林产化学工艺学课程教学改革的探索

林产化学工艺学课程是显现我校应用化学专业特色的选修课程之一.近年来,我们在该课程的教学内容、教学手段和考试方法等方面进行了大幅度改革,取得了良好的教学效果.     

镀镍废水资源化技术

项目简介: 电镀是一项应用很广的工艺手段,镀镍是电镀中主要的镀种.镀镍生产过程中因镀件清洗会产生大量含有金属镍离子的废水,目前这些废水一般采用化学沉淀法处理,实现达标排放,宝贵的水和金属镍资源流入环境,不仅浪费资源而且污染环境.     

Formation of ζ phase in Cu-Ge peritectic alloys

Rapid growth behavior of ζ phase has been investigated in the undercooling experiments of Cu-14%Ge, Cu-15%Ge, Cu-18.5%Ge and Cu-22%Ge alloys. Alloys of the four compositions obtain the maximum undercoolings of 202 K（0.17TL）, 245 K（0.20TL）, 223 K（0.20TL） and 176 K（0.17TL）, respectively. As the content of Ge increases, the microstructural transition of ＂a（Cu） dendrite ＋ ζ＂ peritectic phase → ζ＂ peritectic phase →, ζ dendrite ＋ （ε＋ζ） eutectic＂ takes place in the alloy at small undercooling, while the microstructural transition of ＂fragmented α （Cu）dendrite ＋ ζ peritectic phase →, ζ peritectic phase →ζ dendrite ＋ ε phase＂ happens in the alloy at large undercooling. EDS analysis of the Ge content in peritectic phase indicates that undercooling enlarges the solid solubility of ζ rdendrite, which leads to a decrease in the Ge content in ζ phase as undercooling increases. In the Cu-18.5%Ge alloy composed of ζ peritectic phase, the Ge content in ζ phase increases when undercooling increases, which is due to the restraint of the Ge enrichment on the grain boundaries by high undercooling effect.     

实现高校化学实验绿色化

文章介绍了绿色化学的定义和内涵,就实现化学实验绿色化问题提出了一系列措施,强调树立绿色化学的思想观念,增强环境保护意识;认识不到位,投资不足是其产生的主要原因;采用推广微型化学实验,推广连续合成实验和回收再利用,分类收集、区别处理等多种途径,探索出一套简便易行的实验室废弃物综合治理方法。     

A tubular focused sonochemistry reactor

This paper presents a new sonochemistry reactor, which consists of a cylindrical tube with a certain length and piezoelectric transducers at tube’s end with the longitudinal vibration. The tube can effectively transform the longitudinal vibration into the radial vibration and thereby generates ultrasound. Furthermore, ultrasound can be focused to form high-intensity ultrasonic field inside tube. The reactor boasts of simple structure and its whole vessel wall can radiate ultrasound so that the electroacoustic transfer efficiency is high. The focused ultrasonic field provides good condition for sonochemical reaction. The length of the reactor can be up to 2 meters, and liquids can pass through it continuously, so it can be widely applied in liquid processing such as sonochemistry.     

Determining method and conditional factors of electrochemical fingerprint of Chinese traditional medicine

The thermodynamic systems and kinetic model suitable for the electrochemical token of the compo-nent throng in Chinese traditional medicines have been analyzed. It has been indicated that the damp oscillatory reactions in the non-equilibrium close system and open system without the supplement of dissipative substance have important significance for the throng token and analysis of chemical com-ponents in Chinese traditional medicines. Various factors influencing the electrochemical fingerprint,such as reactant species and their concentrations,electrode types,temperature,stir rate,the kind,dosage and granularity of Chinese traditional medicines,have amply been researched by the B-Z os-cillatory reaction which used malonic acid as a main dissipative substance. In addition,the quantitative information about the chemical components in Chinese traditional medicines has been discussed in detail. The method and its conditions for determining the electrochemical fingerprint used in scientifi-cally distinguishing and evaluating Chinese traditional medicines have successfully been put forward.     

固态有机反应研究进展

综述了近年来固态有机反应的最新进展,包括固态有机反应的常用方法和固态有机反应在氧化反应、还原反应、偶联反应、重排反应、加成反应等重要反应类型中的应用以及固态有机反应在工业中的应用情况.     

苏州科技学院研究生导师王彦林教授

1957年4月生，河南兰考人，中共党员，教授。1981年12月毕业于郑州大学化学系，1982年1月至1987年5月在河南开封染料化工厂负责新产品开发工作，1987年6月至2002年6月在河南大学化学化工学院任教，2002年7月至今在苏州科技学院化学与生物工程学院任教。[第一段]     

采用气相色谱-质谱法分析药对麻黄-羌活的挥发油

采用气相色谱-质谱(GC-MS)法分离测定了药对麻黄-羌活、单味药麻黄和羌活的挥发油,并对其重叠色谱峰采用化学计量学解析法进行了分辨,得到药对和各单味药的纯色谱曲线和质谱。药对麻黄-羌活、单味药麻黄和羌活分辨出的色谱峰,通过质谱库对其进行定性,分别得到58,51和52个定性结果,占总含量的83.75%,88.70%和80.79%。实验结果表明:药对麻黄-羌活中挥发油化学成分有40种来自羌活,13种来自麻黄,新产生了10种化合物。     

中国科学院成都有机化学有限公司

按照中国科学院知识创新工程的总体战略和布局调整,由创立于1958年的中国科学院成都有机化学研究所整体转制组建的中国科学院成都有机化学有限公司成立于2001年6月,是高技术创新和产业发展并重的化工和材料领域的高新技术企业。