APT结晶母液处理新工艺

根据钨钼化合物性质的差异 ,运用分子设计的理论和方法 ,研究出一种用选择性沉淀法从APT结晶母液中除去钼及砷、锑、锡等杂质 ,并从除钼后的溶液中进一步回收WO3和NH4Cl的新工艺 .回收的WO3以APT形态产出 ,其质量达GB1 0 1 1 6— 88中APT— 0级要求 ,回收率达 90 %～ 95 % ;回收的NH4Cl质量完全符合配制解吸液的要求 ,其实收率达 6 0 %以上 .和工业上处理APT结晶母液的现行工艺相比 ,该工艺能带来明显的经济效益     

稀土元素-铬-钼体系的组成分析

本文详细研究了稀土元素，钼、铬体系中各元素定量测定的诸方面条件，提出了一种简单易行，测量准确，于一般条件下即可操作的常量分析的新方法，对于稀土矿物的成分测定具有指导作用。     

苯基氮杂-15-冠-5-八钼多酸钠超分子配合物的结构与热分解

本文对新型超分子配合物[Na(N-Ph)15C5(Et2O)]2Na2Mo8O26拍进行了X-射线四园衍射测定,该晶体属单斜晶系，空间群为P2t／c．a=1．7803(4)，b=1．3674(3)，c=1．4610(3)，β=112.33(2)．V=3．290(1)nm^3．Mr=2021.3，Dc=2.14g／cm^3，μ=1.71mm-1，F(000)=2079.63，R=0．0256和Rw=0．0295．并联系差热-热重分析和^1HNMR实验，讨论了配合物的热分解过程。     

镍钼硒化物的制备和超级电容性能研究——科研成果转化课程思政的挖掘与实施

采用乙酸镍和钼酸铵为镍源和钼源制备镍钼硒化物NiMoSe_x作为电极材料.六方MoSe₂的晶体结构与硒化镍具有相同的空间群，晶体结构非常匹配，可以形成独特异质界面的复合材料.实验数据表明镍钼硒化物具有较稳定的电化学性能.在较高的扫速下镍钼硒化物仍能保持较高的比容量且随着扫速的增大其比容量下降趋势较缓，展现了镍钼硒化物具有良好的倍率性能.本实验通过联系生活中息息相关的电子产品引导学生了解其中电池配件的储能原理和改进的方法，将笔者的科研成果镍钼硒化物的制备和超级电容性能研究转化为专业关联度高、专业教育与思政教育通向进行的创新创业实验课程.在实践过程中基于立德树人，能力导向的指导思想，注重培养学生的创新意识、科学精神、工程素养等思政目标.这一探索过程对于解决地方院校目前理工科实验课程中课程思政过于生硬、课程思政资源单一、教学方法单一等问题具有重大的借鉴意义.     

糠酸正丁酯香料催化合成的新方法

以糠酸和正丁醇为原料,改性钼镍粉作催化剂取代以往常用的硫酸作催化剂,合成糠酸正丁酯香料.实验结果是:在优化条件下,合成的糠酸正丁酯产率达到85.9%,比其他合成的糠酸正丁酯产率提高了十几个百分点.结论为改性钼镍粉作催化剂催化合成糠酸酯类香料,催化剂原料广且价廉,制作催化剂方便,制备好的催化剂能反复使用,催化活性高,不腐蚀设备,不污染环境,工艺简单,酯化产率高,在工业上制取糠酸酯类有推广和应用价值.     

Mo-30Cu合金室温变形组织

对Mo-30Cu合金室温拉伸性能进行了研究,并对其断口进行观察分析.通过对Mo-30Cu合金冷轧实验,研究了不同变形量下组织的变化规律.结果表明:Mo-30Cu合金的断裂以Cu相的韧性断裂为主,并伴随着Mo/Cu界面的分离和Mo晶粒的解理断裂.Mo/Cu界面的分离和Mo晶粒的解理断裂是Mo-30Cu合金室温轧制过程中产生裂纹的主要原因.     

Ore-forming event and geodynamic setting of molybdenum deposit at Wenquan in Gansu Province, Western Qinling

The Wenquan molybdenum deposit is associated with a Triassic granite in this area. The Wenquan granite is enriched in LILE and LREE, poor in HFSE, and has significantly higher contents of alkali （K2O＋Na2O） and Sr, Ba than those of the island arc volcanic rocks. These geochemical characteristics are similar to post-collisional granites in high K calc-alkaline series. Studies of major elements, trace elements, REEs and chronology of the Wenquan pluton show that, in the geodynamic transition stage of continent-continent convergence to extension, the partial melting of the enriched lithospheric mantle generated the basaltic magma and triggered the partial melting of the thickened lower crust which produceded the acidic magma, and the Wenquan pluton was formed by mixing of the two magmas. Molybdenite Re-Os isotopic dating gave Os model ages of 212.7±2.6 Ma to 215.1±2.6 Ma with a weighted mean of 214.1±1.1 Ma, and an Re-Os isochron age of 214.4±7.1 Ma. These ages are close to K-Ar ages （223 to 226 Ma） and a SHRIMP zircon U-Pb age （223±7 Ma） for the Wenquan granite within the error range, but relatively younger. This implies that the Mo mineralization occurred in a late stage of the magmatic intrusion, and the metallogenesis took place in the transition stage from syn-collision to post-collision in the tectonic setting of the Qinling Orogenic Belt （QOB） after continental collision between the North China Block （NCB） and the South China Block （SCB）. This process is also corresponding to the geological events of metamorphism and deformation in South Qinling, closure of the Mian-Lue oceanic basin, and exhumation of the Dabie-Sulu ultrahigh-pressure metamorphic rocks. The large-scale continent-continent collision between NCB and SCB in the middle Triassic triggered significant crustal thickening and exhumation of subducted slab. In the late Triassic, the tectonic setting was transformed to the transition stage from collision to extension. Materials from the asthenospheric mantle would ascend into the root of the lower crust, which could induce partial melting of the lower crust and generate Mo-enriched granitic magma. The ore-forming elements enriched in the fluid derived from the condensation and fraction of the magma resulted in the Mo mineralization. The Mo deposits in the QOB are mainly formed in two episodes, namely 220± Ma and 140± Ma. The two episodes of metallogenesis were developed in the tectonic transition settings from compression to extension, but they were in the different stages of the tectonic evolution. The occurrence of the Wenquan Mo-bearing pluton indicates that the Triassic tectonic-magmatic belt of Western Qinling is another favorable region for Mo mineralization in the QOB. Therefore, it is significant to pay more attention to evaluation of the ore-forming potentiality in the Triassic granites in Western Qinling.     

广西全州越城岭花岗岩体东部钨、锡、钼矿产找矿勘查预测探讨

广西全州越城岭花岗岩体东部地区成矿条件好,钨锡（钼）矿化普遍、矿化点密集分布,迄今除个别矿点工作程度相对较高,达到详查外,大部分矿点皆只限于地表矿点勘查或普查,至今只有一个仅具有地方工业价值的小型矿床,其余皆为矿（4C）点。此次的钨锡（钼）成因类型可分高-中温热液型、矽卡岩型二类,越城岭花岗岩体西侧还有含锡矿、绿柱石及铌钽的伟晶岩型。可初步预测预测该区钨〉10万吨．锡〉5万吨,铅锌〉10万吨。     

镀锌钢上钼酸盐/硅烷复合膜的组成与耐蚀性

分别采用一步法和两步法在热镀锌钢板表面获得钼酸盐/硅烷复合膜,通过X射线光电子能谱分析(XPS)、俄歇电子能谱剥层分析(AES)、盐雾腐蚀试验(NSS)及Tafel极化曲线等对两种复合膜的化学成分和耐蚀性能进行了研究,并将它们与单独的钼酸盐转化膜、硅烷膜进行对比.结果表明:一步法和两步法制备的复合膜具有相似的双层结构,内层以钼酸盐转化膜(含O、Mo、Zn、P)为主,外层以硅烷膜(含C、O、Si)为主,内外层之间及膜与锌基体之间的化学成分呈梯度变化;与单独的钼酸盐膜、硅烷膜相比,两种复合膜对腐蚀的阴极过程的抑制明显增强,自腐蚀电流减小至单层膜的1/5以下,耐蚀性显著提高;两步法制备的复合膜耐蚀性超过常规铬酸盐钝化膜,而一步法制备的复合膜的耐蚀性比由两步法制备的稍差,但仍接近常规铬酸盐钝化膜.     

白光LED用荧光粉Sr_(1-x)Eu_xMoO_4的溶胶-凝胶燃烧法制备及其热稳定性、光学性能

用溶胶-凝胶燃烧法成功制备了Sr1-xEuxMoOt红色荧光粉,mXRD、TEM、荧光磷光分光光度计对其物相、形貌以及发光性能进行表征和研究.结果表明:在395 nm和464 nm两主激发峰均可得到616 nm处红光发射峰,属于Eu3+典型的5Do→7F2的跃迁所致,由464 nm激发得到的发射峰为单峰,峰宽较窄且发射强度较强,粉体平均粒径约为200 nm,颗粒粒度分布均匀.