Analysis of Pyrolysates for Phenol Formaldehyde Resin by Py-GC/MS

Pyrolysis of phenol formaldehyde resin has been investigated by Pyrolysis Gas Chromatography-Mass Spectroscopy at the different temperatures from 500℃ to 750℃. Its composition of pyrclysates has been analyzed. Several compounds, especially benzene, toluene, p-xylene could only be formed above 500-550℃. Howerver, peak intensities for some pbend derivatives were decreased at the higher temperature. During pyrolysis, for thermo-setting phenol formaldehyde resins, polymeric chain scissions take place as a successive removal of the monomer units from the polymeric chain. The chain scissions are followed by secondary reactions, which leads to a variety of compounds. Addition reactions can also take place among the double-bond compounds during pyrolysis.     

纳米CaCO3/丙烯酸树脂浆液的流变性

制备了纳米CaCO3/丙烯酸树脂浆液,当浆液(48 gZ-26、50g纳米CaCO3和83.3 g二甲苯)中分散剂添加量为3 g时,Casson屈服应力τc值最小,浆液的稳定性最好,与工艺条件优化时所得到的一致.纳米CaCO3/丙烯酸树脂浆液的流变性研究表明:该体系的流动特性符合Casson模型,其屈服应力τC较小,稳定性较好;浆液的黏度随剪切速率增加而显著下降,具有明显的剪切稀化特性,且随着纳米CaCO3含量增加,其剪切稀化趋势增强;在所考察的低剪切速率范围内,纳米CaCO3浆液具有明显的触变性,且纳米CaCO3含量越大触变性越大.图10,表7,参8.     

建筑业企业诚信经营的博弈研究

在研究建筑交易市场的重复博弈特征的基础上,建立了建筑交易市场的收益矩阵,对均衡结果进行分析论证,并指出影响均衡结果的主要因素,最后得出建筑业企业诚信经营的必要性。     

对抗体系的一种建模方法研究

首先,通过实例阐明了信息交互在效能涌现中所起的重要作用;其此,提出了“基于信息关联网的体系建模方法”,为研究信息交互过程中对抗体系的效能涌现机理提供了方法论意义上的支持;最后,基于上述体系建模方法,给出了一个具体的建模实例。     

我国排球后备人才的培养与市场管理交流体制

分析了社会转型期我国排球后备人才的培养以及市场交流管理体制，认为我国排球后备人才培养体制由单一、封闭模式向多元、开放模式发展，建立多渠道、多形式的多元培养体制是大势所趋；传统的排球后备人才管理体制存在各种弊端，建立切实可行的排球后备人才流动市场体制，实现人才的最佳化流动，最大限度地合理使用排球后备人才，是提高后备人才使用率和成材率的关键。     

我国城市贫困的权利理论探微

运用印度经济学家阿玛蒂亚·森的权利理论,分析了中国城市贫困群体的权利现状。除以生产为基础的权利无从谈起外,以贸易为基础的权利、自己劳动的权利、继承与转移的权利都在不同程度上恶化,这是城市贫困群体出现和扩大的根本原因。从权利理论的视角反贫困,政府的工作重点应当是采取多种手段和措施改善除以贸易为基础的权利以外的三种权利。     

Hydrogenation of Polymer

1 Introduction Hydrogenated polymer resins arei mprovedsolubility with other polymer ,transparency andstability,usinghot melt adhesive ,insulation oil ,optical materials .The hydrogenationis different to monomer because of shapeobstacle ,spread of molecular ,solid or high viscosity at roomtemperature .And separation of catalyst is not soeasy after the reaction.DCPDresinis hydrogenated with Ni-Kieselgur in cyclohexane .     

中性磷萃淋树脂吸附铼的性能和机理研究ⅢCL－P＿（350）－KReO＿4－HNO＿3体系

本文报道四甲基膦酸二甲庚酸萃淋树脂（ＣＬ－Ｐ＿（３５０）从硝酸溶液中吸附鳞的性能和机理研究。实验结果表明，吸附平衡服从Ｌａｎｇｍｕｉｒ经验等温式。测得吸附物分子中Ｐ（３５０）与Ｒｅ（Ⅶ）的摩尔比为２：１。Ｒｅ（Ⅶ）是以形式被树脂吸附，其吸附机理属于综合反应：并测定了吸附过程的热力学函数。     

The performance of non‐linear exchange rate models: a forecasting comparison

In recent years there has been a considerable development in modelling non‐linearities and asymmetries in economic and financial variables. The aim of the current paper is to compare the forecasting performance of different models for the returns of three of the most traded exchange rates in terms of the US dollar, namely the French franc (FF/$), the German mark (DM/$) and the Japanese yen (Y/$). The relative performance of non‐linear models of the SETAR, STAR and GARCH types is contrasted with their linear counterparts. The results show that if attention is restricted to mean square forecast errors, the performance of the models, when distinguishable, tends to favour the linear models. The forecast performance of the models is evaluated also conditional on the regime at the forecast origin and on density forecasts. This analysis produces more evidence of forecasting gains from non‐linear models. Copyright © 2002 John Wiley & Sons, Ltd.     

氨基膦酸羧酸螯合树脂的合成及其对痕量镧系稀土富集分离性能的研究

简要叙述了氨基膦酸羧酸树脂的合成路线 ,用 ICP- AES对其富集分离痕量镧系稀土元素进行了研究 ,讨论了吸附酸度、洗脱、吸附流速以及共存离子干扰等的影响 ,并进行了实际样品的分析 ,获得了满意的结果 .