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281.
MPA包覆的银纳米粒子修饰电极制备和电化学表征 总被引:1,自引:0,他引:1
运用自组装和电化学组装法,将MPA包裹的银纳米粒子修饰到金电极表面,制备成银纳米粒子单层和多层膜修饰电极. 循环电压-电流和电化学阻抗谱测定结果表明:以MPA包覆的银纳米粒子修饰电极的氧化电位明显负移,显示出银纳米粒子具有更高的活性. 以0.5mmol/L的K3[Fe(CN)6]溶液为检测体系,电化学阻抗谱测试得出电极表面对探针分子的阻碍作用有所增加. 循环电压-电流结果表明:与单层膜修饰电极相比,多层膜修饰电极的峰电流显著增加. 相似文献
282.
用光谱法研究了带有吩嗪基团的酚藏花红与DNA的相互作用.研究表明,酚藏花红能嵌入到DNA骨架的碱基对之间,在实验允许的误差范围内,用不同的光谱法测得的结合常数一致,均为104L·mol-1数量级,结合位点数约为7.阴离子KI的荧光猝灭实验进一步证实了酚藏花红与DNA之间的嵌入作用.该研究为以DNA为靶的药物设计提供了一种新的嵌入剂功能团. 相似文献
283.
284.
电极结构对介质阻挡放电(DBD)的特性有重要影响,研究DBD的电极结构以及等离子体参数对优化DBD反应器运行参数和提高放电效率具有重要意义.针对于此,本文研究了交流电源激励下的双电极DBD和三电极DBD的放电特性,比较了它们的放电图像,电压和光信号波形的异同,不同电压幅值下放电参量的变化,以及放电在300~800 nm的发射光谱.结果表明,双电极DBD和三电极DBD由于放电装置的不对称性,正负半周期的放电均存在不对称性;发射光谱中都包含N2的第二正带系(C-B)(含波长为337.1 nm的谱线),N2的第一正带系(B-A),N+2的第一负带系(A-X)(含波长为391.4 nm的谱线),以及777.4 nm处氧原子谱线,但相对强度不同;与双电极DBD相比,三电极DBD具有起始电压低,放电产生活性粒子多,发光强度大的特点. 相似文献
285.
研究北祁连造山带玉石沟橄榄岩中富甲烷流体包裹体。激光拉曼光谱原位分析结果显示, 这些流体包裹体主要由液态或气态 CH4+C(石墨)组成, 次要成分为N2, H2O, C2H6和C3H8, 代表还原性的C-H流体形式。根据石墨的拉曼特征谱峰, 利用石墨化碳质拉曼光谱(RSCM)温度计计算石墨形成温度, 结果指示石墨在流体中沉淀的最低温度介于430~590°C之间, 表明CH4+C是非生物成因的, 并形成于地幔环境。 相似文献
286.
For this study, we synthesized Aurivillius Bi5Ti3FeO15 ceramic using the generic solid-state reaction route and then performed room-temperature X-ray diffraction to confirm that the compound had a single phase with no impurities. The surface morphology of the prepared sample was observed to contain microstructural grains approximately 0.2–2 μm in size. The dielectric properties of the sample were determ-ined as a function of frequency in a range of approximately 100 Hz to 1 MHz at various temperatures (303 K ≤ T ≤ 773 K). Nyquist plots of the impedance data were found to exhibit a semi-circular arc in the high-temperature region, which is explained by the equivalent electrical circuit (R1C1)(R2QC2), where R1 and R2 represent the resistances associated with the grains and grain boundaries, respectively, C1 and C2 are the re-spective capacitances, and Q is the constant phase element (CPE), which accounts for non-Debye type of behavior. Our results indicate that both the resistance and capacitance of the grain boundaries are more prominent than those of the grains. The alternating current (ac) conductiv-ity data were analyzed based on the Jonscher universal power law, which indicated that the conduction process is dominated by the hopping mechanism. The calculated activation energies of the relaxation and conduction processes were very similar (0.32 to 0.53 eV), from which we conclude that the same type of charge carriers are involved in both processes. 相似文献
287.
Cobalt (Co)-modified brownmillerite KBiFe2O5 (KBFO; [KBiFe2(1?x)Co2xO5 (x = 0, 0.05)]) polycrystalline is synthesized following the solid-state reaction route. Rietveld refinement of X-ray diffraction data confirmed the phase purity of KBFO and KBiFe1.9Co0.1O5 (KBFCO). The optical bandgap energy (Eg) of KBFO decreased from 1.59 to 1.51 eV because of Co substitution. The decrease in bandgap can be attributed to the tilting of the Fe–O tetrahedral structure of KBFCO. The observed room-temperature Raman peaks of KBFCO shifted by 3 cm?1 toward a lower wavenumber than that of KBFO. The shift in Raman active modes can be attributed to the change in the bond angles and bond lengths of the Fe–O tetrahedral structure and modification in response to oxygen deficiency in KBFO because of Co doping. Compared with that of KBFO, the frequency-dependent dielectric constant and dielectric loss of KBFCO decrease at room temperature, which is a con-sequence of the reduction in oxygen migration and modification in response to vibrational modes present in the sample. 相似文献
288.
随着红外探测器性能的不断提升, 红外目标跟踪在智能安防等领域的应用越来越广泛。然而红外图像分辨率较低, 依赖其进行目标跟踪仍然是一个制约相关应用发展的难题。针对红外图像分辨率低的特点, 以多域网络为模型算法框架, 结合目标运动过程中的尺寸变化特点, 提出了一种基于多域网络的红外目标跟踪算法。为了评估算法性能, 分别在VOT-TIR2016数据库和AMCOM红外数据上进行了实验。实验结果表明, 目标尺度预测机制能够显著提高算法的跟踪精度。 相似文献
289.
290.
C. S. Champion D. Kumar M. T. Rajan K. S. Jagannatha Rao M. A. Viswamitra 《Cellular and molecular life sciences : CMLS》1998,54(5):488-496
Spectroscopic study of the interactions of metal ions, Co, Mn, Mg and Al with d(GCCCATGGGC) and d(CCGGGCCCGG) revealed the
following. Metal ions Mn, Al and Mg at the lowest concentrations enhanced the t
m of oligomers, whereas Mn and Mg at higher concentrations decreased the t
m . Co enhanced the t
m of oligomers at higher concentrations. The studies have also indicated that Mn at lower concentrations displaced EtBr fluorescence,
Mg and Co at moderate concentrations and Al only at higher concentrations. Addition of Co, Mn, Mg and Al altered the bands
of the circulars dichroism (CD) spectra of the oligomers in a concentration-dependent manner. The CD spectra of d(GCCCATGGGC)
and d(CCGGGCCCGG) indicated B and Z forms of DNA, respectively, in contrast to the A form observed in the crystal structures.
Mg and Co at different ionic strength induced Z–B transition in d(CCGGGCCCGG), while Al at higher concentrations induced a
Z–A transition. Mn did not induce any transition. This is the first report to show that Al causes structural transitions in
sequence-specific oligomers and has strong binding ability with GC-rich euchromatin oligomers.
Received 22 December 1997; received after revision 16 March 1998; accepted 16 March 1998 相似文献