纳米固体超强酸SO42-/ZnO催化合成乙酸异戊酯的研究

本文利用纳米固体超强酸SO4^2-/ZnO催化合成乙酸异戊酯的最佳反应条件,既反应时间2.0h,催化剂用量为酸质量的1.0%,酸醇比为1∶2,验证实验产率为96.7%,且该实验反应时间短,无腐蚀无污染,催化剂可回收可重复利用.     

220KV变压器常见故障处理分析

文章介绍了电力变压器的常见故障,并对消除故障的方法进行了归纳总结,具有一定的工程实用价值。     

Chemical composition of decomposing stumps in successive rotation of Chinese fir （Cunninghamia lanceolata （Lamb.） Hook.） plantations

Decomposition of stumps in successive rotation of Chinese fir （Cunninghamia lanceolata （Lamb.） Hook.） plantations was studied using a chronosequenee approach. The results showed that decomposition rate constant of Chinese fir stump was 0.02695 as calculated from Olson＇s model. The N content of stump increased during the first two-year decomposition. When the dead stump C/N ratio was 463.2 ± 27.3, the stumps started to release N. The pattern of P release was similar to that for N. However, K content of stumps showed a consistent declining trend over time during the whole decomposition. ^13C nuclear magnetic resonance spectroscopy with cross polarization and magic-angle spinning （^13C CPMAS-NMR） was used to analyse organic carbon （C） components in decomposing stumps. The ^13C CPMAS-NMR spectra of stumps displayed that stump was dominated by cellulose and hemieellulose. The spectra also showed the accumulation of intensity in alkyl C, aromatic C, and earboxyl C spectral regions, which was expected as the labile cellulose and hemieellulose components in O-alkyl C spectral region were selectively decomposed first.     

600MW火电机组出线降压改造

目前，湖南省内大部分600Mw火电机组出线均接500kV输电线路，由此造成区内高负荷时段500kV系统下网负荷较高，电网安全供电局面被动．针对以上情况，本文介绍了将600Mw火电机组由500kV系统改接至220kV系统的改造方法．对某电力公司的火电机组进行改造后，机组开机一次并网成功，并网安评一次通过．项目实施的成功可为同类机组的相关改造提供参考．     

220kV及以上电压输电线路的继电保护可靠性及状态检修研究

传统220kV及以上电压输电线路的继电保护可靠性及状态检修过程实现过程复杂,且容易受到外界环境的干扰,导致可靠性及状态检修研究结果不准确。因此研究了一种新的继电保护可靠性及状态检修过程,根据220kV及以上电压输电线路继电保护装置自身特点,对干扰其可靠运行的因素进行分类,构建相应的故障树模型,通过马尔科夫矩阵转移法计算继电保护装置的可用度和发生故障的概率,研究了装置硬件和软件的可靠性。经实例分析发现,继电保护装置的可用度随检修效率、状态评估效率和检修工人效率的增大呈先增加后不变的趋势。分析了检修周期对继电保护装置可靠性的影响,在此基础上研究了继电保护状态检修过程。     

蕴含Ar＋1^（m）-可图序列刻划定理的一个构造性证明

采用构造性方法证明了蕴含Ar＋1^（m）-可图序列刻划定理．     

Fission Yield Data Systematics for ^238U

Based on the mass distribution data up to 200 MeV measured by Zoner with kinetic energy method （corrected）, the systematics on dependence of chain yield on incident neutron energy for each mass number A with a linear and quadric function was studied. And also the systematics of mass distribution on mass A and incident neutron energy was investigated by using 5 （or 3 ） Gaussian model. A code of nonlinear squared least method was developed and the parameters were deduced by fitting the experimental data. The calculated results with the parameters obtained could reproduce the experimental data used well. But comparisons with the data measured by radiochemistry method show some systematical difference. It is shown that there is some systematical difference between the measured data with kinetic and radioactive nuclide methods, the masons of which need to be investigate further.     

超强酸催化有机酸衍生化分离分析研究

固体超强酸具有较高的反应活性和较好的选择性．文章研究了玫瑰茄油在固体超强酸催化下合成高级脂肪酸脂．再采用GC—MS对其中的脂肪酸进行了定性和定量分析．玫瑰茄油中各种脂肪酸的质量分数分别为棕榈酸18%；硬脂酸30%；油酸38%；亚油酸14%。     

焙烧温度对S2O8^2-／ZrO2介孔超强酸的结构与性能的影响

以硝酸锆为锆源,以阴离子表面活性剂十二烷基硫酸钠（SDS）为模板剂,S2O8^2-浸渍无定形Zr（OH）4,制得介孔S2O8^2-／ZrO2固体超强酸,通过N2吸附－脱附、XRD分析、Hammett非水滴定、TEM等方法,考察了不同焙烧温度对S2O8^2-／ZrO2介孔超强酸晶体结构、酸强度等性能的影响。结果表明,当焙烧温度600℃,S2O8^2-／ZrO2样品比表面积为140m2／g,平均孔径在3～4nm之间,酸强度H0≤-12．7,为介孔相固体超强酸。     

EX220-3型挖掘机执行机构联合作业不协调的故障诊断与排除

EX220-3型挖掘机是日本日立建机公司生产的小型履带式挖掘机,该挖掘机有工作装置、上部转台和行走装置3部分组成。该型挖掘机执行机构联合作业不协调,是典型的流量分配控制系统问题,详细分析执行机构流量分配控制系统原理及其故障诊断与排除的方法,这对该型号的挖掘机执行机构的联合作业不协调的故障诊断起到一定的指导作用。