氧化镍掺杂酚醛树脂热解炭的结构及抗氧化性研究

在酚醛树脂中直接掺杂三氧化镍粉末,研究氧化镍掺杂量、炭化温度对氧化镍改性树脂热解炭结构和氧化温度的影响。用X射线衍射、拉曼光谱、扫描电镜和综合热分析等手段对氧化镍改性树脂热解炭的石墨化度、显微结构及氧化温度进行表征。结果表明,埋炭条件下掺杂三氧化二镍,450～750℃温度下被逐级还原成一氧化镍和单质镍,其催化热解炭形成晶须、片状或块状结构;氧化镍改性树脂热解炭石墨化度随炭化温度升高和氧化镍掺杂量增加而增高,其氧化温度高于酚醛树脂氧化温度;氧化镍的最佳掺杂量为3%～5%。     

一种用51单片机仿真PLC控制的方法

随着计算机技术的成熟和发展,微机控制系统产生了PLC控制和单片机控制两大分支。PLC以其高可靠性,使用简便等优点,以高价格占据了工业微控市场;单片机又以其体积小,重量轻,价格便宜等优势广泛应用于家电产品。本文以项目引导,任务驱动为楔机,阐述了用单片机设计出模拟PLC控制的教学模块,如何应用单片机设计电路仿真PLC控制。     

Photocatalytic activity of TiO<Subscript>2</Subscript> sensitized by CdS quantum dots under visible-light irradiation

In this paper, CdS quantum dots sensitized TiO2 composite powders (QD-CdS/TiO2) were synthesized by impregnating TiO2 powder into CdS sol with different concentrations. X-ray diffraction pattern (XRD) shows the crystal structures of CdS and TiO2 are cubic phase and anatase phase separately in QD- CdS/TiO2 powder samples; the crystal size of CdS in QD- CdS/TiO2 is about 3-7 nm, while TiO2 crystal size is about 20 nm. With increasing CdS content in QD-CdS/TiO2 composite, the UV-Vis absorption spectrum shifted to the longer wavelength lines, exhibiting obvious quantum size effect. The fluorescence intensity of QD-CdS/TiO2 irradiated by blue light is weaker than that of pure CdS. When the molar ratio of CdS and TiO2 is about 1∶2, the QD-CdS/TiO2 powder has the best catalytic properties under visible-light irradiation, and the degradation rate of rhodamine B (RhB) is up to 92.2% within 60 min.     

Colpitts电路中的双涡卷混沌寄生振荡分析

通过在Colpitts振荡器中引入二次反馈项,观察到了新奇的双涡卷吸引子.这个具有反馈项的混沌系统具有3个平衡点,产生不同于Lorenz和Colpitts系统的复杂吸引子.对系统的一些基本特性,如平衡点、稳定性、Lyapunov指数谱、分岔图、相轨与庞加莱截面等进行了详细的分析.     

M2M大型装备远程监控

M2M产生于20世纪90年代中后期,以监控设备和资产为目标而产生.随着社会的不断发展和技术的不断进步,M2M不再是简单的数据在机器间的传输,更重要的是,它是机器与机器间智能化、交互式的通信.利用M2M网络实现大型装备的远程实时监控.对于企业和国家都越发重要.     

湖南省低碳经济发展相关因素探讨

地区的低碳经济发展建设是一项综合性的工程,与地区的人口、城市化、GDP总量、人均GDP等众多因素有着密切的内在联系.通过相关系数法定量地测定湖南省在低碳经济建设中的碳排放总量与其他影响因素之间的相关性,并利用修正了的I=PAT模型对其进行拟合分析,以判断在主要相关各因素变动下的碳排放变动趋势.     

一类二阶微分方程的无穷周期解

通过临界点理论和Z2不变群指标理论,证得I(x)有无穷多个临界点,再由变分原理可得方程(2)与方程(3)等价,在改变条件的情况下,得出了一在二阶泛函微分方程存在无穷多个周期解.     

Plasmonic biosensors and nanoprobes based on gold nanoshells

Gold nanoshells (GNSs), consisting of a dielectric core coated with gold, have gained extensive attention as they show readily tunable optical properties and good biocompatibility. As highly sensitive and label-free optical biosensors with wide applications, GNSs have been investigated in many fields including drug delivery, immunoassay, cancer treatment, biological sensing and imaging. Taking advantage of the adjustability of the local surface plasmon resonance (LSPR) and the sensitivity of the surfaceenhanced Raman scattering (SERS) signal of GNSs, we have developed diverse applications including plasmonic biosensors and nanoprobes based on GNSs. In this review we introduce plasmonic and electromagnetic properties and fabrication methods of GNSs. We describe research progress in recent years, and highlight several applications of GNSs developed by our group. Finally we provide a brief assessment of future development of GNSs as plasmonic materials that can be integrated with complementary analytical techniques.     

单-6-叠氮-β-环糊精与苯乙炔的点击化反应

利用CuI/NBS这种新型催化体系来促进单-6-叠氮-β-环糊精与苯乙炔之间的偶联反应,通过这个多组分反应可以高效地以炔和叠氮为原料一锅法制备5-碘代-1,4-取代-1,2,3-三氮唑类化合物.