[Zn(PBIMH)2(H2O)]n的合成及晶体结构

水热条件下,合成了配位聚合物[Zn（L）2（H2O）]（nLH=2-吡啶-2-苯并咪唑）.X-射线单晶衍射分析结果表明：配合物属单斜晶系,P2（1）/c空间群,晶胞参数分别为：a=12.5657（2）,b=12.9258（2）,c=13.2403（3）A°,β=102.738（1）A°.锌离子与两个LH的4个氮原子,1个端基水配位形成变形的四角锥,（I）通过O---H---N氢键形成一维超分子结构.     

三丁基锡对水生生物毒理学影响的研究进展

综述了三丁基锡(TBT)对水生生物的毒理学效应,认为主要表现在干扰海产腹足类的内分泌而诱导性畸变现象的产生,抑制微藻的光合作用和呼吸作用,破坏水生动物超氧化物歧化酶、酸性磷酸酶、碱性磷酸酶等蛋白质的活性,对软体动物的DNA造成不同程度的损伤.同时,探讨了TBT的降解、伤害作用机制及研究前景等.     

Biomineralization of phototrophic microbes in silica-enriched hot springs in South China

Microbial mats in two hot springs in South China were sampled for the research of mineralization of microbes and its mechanism by the methods of geology and modern biology. The results show that hot spring microbes have the key capability for enrichment of Si, Al, Fe, Ca and other elements, and the microbes are also crucial for the formation of SiO2, CaCO3, clay and so on. The extracellular polymeric substances (EPS) play important roles in the process of mineralization of hot spring microbes, which mainly takes place in the layer of EPS outside cell wall or sheath of cyanobacteria. The sheath outside cell wall, which keeps the normal metabolism of cyanobacteria during the process of mineralization on its surface, is also considerable for the biomineralization of cyanobacteria. According to structure and mineralization characteristics of two microbial mats, the process of mineralization can be divided into three stages, namely, early surface mineralization, middle degradation mineralization, and late des- quamation of mineral. The above conclusions are significant for comprehension of the process of mineralization, the process of deposition and the preservation of microfossil in modern and ancient extreme environments.     

When and how did plate tectonics begin？ Theoretical and empirical considerations

Plate tectonics is the horizontal motion of Earth’s thermal boundary layer (lithosphere) over the convecting mantle (asthenosphere) and is mostly driven by lithosphere sinking in subduction zones. Plate tectonics is an outstanding example of a self organizing, far from equilibrium complex system (SOFFECS), driven by the negative buoyancy of the thermal boundary layer and controlled by dissipation in the bending lithosphere and viscous mantle. Plate tectonics is an unusual way for a silicate planet to lose heat, as it exists on only one of the large five silicate bodies in the inner solar system. It is not known when this mode of tectonic activity and heat loss began on Earth. All silicate planets probably experienced a short-lived magma ocean stage. After this solidified, stagnant lid behavior is the common mode of planetary heat loss, with interior heat being lost by delamination and “hot spot” volcanism and shallow intrusions. Decompression melting in the hotter early Earth generated a different lithosphere than today, with thicker oceanic crust and thinner mantle lithosphere; such lithosphere would take much longer than at present to become negatively buoyant, suggesting that plate tectonics on the early Earth occurred sporadically if at all. Plate tectonics became sustainable (the modern style) when Earth cooled sufficiently that decompression melting beneath spreading ridges made thin oceanic crust, allowing oceanic lithosphere to become negatively buoyant after a few tens of millions of years. Ultimately the question of when plate tectonics began must be answered by informa- tion retrieved from the geologic record. Criteria for the operation of plate tectonics includes ophiolites, blueschist and ultra-high pressure metamorphic belts, eclogites, passive margins, transform faults, paleomagnetic demonstration of different motions of different cratons, and the presence of diagnostic geochemical and isotopic indicators in igneous rocks. This record must be interpreted individually; I interpret the record to indicate a progression of tectonic styles from active Archean tectonics and magmatism to something similar to plate tectonics at ~1.9 Ga to sustained, modern style plate tectonics with deep subduction——and powerful slab pull——beginning in Neoproterozoic time.     

Clay minerals in surface sediments of the Pearl River drainage basin and their contribution to the South China Sea

Clay minerals have played a significant role in the study of the East Asian monsoon evolution in the South China Sea by being able to track oceanic current variations and to reveal contemporaneous paleoclimaUc changes prevailing in continental source areas. As one of the most important rivers inputting terrigenous matters to the northern South China Sea, the Pearl River was not previously paid attention to from the viewpoint of clay mineralogy. This paper presents a detailed study on clay minerals in surface sediments collected from the Pearl River drainage basin （including all three main channels, various branches, and the Lingdingyang in the estuary） by using the X-ray diffraction （XRD） method. The results indicate that the clay mineral assemblage consists dominantly of kaolinite （35%-65%）, lesser abundance of chlorite （20%-35%） and illite （12%-42%）, and very scare smectite occurrences （generally 〈5%）. Their respective distribution does not present any obvious difference throughout the Pearl River drainage basin. However, downstream the Pearl River to the northern South China Sea, the clay mineral assemblage varies significantly： kaolinite decreases gradually, smecUte and illite increase gradually. Additionally, illite chemistry index steps down and illite crystallinity steps up. These variations indicate the contribution of major kaolinite, lesser illite and chlorite, and very scarce smecUte to the northern South China Sea from the Pearl River drainage basin. The maximum contribution of clay minerals from the Pearl River is 72% to the northern margin and only 15% to the northern slope of the South China Sea. In both glacials and interglacials, kaolinite indicates that the ability of mechanical erosion occurred in the Pearl River drainage basin.     

环境温度作用下隧道结构变形分析

为了探讨隧道结构的变形缝合理设置问题,对某隧道的钢筋混凝土超长结构进行了使用阶段环境温度影响下结构变形现场量测,应用一维非稳态热传导理论和温度应力理论对环境温度影响下隧道结构的温度和变形进行计算.计算表明,对于超长混凝土隧道结构,使用期内环境温度的变化对于结构的温度变形影响不能忽视,变形缝的设置需要考虑永久变形缝的容许变形和混凝土施工时间的影响.     

和谐社会建设与图书馆作用发挥探讨

构建社会主义和谐社会,是以胡锦涛为总书记的党中央作出的重大战略举措,也是无数共产党人为之上下求索的根本目标。作为高校图书馆及图书馆人面对这庄严而紧迫的神圣任务,应以邓小平理论和“三个代表”重要思想为指导,全面贯彻落实科学发展观,充分发挥图书馆在社会主义精神文明和政治文明重要窗口的作用,现代信息搜集和传递集散地的功能,为社会开展咨询活动的有利环节和满足人民群众日益提高的文化需求服务部门的职责,尽心尽力为建设和谐社会作贡献。     

酚与4,4′-联吡啶π-π叠加作用的核磁氢谱研究

通过核磁氢谱法研究酚类化合物与4,4′-联吡啶季铵盐π-π叠加作用,研究了吡啶环上α-H,β-H及氧乙基上的α′-H,β′-H的化学位移值及其改变的情况.结果表明,β-萘酚、α-萘酚、对苯二酚、间苯二酚及苯酚使上述氢的化学位移降低,其化学位移降低次序为:β萘酚>α-萘酚>对苯二酚、间苯二酚>苯酚.而8-羟基喹啉和间硝基苯酚导致上述氢的化学位移稍升高.     

谈幼儿歌舞对幼儿身心发展的作用

文中通过歌舞对幼儿生理、语言、个性、智力等方面的影响,说明幼儿歌舞对幼儿身心发展起着很大的促进作用。     

钢框架节点局部断裂冲击作用实验研究

对钢框架节点在强烈地震或极端荷载情况下因突然断裂引起的冲击作用进行了研究．讨论了断裂冲击值与断裂位置内力释放值的对应关系，通过单质点模型分析了冲击反应的量值范围，考察了冲击反应峰值与冲击作用时间和断裂发生后体系自振周期之比的关系．设计并实施了钢材单轴断裂和模型框架节点断裂两种实验，验证了采用具有高频采样能力的测试设备准确测取断裂过程中结构反应的可行性，揭示了节点瞬间断裂仍然包含渐进性和局部性两项特点．对节点瞬间断裂引起的冲击反应进行了初步的数值评估．