浅谈大气中NOx污染控制对策

氮氧化物（NOx）是造成大气污染的重要前体物,可以造成肺、皮肤癌、白内障以及呼吸道等呼吸系统疾病,是治理大气污染的一大难题.目前氮氧化物的控制存在五方面的问题,针对其提出以下七方面控制氮氧化物排放量的对策：加强基础研究和技术开发及推广,理清管理思路,加强减排管理;建立科学合理的统计方法,确定排放清单;实施多指标综合管理;开展NOx区域联防联控;建立减排监督机制;加快示范工程建设.     

660MW超临界锅炉降低NO_X排放的调整优化

本文介绍了NOX产生的条件、控制手段以及火力发电厂中降低NOX排放的技术。结合河北某电厂4号锅炉所进行的低NOX燃烧调整试验,说明了所采取的优化措施,以及在实际运行中所取得的较好的优化效果。对于火电厂降低NOx排放、运行方式优化和节能减排工作有着一定的参考价值。     

NO_x在大气环境中的化学行为及生态效应

系统地综述了ＮＯｘ 在光化学烟雾、酸雨、臭氧层消失和温室效应几个极为重大的环境问题中所起的作用，并对由此产生的生态效应进行了论述     

Integrated modeling of nitrogen oxides formation in diesel engines

To account for the effects of both chemistry and flow turbulence, the present study proposes an integrated NO sub-model that combines the extended Zel'dovich mechanism and engine CFD computations to simulate the NO histories in a diesel engine. NOx sub-model parameters and pollutant formation mechanisms can be more easily investigated by solving the NOx sub-model. The new NO formation model incorporating the effects of both chemical kinetics and turbulent mixing was applied to simulate a diesel engine with a quiescent combustion chamber, and one with a re-entrant combustion chamber; the premise of the model being the reaction rate is mainly determined by a kinetic timescale and a turbulent timescale. The results indicate that the predicted NO formulation from the new model agrees well with the measured data. As the utilization of fossil fuels continues to increase, the control of NOx emissions is a worldwide concern; and it is imperative to understand fully the NOx reaction processes in combustion systems. This technology has the potential to enhance the application of various combustion techniques used to reduce NOx emissions from practical combustion systems.     

低温等离子体净化NOx的实验研究

本文旨在通过实验对等离子体技术净化NOx进行研究，为该技术的进一步发展提供理论和实验依据。实验中采用低频高压脉冲电源与等离子体发生器来净化NOx，检验了不同电压和频率，以及不同气体成分对净化效果的影响．实验证实低温等离子体技术对NOx的净化效果较好。对NOx的净化率可达65．8％；通过提高脉冲电源的电压和频率，可进一步提高净化效果．尤其是在实验中发现C3H6对氨氧化物的净化具有重要作用。对NOx的净化率，可从没有C3H6情况下的30．40％，提高到有C3H6情况下的约60％。该技术特性在汽车尾气处理、工厂烟气脱硝等领域，可望具有较好应用前景．     

减少空气污染物的主要途径

本文概述了空气污染物对人类、动植物生长和大气环境的损害及影响,较详细阐述各种动力装置的主要排放物和光化烟雾特性,最后论述了目前减少污染物的主要方法。     

络合吸收烟气脱氮体系中FeⅢ(NTA)的生物还原

利用驯化得到的微生物对FeⅢ(NTA)的还原进行了研究.结果表明,葡萄糖比柠檬酸钠、乙醇、甲醇更适合于作为体系的碳源;反应最适pH值范围为5~8;温度在30~40℃之间变化,FeⅢ(NTA)还原率相差不大,温度大于40℃以后,还原率随温度升高而急剧下降.碳源量和菌体接种量满足还原反应需要即可,过量碳源或菌体接种量对还原率没有明显的促进作用.在实验考察的浓度范围内(0~24 mmol/L),FeⅢ(NTA)对微生物还原没有抑制作用.     

大气中氮氧化物的污染与防治

分析讨论了氮氧化物(NOx)对环境造成的污染问题，在此基础上提出了控制氮氧化物排放量的防治对策。     

A New Process Study on Comprehensive Utilization of NOx from Nitric Acid Plant

Based on studies of controlling NOx from nitric acid exhaust gas domestic and abroad, this paper has developed a new technique on removal of NOx and production of a by-product with high added value-- MnO2. Experiment shows, pyrolusite, whose valid composition is MnO2, of absorbing NOx has the following characteristics: quick, low cost, no secondary pollutant. Moreover, exhaust gas can attain the required standards. If the temperature of the pyrolusite serum is 30℃, pH=4, containing 90 g/L MnO2, the absorptivity for 3 000 mg/m3 NOx is 89.2%. Furthermore,few of the impurities in pyrolusite dissolve in the absorption mother solution. The purification cost of product is very low.The purity of end product MnO2 is more than 99. 995% after purifying. Therefore, it is workable for the new technique on economy and technology. There are also obvious environmental benefits and marked economic returns.     

己二酸生产中亚硝气的回收工艺研究

神马集团尼龙化工公司己二酸生产中亚硝气的回收工艺、原理有显著特点,通过对影响其稳定运转的因素进行了初步探讨,为己二酸生产装置长期运转提供了理论参考和现实依据。