Synthesis and crystal structure of tetranuclear zinc benzoate

A tetranuclear zinc benzoate Zr4O(C6H5CO2)6 was synthesized and characterized by X-ray single crystal determination. It crystallizes in cubic, space group Ia-3d. Its crystal cell is very large, α=4.10063(18)nm, V=68.953(5)nm^3 and Z=48. The structure is composed of discrete Zr4O(C6H5CO2)6 molecules. In each molecule, four zinc atoms are held together by a central oxygen atom, which results in the formation of a regular tetrahedron. All benzoate ligands coordinate to zinc atoms in a bidentate bridging mode. Each zinc atom is in a slightly distorted tetrahedral geometry, coordinated by three benzoate oxygen atoms and the central oxygen atom. The intermolecular interactions result in the formation of a three-dimensional supramolecular framework, with non-intersecting parallel channels.     

多义词company的理解与应用

一词多义是各种语言中的普遍现象。选择正确的词典义,使之顺应特定的语境义至关重要。本文旨在通过“company”一词浅议这一现象。     

Pneumatic active suspension system for a one-wheel car model using fuzzy reasoning and a disturbance observer

This paper presents the construction of a pneumatic active suspension system for a one-wheel car model using fuzzy reasoning and a disturbance observer. The one-wheel car model can be approximately described as a nonlinear two degrees of freedom system subject to excitation from a road profile. The active control is composed of fuzzy and disturbance controls, and functions by actuating a pneumatic actuator. A phase lead-lag compensator is inserted to counter the performance degradation due to the delay of the pneumatic actuator. The experimental result indicates that the proposed active suspension improves much the vibration suppression of the car model.     

试论"一国两制"与祖国统一

“一国两制”构想是马列主义普遍原理和中国实际相结合的产物。它从实践中来,又到实践中去。当前,国内外形势发生了很大变化。按照“一国两制”构想来解决台湾问题,虽然面临着一些现实困难,但也初步具备了国际国内条件。我们应该坚定祖国和平统一的信心和决心,推进祖国统一大业早日完成。     

HIV-1gp120V3区的结构特征及其生物学功能

研究表明HIV-1包膜蛋白gp120上的V3环在病毒结合到靶细胞的过程中起着重要的作用.这个区域中的几个氨基酸残基与gp120同辅受体的结合相关联.在HIV-1感染过程的早期,V3环在患者体内诱导针对HIV病毒的抗体应答,并被确定为主要中和决定簇.一些针对V3环的抗体具有广泛的中和活性.但是,V3环是HIV包膜蛋白的一个高变区,发生着广泛的变异.综述了V3环的结构特征和变异以及生物学功能,并对V3环的免疫反应进行了探讨.     

"一面两孔"夹具定位实验的开发

介绍了"一面两孔"夹具定位实验开发的目的和意义,给出了实验的原理、方法、装置构成以及改进方向.     

Involvement of nitric oxide in the signal transduction of salicylic acid regulating stomatal movement

The effects and the relationship between sali-cylic acid(SA)and nitric oxide(NO) on Vicia faba L.stomatal movement were studied.The results here showed that exogenous SA and NO induced stomatal closure,100μmol/L SA induced a rapid and striking NO increase in the cytosol of guard cells.This phenomenon was largely prevented by 2000μmol/L 2-phenyl-4,4,5,5-tetramethylimidazoline-l-oxyl-3-oxide(PTIO),a specific NO scavenger,and 25μmol/L N^G-nitro-L-Arg-methyl eater (L-NAME),an inhibitor of NO synthase(NOS) in mammalian cells that also inhibits plant NOS.In addition,SA-induced stomatal closure was largely prevented by PTIO and L-NAME.These results provide evidence that guard cells generate NO in response to SA via NOS-like activity,and that such NO production is required for full stomatal closure in response to SA.H-(1,2,4)-oxadiazole-[4,3-α]quinoxalin-l-one(ODQ),an inhibitor of guanylate cyclase,and nicotinamide,an antagonist of cADPR production,inhibited the effects of SA-and NO-induced stomatal closure.It suggests that both cGMP and cADPR might mediate the signal transduction of SA and NO-induced stomatal closure.     

Thermodynamic characterization of two novel spin-crossover complexes

Spin-crossover complexes are of great interest to the scientists because of their potential application in molecular-based electronic devices. Some octahedral metal compounds with 3dn (4 ≤ n ≤ 7) configuration can induce a spin state conversion through a fine tuning condition (temperature, pressure, light irradiation, etc.). If the conversion occurs reversibly with a hystersis loop and color change, it will make the system possessing memory effect. The memory effect can be magnified and the …     

嫦娥一号的奔月日记

北京时间2007年10月24日18时05分，长征三号甲火箭托举着我国第一颗月球探测卫星——嫦娥一号在西昌卫星发射中心，从三号甲塔架点火发射。11月5日上午11时，嫦娥一号顺利被月球“捕获”成为一颗绕月卫星。在经过三次近月制动后，嫦娥一号进入开展科学探测的工程轨道，随后将进行为期一年的对越科学探测。这是探月三部曲的第一步，也是中国空间探测历史上的新的里程碑。本文介绍了嫦娥一号从发射到2007年11月26日的每一次重要事件。     

球形闪电的形成及运行机理初探

指出了闪电时形成的离子管形层流,其间歇流动产生涡环,提出了由若干导电离子流形成的涡环组合,它们间的相互作用构成稳定的球形闪电,该假设能解释球形闪电的形成、构造及其长寿命等基本性质.