4－氧代戊酸酯类缩酮的合成研究

本文以糠醇为原料，以醇作溶剂，在酸性条件下糖醇开环制得一系列乙酞丙酸酯类化合物。然后再以乙酞丙酸酯类化合物为原料，制得一系列未见报道的此类酯与醇的缩合产物，并用ＨＰ５９８８ＧＣ－ＭＳ联用仪研究了反应产物的组成。     

微波水相法合成外消旋1,1''''-联-2-萘酚

报道了以FeCl3·6H2O为氧化偶合剂,水为溶剂,利用微波辐射技术,快速合成了1,1′-联-2-萘酚.同时对影响收率诸因素进行考察,确定了最佳反应条件微波功率495 W,辐射时间40 s,n(β-萘酚)n(三氯化铁)=12,收率达91%.与常规方法相比,本实验方法具有产率高、反应时间短、产物易分离和反应条件温和等优点.     

丙烯酸异冰片酯-丙烯腈共聚合及其聚合物的性能

测定了丙烯酸异冰片酯(IBA)与丙烯腈(AN)的共聚合反应竞聚率。当M_1=AN,M_2=IBA,测得r_1=0.49,r_2=0.23。共聚物的拉伸与压缩强度较PIBA有较大提高;Tg值均在100℃以上,共聚物透明性好,折光指数n_D~(25)在1.5017～1.5068之间。     

《有机化学实验》教材中己二酸制备的改进

目前实验室制备己二酸的方法大部分采用环己醇经高锰酸钾氧化来制得,这种方法所耗用的氧化剂用量大,而且所制备出的已二酸实际产率不高。我们采用环己酮为原料来制己二酸,此方法可达到较理想的效果。改进后同样能使学生掌握实验技能,达到实验教学的目的,而且也节省了资金和时间。     

THE TRANSFER BEHAVIOUR OF SOME CATIONS AT WATER／NITROBENZENE INTERFACE BY SEMIDIFFERENTIAL CYCLIC VOLTAMMETRY

The transfer of Sr~(2+) and Ba~(2+) ion, facilitated by 18-Crown-6 present in the aqueous phase, and of succinylcholine ion at w/nb interface were investigated by semi-differential cyclic voltammetry. A good polarographic curve of succinylcholine ion dissolved in water was obtained in the system of 0.01 mol/l LiCl (w)——0.01 mol/l TBATPB (nb). The peak current is directly proportional to the concentration of SC~(2+) ion. It can be used for the determination of SC and the detection limit is 1.05×10~(-5) mol/l.The apparent D~w and D~(nb) have been estimated. The transfer of Sr~(2+) and of Ba~(2+) at the interface are facilitated by 18-Crown-6 present in the aqueous phase and the peak current is directly proportional to the concentration of 18-Crown-6 in water. This method can be used for the determination of the complexing agent and for the stability constant of the complex formed in the aqueous phase.All the experimental results are in keeping with the theoretical.     

HPA/MXOY杂多酸在合成异戊酯上的应用研究

本文研究了HPA/MXOY固体杂多酸催化剂的制备及负载,并以异戊醇合成异戊酯为探针,用硅盐、锆盐、活性炭等物质为载体,进行了催化效果的研究及表征。实验结果得出:HPA/ZrO型杂多酸催化剂效果最佳,酯收率可达82%。