New structure model of oxygen-evolving center and mechanism for oxygen evolution in photosynthesis

So far, many important questions and problems concerning the structure and mechanism of photosynthetic oxygen evolution are still unsolved. On the basis of recent achievements in this field, a new structure model is proposed whereby two H2O molecules bind asymmetrically to two manganese ions (Mn1Ⅱ and Mn4Ⅲ) at the open end of "C" shaped cluster and keep rather large distance. Two histidine residues coordinate to the other two manganese ions in higher oxidation state (Mn2Ⅳ and Mn3Ⅳ ) through their nitrogen atoms of the imidazole. Cl bound as terminal ligand to Mn4Ⅲl is connected to Ca, and the latter is needed to maintain the special configuration of two Mn2O2 units by bridged-oxo and bridged-carboxylate ligands. The whole structure of oxygen evolution center is asymmetry. A new mechanism for oxygen evolution invokes predictions of asymmetric oxidation of two H2O molecules, dynamic structural changes of oxygen e-volving center and indirect proton transport, etc. Only in S2 state, could Mn1Ⅳ = O. intermediate with high oxidation potential be formed. The S2→S3 process occurs with significant structural changes, as well as intramolecular and intermolecular hydrogen transfer. The S3 state corresponds to intermediate of Mn1Ⅳ-O… H… O-Mn4Ⅳ . During S3→ [S4] →S0, the O-O bond is formed only in S4 state. The change of nucleophilic interaction between Cl and manganese ions different oxidation states has consequence for the significant structural changes in H2O oxidation process.     

刚体平衡问题再研究

以刚体的平衡方程为理论依据推断出刚体在各种运动状态下能否处于平衡状态，并导出处于平衡状态所满足的运动学条件；同时对刚体在平面力系作用下平衡条件的等价条件作了证明。     

试谈以学生为中心的化学教学设计

对以学生为中心的化学教学设计的内涵和特征作了初步的探讨，并分析盐类水解的化学程序启发教学设计，是如何充分体现了以学生为中心。     

A Shortest Path Problem

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基于绿色设计准则的塑料门窗铣削机设计

介绍了绿色设计在技术先进性,环境、材料和结构等方面的准则,并运用于塑窗锯铣加工中心的铣削机设计中,表明绿色设计可从技术上保证安全,可靠,经济地实现产品的各项功能和性能,同时只有在设计阶段将产品的“绿色度”作为设计目标,才能取得理想的设计结果。     

服装流行的内核、边际与市场预测

分析服装流行的各种理论,提出服装流行的“内核”与“边际”概念,以此出发寻找服装设计和市场应用的有效工具,以期为服装生产实践和经营行为提供参考依据。     

基于卫星云图的无眼台风中心定位算法

基于数学形态学理论,采用球形结构元素设计了一种滚球滤波器,以去除红外卫星云图的噪声。采用多值自适应分割算法,生成自适应的分割模板,分割出主体台风云系。通过分析不同类型无眼台风云系的眼区特点,提出了具有自适应特性的无眼台风云系中心自动定位算法。通过红外通道和水汽通道的多谱图像融合,校验无眼台风中心的定位。实验结果表明,这种方法可以初步解决大部分无眼台风的中心定位。     

Assignment of Soret MLCT band of reduced form of copper binuclear cluster in cytochrome c oxidase film

Low concentration of dithionite results in the reduction of Cu-Cn binuclear and heine a active sites of the cytochrome c oxidase thin solid film immersed in the acidic phosphate buffer, but Fe-Cu binuclear center keeps in the oxidation state. It manifests as a negative peak at 426 nm and a positive one at -408 nln in the difference spectra induced by dithionite. The former implies decrease of the oxidized form of heme a center, that is, Fea^3 →Fea^2 . And the latter results from the contribution of metal-ligand charge transfer (MLCT) transition in the reduced binuclear Cu-Cu cluster, rather than from that of heine a center. This stronger Soret MLCT band must be helpful to overcoming the difficulty in distinguishing the weaker copper sign from the stronger one of iron when studying copper-iron protein.     

基于高分辨雷达的运动目标参数估计方法研究

根据运动目标的频域回波的特点，深入研究了一种具有多项式相位结构的运动目标回波仿真模型，并提出了基于该模型的多特征参数提取方法。该方法基于匹配傅立叶变换理论，依据频域雷达目标回波特征构造匹配函数，对目标回波数据进行匹配傅立叶变换，变换结果的主瓣坐标反映了目标散射点的距离及速度信息。大量的仿真实验结果证明，该方法十分有利于进行运动目标的特征提取。根据对仿真结果的分析，进一步给出了改进算法，使得在较低信噪比情况下也能够有效的检测出目标上的散射点的距离与速度参数。     

一种改进的单纯形算法

针对无约束函数最优化问题,提出了一种能有效加快收敛速度的改进单纯形算法。在N-M单纯形算法的基础上,利用目标函数值的信息对反射中心重新定位,使反射方向更靠近目标函数最优值的方向,提高了搜索效率。函数寻优的对比测试结果表明,改进算法明显提高了单纯形算法的收敛速度和寻优质量。