Acyl-chloride functionalized graphene oxide chemically grafted with hindered phenol and its application in anti-degradation of polypropylene

In this study,graphene oxide (GO) nanosheets were first functionalized by the acyl-chloride reaction and then reacted with hindered phenol (HP) to obtain HP grafted GO (GO-g-HP).The GO-g-HP prepared under the optimized condition exhibited a high efficiency against both thermal and photo oxidation of isotactic polypropylene (iPP).GO-g-HP exhibited a much better anti-aging efficiency than that of HP and GO used individually or that of their physical mixture.The outstanding anti-aging effect of GO-g-HP was attributed to the excellent synergistic effect produced between the chemically bonded GO and HP,which resulted in an improved oxygen barrier property of GO and excellent utilization of the free radical scavenging capability of GO and HP.Also,thanks to the grafting of HP on GO,the physical loss of HP,which was one of the main shortcomings for traditional small molecular antioxidants,was largely suppressed.It is expected that the GO-g-HP prepared can well meet the requirement of long-term applications of polymers in some harsh service conditions.     

双层钙钛矿Sr2FeMoO6，Ba2FeMoO6的电磁性质研究

分析了双层钙钛矿结构的锰氧化合物Sr2FeMoO6,Ba2FeMoO6物相结构和电磁学性质,对巨磁阻效应进行了探讨,揭示了Sr2FeMoO6样品为半导体导电性,Ba2FeMoO6样品为金属导电性.     

椭圆偏振法研究四方氧化锆对Zr-Sn-Nb合金氧化膜耐腐蚀性能的影响

将经过不同热处理的Zr-Sn-Nb合金样品放在350℃、16．8mol／LPa、0．01mol／LLiOH溶液的高压釜中进行腐蚀。用椭圆偏振法研究氧化膜中的四方氧化锆，发现经过580℃／冷轧／500℃处理的样品在腐蚀42天和190天后氧化膜中的四方氧化锆比其它样品的多。四方氧化锆是影响合金耐腐蚀性能的一个主要因素，四方氧化锆的形成有利于提高合金的耐腐蚀性能。     

高效多功能固态发射组件控保电路

固态雷达发射组件是有源阵的关键部件，而控保电路是实现固态脉冲功放的重要部分。本文介绍了为雷达第一级固态发射组件研制的高效多功能控保电路以及它的实践情况。     

固相微萃取法-气相色谱-质谱联用技术简化分析生活污水

用不同的固相微萃取（SPME）针头结合气相色谱－质谱分析对生活污水进行提取、浓缩、分离、测定，对照结果表明，用聚硅氧烷涂层可以减少一次分析化合物的种类，提高分析的准确性。     

双金属氧化物和氧化物载体组分间的相互作用

讨论了一些过渡金属氧化物（NiO,CuO或MoO3)在经改性所得复合载体（TiO2-γ-Al2O3，MoO3-t-ZrO2或NiO-t-ZrO2)上的分散作用，这些三地体系中实验测定的氧化物分散容量与研究负载型二元氧化物体系所得嵌入模型的估算值基本相符；样品的表面组成、结构和性能与载体的表面结构、过渡金属氧化物的负载量和加料顺序以及焙烧温度密切相关。     

负载型金属氧化物常温精脱硫剂的制备与表征

以γ—Al2O3为载体，用浸渍沉淀法制备复合金属氧化物脱硫剂，添加竞争吸附剂得到高分散、均匀型金属氧化物精脱硫剂。常温、缺氧条件下精脱H2S穿透硫容可达16．8％．采用EP、TEM技术分析了金属氧化物活性组分的均匀分布及脱硫前后的脱硫剂微表面的变化。     

Nitric oxide suppresses stomatal opening by inhibiting inward-rectifying K_(in)~ channels in Arabidopsis guard cells

We explore nitric oxide (NO) effect on K in channels in Arabidopsis guard cells. We observed NO inhib- ited K in currents when Ca2 chelator EGTA (Ethylene glycol-bis(2-aminoethylether)-N,N,N′,N′-tetraacetic acid) was not added in the pipette solution; K in currents were not sensitive to NO when cytosolic Ca2 was chelated by EGTA. NO inhibited the Arabidopsis stomatal opening, but when EGTA was added in the bath solution, inhibition effect of NO on stomatal opening vanished. Thus, it implies that NO ele- vates cytosolic Ca2 by activating plasma membrane Ca2 channels firstly, then inactivates K in chan- nels, resulting in stomatal opening suppressed subsequently.     

基于ZnO纳米结构的H_2、NH_3气体敏感性研究

通过简单的水热法在金电极上制备了氧化锌纳米棒,从而制成了气体传感器.研究了氧化锌纳米棒的结构和特性,发现用该材料制成的气体传感器对于500 ppm的NH3和H2在150 ℃下有较灵敏的反应,并探讨了产生传感效应的机理.该传感器制备方法简单、廉价、环保,适合大批量生产,有望应用于工业生产和日常生活的气体探测.     

固体导弹采用导管的分析研究

固体导弹由于测压、安全、关机与点火等的需要,采用的管路系统越来越多、越来越复杂,本文讨论了避免采用管路系统的重要性、可能性与具体方案,提出应严格制定并不断完善研制规范、加强管路系统的地面试验。