大跨度桥梁结构施工控制过程中的变形控制研究

以一座实桥为工程背景,对采用分节段悬臂浇筑施工的大跨度桥梁结构施工控制过程中的变形控制进行了研究,提出了变形控制过程和实现的方法．同时根据所采用国际通用大型计算软件一ANSYS软件,应用“生”、“死”单元的方法,建立了统一计算模型,即：全桥模型,减小了计算工作量．最后,通过对该实桥变形监控结果的分析,证明了本文所提方法的正确性和有效性．     

Special IR properties of palladium nanoparticles and their aggregations in CO molecular probe infrared spectroscopy

Dispersed Pd nanoparticles (Pdn) have been synthesized by reducing H2PdCI4 with ethanol, and stabilized using poly(vinylpyrrolidone) (PVP). The Pdn is applied to the glassy carbon substrate to form a thin film, and then the potential cyclic scanning at 50 mV.s^-1 from -0.25 to 1.25 V was carried out for about 30 min to form the aggregations of Pdn (Pdn^ag). FTIR spectroscopy of both transmission and reflection modes was employed to study CO adsorption on Pdn and Pdn^ag in both solidlliquid and solidlgas interfaces. It has been revealed that CO adsorption on Pdn film yields two IRbands near 1964 and 1906 cm-1, which are assigned to IR absorption of CO bonded on asymmetric and symmetric bridge sites, respectively. In contrast to the IR properties of CO adsorbed on Pdn, only species of CO bonded on asymmetric bridge sites was determined on Pdn^ag, and the direction of the IR band near 1963 cm^-1 is completely inverted. The full width at half-maximum (FWHM) of the COB^as band near 1964 cm^-1 is measured to be 14 cm^-1 on Pdn film, while it is 24 cm^-1 on Pdn^ag film. The results of the present study demonstrated that the inverting of the IR band direction is a general phenomenon that is closely related to the interaction between nanoparticles in aggregation of Pdn.     

Science Letters：Synergetic effects for p-nitrophenol abatement using a combined activated carbon adsorption-electrooxidation process

A novel fluidized electrochemical reactor that integrated advanced electrochemical oxidation with activated carbon (AC) fluidization in a single cell was developed to model pollutant p-nitrophenol (PNP) abatement. AC fluidization could enhance COD removal by 22%-30%. In such a combined process, synergetic effects on PNP and COD removal was found, with their removal rate being enhanced by 137.8% and 97.8%, respectively. AC could be electrochemically regenerated and reused, indicating the combined process would be promising for treatment of biorefractory organic pollutants.     

嵌段共聚水溶性高分子在空气/水界面吸附态的构象

对于用几种不同疏水／亲水单体比合成的聚(丙烯酸丁酯／丙烯酸)共聚物样品测定了其水溶液的表面张力,运用Gibbs吸附方程求得在样品溶液临界胶束浓度时样品在气／液界面的分子吸附面积,以此推测其吸附态构象。结果表明,亲水单体单元在共聚物中含量多时,样品分子趋于在水中溶解;疏水单体单元多时,样品分子趋于在表面吸附。其吸附态构象为分子链上相邻的数个丁酯侧基吸附于水面,形成“薄煎饼状”疏水微区。     

位移连续变更与极限状态函数的连续生成

基于我国《建筑结构设计统一标准》的极限状态设计原则,结构物不允许出现影响正常使用的外观变形,提出了刚架结构位移连续变更方法·用数值分析与递推公式相结合的方法,实现连续变更结构的变形极限状态函数的连续生成·重分析不必重新形成结构刚度矩阵,不必反复求逆矩阵,使得识别系统主要失效模式的方法得以简化,有效地提高了计算时效,并为刚度可靠性分析提供了新方法·算例验证了方法的正确性及实用性·     

氧化铝上吸附平衡与动力学的分形特性

在实验测定氧化铝吸附氮气的平衡和动力学过程的基础上,由平衡数据得到分形维数,对动力学结果分别用欧氏几何和分形几何的动力学模型进行处理,比较两种方法得到的扩散系数之间的判别。结果表明：粉状氧化铝的分形维数为2．12;采用分形动力学模型得到的扩散系数同欧氏几何扩散模型的结果不同一样,扩散系数不随浓度的变化而改变;而欧氏几何扩散模型中的扩散系数随浓度变化发生改变,且变化符合Darken关系。     

句法乎?语法乎?--"语法的三个平面学说"质疑

语法的三个平面的研究,形成了"结合论"和"包含论"两个不同的研究倾向."结合论"者把语法同语义、语用相并立,坚持语法的独立性或句法的纯洁性;"包含论"者认为语法中包含着句法的、语义的、语用的内容,应从句法、语义、语用这三个方面来对语法进行研究.关于是"句法"还是"语法"的看法,这绝不是一字之差的小问题,它导致了语法本体论的不同,并由此形成了不同的方法论,形成了不同的语法体系.     

应"知"还须"行"--思想品德教学中的几点体会

在思想品德教学中,要努力渗透道德认识和情感教育,质"知"、"行"统一,从三方面着手1、在情感熏陶中培养良好的道德基础和情感,奠定道德行为的基础;2、在道德评价中提高认识,指导行为;3、在实践活动中,锻炼思想,检验行为.     

Experimental study on centrifugal concrete-filled steel tubes under bending and torsion

A real-size experiment on 11 tubes was done to study the performance of centrifugal concrete-filled steel tubes under bending and torsion. This paper first introduces the relevant operating method, equipment, subjects and processes. The factors that affect deformation and stiffness and the break mechanism under different loading were studied. Experimental stress analysis showed that the values of practical critical stress of steel tubes accorded well with the MISES Yielding Rule. The correlative equation (on the bearing capacity of a structural member under bending and torsion) deduced in this study may provide valuable reference for the desima of this structural member.     

混凝土多轴性能试验装置

在5000kN压力机的基础上研制了一套混凝土多轴性能试验装置。该装置可进行平面应力平面应变以及一般三轴荷载等不同应力组合的混凝土强度和变形试验,并可适应多种试件形式。