Co2+离子在CsMgCl3晶体中的g因子和超精细结构常数研究

用基团模型的3d^7离子在三角对称下的高阶微扰公式计算了CsMgCl3晶体中Co^2＋杂质中心的g因子g∥,g⊥和超精细结构常数A∥和A⊥。计算中，不仅考虑了基态和激发态间的组态相互作用效应，而且考虑了3d^7离子d轨道与配体p轨道之间的共价效应，与这两种效应相关的参数可由所研究晶体的光谱和结构数据得到。在考虑了键长与键角的微弱畸变后，理论计算值与实验观测值符合较好。     

溶胶凝胶法制备三维规则排列大孔TiO2材料

以聚苯乙烯微球 (LatexSphere)离心后形成的三维规则排列的胶晶 (colloidcrystal)作模板 ,用钛酸丁酯、水、乙醇等配制的溶胶填充微球之间的间隙 ,然后原位形成凝胶 ,最后通过焙烧除去微球得到三维规则排列大孔TiO2 材料 (3DOM)。溶胶的浓度一般控制在 0 5～ 1 0md/L之间。焙烧过程的升温速度应控制在 5℃ /min以下。得到的样品表面可观察到五颜六色的彩光。从SEM照片可观察到 ,球形孔大小均匀 ,排列整齐 ,孔壁填充完全。孔径在 5 30nm左右 ,孔的排列呈面心立方结构 ,孔与孔之间由小孔窗相互交连。XRD表明孔壁含有锐钛矿和金红石两种晶型 ,2种晶型质量分数大约各占 5 0 %。     

Accurate forecasting of the undecided population in a public opinion poll

The problem of pollsters is addressed which is to forecast accurately the final answers of the undecided respondents to the primary question in a public opinion poll. The task is viewed as a pattern‐recognition problem of correlating the answers of the respondents to the peripheral questions in the survey with their primary answers. The underlying pattern is determined with a supervised artificial neural network that is trained using the peripheral answers of the decided respondents whose primary answers are also known. With peripheral answers as inputs, the trained network outputs the most probable primary response of an undecided respondent. For a poll conducted to determine the approval rating of the (former) Philippine president, J. E. Estrada in December 1999 and March 2000, the trained network predicted with a 95% success rate the direct responses of a test population that consists of 24.57% of the decided population who were excluded in the network training set. For the undecided population (22.67% of December respondents; 23.67% of March respondents), the network predicted a final response distribution that is consistent with the approval/disapproval ratio of the decided population. Copyright © 2002 John Wiley & Sons, Ltd.     

新型固体酸SO_4~(2-)MoO_3-TiO_2催化合成苹果酯

自制了一种新固体酸催化剂SO2 -4MoO3 -TiO2 ,FT -IR谱图表明 ,催化剂表面具有强酸中心 ,该催化剂对苹果酯合成的活性高 ,并得到该反应的优化条件如下 :乙酰乙酸乙酯 0 .3mol,乙二醇 0 .6mol,环己烷 30ml,催化剂 3g ,反应温度 110℃ ,反应时间 1.5h ,在此条件下 ,苹果酯产率达 90 % ,且催化剂易回收 ,具有较好的重复使用性能     

基于代理的校园网计费管理系统

根据目前Cernet校园网典型结构,设计了一种适应性广、通用性强的校园网计费管理系统,探讨了使用代理服务器进行计费的主要功能和工作流程.     

UPS网络控制和电压波形显示的研究

对目前在UPS方面研究的焦点问题作了阐述 ,并重点介绍了UPS网络控制系统的实现方法、系统功能和技术特点     

基于特征造型的注塑件CAD/CAE研究

以某电器零件的特征造型与注塑分析模拟为例，介绍了Pro/Engineer的特点以及在注塑件产品开发中的应用。     

THE TRANSFER BEHAVIOUR OF SOME CATIONS AT WATER／NITROBENZENE INTERFACE BY SEMIDIFFERENTIAL CYCLIC VOLTAMMETRY

The transfer of Sr~(2+) and Ba~(2+) ion, facilitated by 18-Crown-6 present in the aqueous phase, and of succinylcholine ion at w/nb interface were investigated by semi-differential cyclic voltammetry. A good polarographic curve of succinylcholine ion dissolved in water was obtained in the system of 0.01 mol/l LiCl (w)——0.01 mol/l TBATPB (nb). The peak current is directly proportional to the concentration of SC~(2+) ion. It can be used for the determination of SC and the detection limit is 1.05×10~(-5) mol/l.The apparent D~w and D~(nb) have been estimated. The transfer of Sr~(2+) and of Ba~(2+) at the interface are facilitated by 18-Crown-6 present in the aqueous phase and the peak current is directly proportional to the concentration of 18-Crown-6 in water. This method can be used for the determination of the complexing agent and for the stability constant of the complex formed in the aqueous phase.All the experimental results are in keeping with the theoretical.     

新型锆质不定形耐火材料的研制

以废旧电熔锆刚玉为主要原料,采用合理的粒度级配,应用复合结合剂和外加剂以凝聚结合的方式研制成功具有高荷重软化温度、高强度、低气孔率、低烧结线变化的新型锆质不定形耐火材料。图4,表4,参3。     

基于C/S与B/S相结合的教学管理系统的规划

针对当前高等教育体制改革学校办学规模不断扩大,存在多校区的办学模式,原来基于C/S或B/S单一模式结构的教学管理系统存在诸多弊端,对目前高校教学管理的实际需要和特点进行了分析,比较了两种模式的优缺点,提出了一种基于C/s和B/S结合的结构模式的教学管理系统,给出了基于该模式下教学管理系统的功能模块、实现方法、系统的软硬件支撑条件.