转型期乡土法律文化对乡镇煤矿安全法制影响力研究

当前,乡镇煤矿事故频繁发生,成为煤矿安全监察的"老大难".由于乡镇煤矿地理位置上位于乡村、小镇一带,矿工大多来自本地农民工.因此,解构转型期乡土法律文化,从另一视角研究乡镇煤矿安全法制,对我国乡镇煤矿立法不无裨益.转型期村民法律心理、法律意识有其特殊性,当前关于乡镇煤矿的法律制度不完备,乡村维权机构与设施不合理,针对以...     

亚磷酸异构化的量子化学研究

用从头计算方法研究了亚磷酸的异构化，优化了过渡态的几何构型，计算了反应的活化能及热效应，并对反应过程中各原子间电子的迁移进行了分析，从理论上预测了反应的机理．     

二溴卡宾与对-甲基苯乙酮环加成反应机理的量子化学研究

用ＡＭ１方法优化了二溴卡宾与对－甲基苯乙酮环加成反应的反应物、过渡太、中间体和产物的构型，找到了反应的过渡态，从理论上论证了二溴卡宾与对－甲基苯乙酮加成反应的机理，得出了该反应为强放热反应，第二步反应为反应控制步骤的结论。     

Advanced materials for aqueous supercapacitors in the asymmetric design

Supercapacitors have been recognized as one of the promising energy storage devices in the future energy technology. In this perspective, rapid progress is made in the development of fundamental and applied aspects of supercapacitors. Various techniques have been developed specifically to estimate the specific capacitance. Numerous efforts have been made in the literature to increase the specific capacitance of electrode materials. Recently, researchers pay more attention on designing supercapacitors of asymmetric type with extending cell voltage and dissimilar materials with complementary working potentials. Researchers try to increase the specific energy of asymmetric supercapacitors (ASCs). Conversely, it is still a challenge to find a suitable operation conditions for ASCs in various designs, especially for the one with battery type electrode. In this review, we describe our recent research works and other reports on the preparation of various nanostructured electrode materials and the performances of both symmetric and asymmetric supercapacitors. Finally, we demonstrate effects of charge balance on the capacitive performances of ASCs which consist of one electrode material of the battery type and one capacitive material. We also demonstrate how to evaluate the charge capacities of both positive and negative electrode materials for this ASC application.     

基于移民-疾病-死亡过程模型预测患者人数的研究

本文将移民过程引入疾病-死亡模型，并用新模型来预测住院患者人数。同时使用蒋庆琅的模型预测当转移强度为常量时住院患者人数。比较两个模型得出结论：在转移强度为常量的情况下，患者人数是稳定的。     

Ligand-metal interaction in transition-metal complexes with tripodal polyaza ligands

Five complexes ([Cu(tpc)]²⁺ 1, [Cu(tpa)]²⁺ 2, [Co(tpa)]²⁺ 3, [Fe(tpa)]²⁺ 4 and [Mn(tpa)]²⁺ 5) (tpc=N, N’, N"-tris[(2-pyridyl)methyl]-1,4,7-triaza-cyclononane(L1) and tpa=tris[2-((2-pyridyl) methyl-imino)ethyl]amine(l2)) were synthesized and characterized. The crystal structures of 1, 3 and 4 were determined by X-ray crystallography. Electrochemical investigations over two cupric complexes reveal that 2 has a less negative redox potential than that of 1. Electronic spectra of 2, 3, 4 and 5 show that the distinction in metal ion results in a shift of the ligand-based π*→π transition. Foundation item: Supported by the Natural Science Foundation of Hubei province Biography: Yin Ye-gao (1950-), male, Associate professor, researching for the the synthsis and properties of tripodal polydentate ligands.     

NBUC马氏过程的特征

讨论一类NBUC马氏过程的某些特征及其一个马氏过程X∈NBUC的等价性条件;给出由转移算子和位势算子所表示的相应等价性定理;并指出对NBUE类亦有相应的结果。     

视觉光化学过程中的构象电子跃迁

本文应用构象电子跃迁理论讨论了视觉光化学过程中的构象电子跃迁,证明了维生素A从All—Trans构象到11—cis构象的跃迁几率大于到9—cis构象的跃迁几率2.8倍,与实验及自然界前者优于后者较好地符合。     

CO和OH自由基反应机理的量子化学研究

用密度泛函理论(DFT)的B3LYP方法,在6-311 G(d,p)基组水平下研究了CO与OH自由基反应的微观机理.全参数优化了反应过程中各反应物、中间体、过渡态和产物的几何构型,振动分析结果证实了中间体和过渡态的真实性,IRC计算结果进一步证实了过渡态的真实性.在G3水平上计算了它们的能量,OH自由基与CO反应机理的研究结果显示:OH自由基与CO反应为双通道反应过程,分别为(1)CO OH→IM1→TS1→CO2 H;(2)CO OH→IM1→TS2→IM2→TS3→CO2 H.其中通道(2)的活化能较低,为主要反应通道.     

故障分量虚拟电压差夹角余弦母线保护方法

针对母线比率差动保护在区内故障有汲出电流情况下,由于元件灵敏度下降导致保护整组动作速度减慢或拒动问题,采用故障分量虚拟电压差夹角余弦的母线保护新方法。该方法通过平移故障分量电压信号的位置,计算平移得到的两个故障分量虚拟电压差的夹角余弦来判别区内和区外故障。在区内故障时,故障分量虚拟电压差方向相反,夹角余弦值为负值;在区外故障时,故障分量虚拟电压差方向相同,夹角余弦值为正值。最后通过理论分析和PSCAD(power systems computer aided design)搭建拉西瓦水电站模型验证了新方法在母线内部故障有汲出电流时,其动作裕度至少为比率差动保护的5.97倍;通过平行四边形定则分析并仿真验证了新方法不受母线区内故障高阻抗接地影响;且方法具有较强的抗电流互感器饱和能力。