名 ,且棘虎伪指环虫为中国新记录 .现报道如下 ,新种的模式标本保存于华南师范大学生物系 .1 .钦州指环虫 ,新种Ｄａｃｔｙｌｏｇｙｒｕｓｑｉｎｚｈｏｕｅｎｓｉｓｓｐ ｎｏｖ .(图 1 -ａ ,ｂ )图 1　钦州指环虫 ,新种Ｄａｃｔｙｌｏｇｙｒｕｓｑｉｎｚｈｏｕｅｎｓ…     

CO adsorption on electrode of Pt nanoparticles investigated by cyclic voltammetry and <Emphasis Type="Italic">in situ</Emphasis> FTIR spectroscopy

Pt nanoparticles were prepared by the chemical reduction method.The average diameter of Pt nanoparticles was determined to be 2.5nm by TEM.The electrochemical propertis of Pt nanoparticles were studied by cyclic voltammetry,In comparison with massive Pt,the oxidation current peak of CO adsorbed on Pt nanoparticles in broader.Twin adsorbates of CO on Pt nanoparticles were determined by in situ FTIRS for the first time.It has revealed that the linear and twin-bonded CO can be converted into bridge-bonded CO with the variation of electrode potential.A series of special properties of Pt nanoparticles,such as enhanced IR absorption of CO adsorbates,were also observed.     

Pt羰基簇合物途径制备的Pt/C催化剂对甲醇的电催化氧化

通过Pt羰基簇合物在N2气氛下于150℃热分解制得了无定形的碳载纳米Pt催化剂。发现甲醇在这种催化剂上氧化的起始电位和峰电位均比在传统的液相还原法制得的Pt／C催化剂上发生了,负移,峰电流也有明显的增加,且稳定性好。表明通过Pt羰基簇合物热分解制备Pt／C催化剂是一种较好的制备甲醇氧化电催化剂的方法。