应用耦合法计算大型铝电解槽的电流场

本文建立了大型铝电解槽电流场的数学模型,应用有限元和边界元耦合法进行计算,方便地处理了阴极炭块的非均匀正交各向异性问题;在计算中使用了具有场域自动剖分,矩阵分块,矩阵行优化排序和非零存贮等稀疏矩阵技术的计算程序,在对多种结壳情况下铝电解槽电流场的数值计算结果进行分析的基础上,得出了一种使铝液中水平电流较小的结壳形状。     

AACH热解法制备纳米氧化铝粉体

以NH4Al(SO4)2和NH4HCO3为原料,用沉淀法在搅拌转速10000r/min,1%(质量分数)分散剂PEG1000,陈化15h的条件下制备了氧化铝前驱体碳酸铝铵(AACH)。经850℃×30min煅烧制得了粒度为20～30nm,比表面积为245.8m2/g,形貌为球形的纳米γAl2O3,并研究了AACH焙烧过程中晶体结构的变化。研究表明:搅拌强度、有机表面活性剂、陈化时间对前驱体晶体结构有重要影响。γAl2O3的粒径分布及形貌与AACH的粒径分布及形貌有密切的关系;强化搅拌及添加有机表面活性剂对阻止纳米颗粒的团聚有较好的效果;室温下陈化时间超过30h,前驱体形貌有转变为棒状的趋势。     

铝合金切削加工条件选择及其切削加工性能改善

铝合金的切削加工主要是车、铣加工,本文阐述了刀具材料的选择、典型切削参数以及改善铝合金切削加工性能的措施。     

过碳酰胺施用对中国南方六种土壤pH及活性铝短期变化的影响

为了研究施用过碳酰胺后中国南方6个酸性土壤pH值及活性Al的短期变化,进行了实验室模拟土培试验．结果表明：对6种酸性土壤施用不同浓度过碳酰胺,其pH值在短期内都随着施入过碳酰胺浓度的增大而急剧上升,交换性铝含量随着施用过碳酰胺浓度的增大而急剧下降;施用过碳酰胺后,土壤pH值上升的现象是短期的,pH值达到最大值后缓慢下降,而土壤中铝元素的有效性与土壤pH的变化趋势呈显著负相关;短期内,经过碳酰胺处理的玉米幼苗主根明显缩短,侧根生长受到抑制,并且其玉米铝毒明显重于不经过碳酰胺处理的玉米,被玉米吸收的铝主要分布在玉米的地下部分,只有较少的铝被转移到地上部分．     

有序Ni纳米线阵列的样模制备法及其磁单畴特性

研究以多孔氧化铝为样模通过电沉积制备金属Ｎｉ的有序一维纳米线阵列,对其形貌和结构进行了表征,并测量了有序Ｎｉ纳米线阵列的磁滞回线。结果表明：以多孔氧化铝为样模所制得的Ｎｉ纳米线尺寸均匀、排列有序且直径和长度可在一定范围内任意调节;直径为１０ｎｍ,长达８μｍ的Ｎｉ纳米线阵列在磁性质上表现出显著的磁单畴特性。     

TiN/Al复合材料的微观组织及性能研究

用熔铸法制备了TiN/Al复合材料,通过SEM和EDS研究复合材料的微观组织和元素组成;测定了复合材料的布氏硬度和压缩性能.实验结果表明：用熔铸法制备TiN/Al复合材料,其增强相TiN均匀分布在基体中,随TiN含量的增加TiN由颗粒状、短棒状变成长条状;其布氏硬度和压缩强度随TiN含量的增加而增大.     

基于壳体的液压电机泵轻量化研究

为了进一步减小液压电机泵样机的质量,通过采用轻质材料以及合理减小结构尺寸的方法对液压电机泵壳体进行了轻量化设计,应用ANSYS软件对轻量化壳体的强度、刚度进行了分析,同时校核了钢铝连接中的螺栓强度。研究发现,液压电机泵壳体有较大的改进空间,采用6061铝合金材料及结构尺寸优化后,壳体能够满足强度、刚度的要求,且质量减小了70.1%,可见液压电机泵基于壳体的轻量化设计具有明显的效果。     

基于化学成分的铝合金热变形抗力模型

现有的铝合金变形抗力模型只针对具体牌号合金,之间没有联系,一旦成分变化就不再适用了。为了克服这个问题,本文对21种热成形典型铝合金以Hansel–Spittel模型为基础,对其模型系数A,m1,m2,m3,m4进行基于化学成分的线性拟合,建立了Hansel–Spittel模型系数的化学成分模型,进而获得基于化学成分和高温变形参数的热变形抗力模型,经检验所得模型具有较好的精度。     

Synchrotron X-ray diffraction techniques for in situ measurement of hydride formation under several gigapascals of hydrogen pressure

The high-pressure technique is a fundamental tool for realizing novel phase transitions, chemical reactions, and other exotic phenomena. Hydrogenation is one example of a high-pressure reaction; at high pressures of several gigapascals, hydrogen becomes chemically active and reacts with metals and alloys to form hydrides. This paper covers a high-pressure study of the hydrogenation process and the synthesis of hydrides using a cubic-type multi-anvil apparatus. The experimental details of a hydrogenation cell assembly, high-temperature and highpressure generation, and an in situ observation technique are presented. These experiments are conducted with the aid of in situ synchrotron radiation X-ray diffraction measurements operated in an energy-dispersive mode in the conventional manner for time-resolved measurements and a newly developed angle-dispersive mode for observation of the crystal growth process during formation of metal hydrides. Two successful cases of high-pressure hydrogenation are presented： aluminum hydride, Al H3, and an aluminum-based alloy hydride, Al2 Cu Hx, which are potential candidates for hydrogen storage materials.     

Performance Research of UPR/Al_2O_3 Composite Particles

UPR/Al2O3 composite particles were synthesized from unsaturated polyester resin(UPR) and nanometer/ultra-fine Al2O3 powders by means of suspension polymerization.The effects of Al2O3 with two different particle diameters on the density and hardness of the composite particles during the synthesis were studied.The results show UPR/Al2O3 composite particles synthesized by suspension polymerization are spherical,smooth,with a yield of 60%～75%(wt),and the particle diameters are 140～250μm;Al2O3 can effectively improves the density and hardness of the composite particles;when the contet is the same,effect of ultra-fine Al2O3 on the density and hardness of the composite particles is better than that of nanometer Al2O3;When the mass fraction of Al2O3 is 55%,the maximum hardness of ultra-fine Al2O3 composite particles and nanometer Al2O3 composite particles are 39.42HV and 25.66HV respectively.