Influence of thermal-decomposition temperatures on structures and properties of V2O5 as cathode materials for lithium ion battery

Submicron spherical V2O5 particles with a uniform size and a lower crystallinity were successfully synthesized by a chemical precipitationthermal decomposition technique using the commercial V2O5 powders as starting material. The crystal structure and grain morphology of samples were characterized by X-ray diffraction(XRD) and scanning electron microscopy(SEM), respectively. Electrochemical testing such as discharge–charge cycling(CD) and cyclic voltammetry(CV) were employed in evaluating their electrochemical properties as cathode materials for lithium ion battery. Results reveal that the crystallinity and crystalline size of V2O5 particles increased when the thermal-decomposition temperature increased from 400 ℃ to 500 ℃, and their adhesiveness was also synchronously increased. This indicate that the thermaldecomposition temperature palyed a significant influence on electrochemical properties of V2O5 cathodes. The V2O5 sample obtained at 400 ℃ delivered not only a high initial discharge capacity of 330 m A h g-1and also the good cycle stability during 50 cycles due to its higher values ofα in crystal structure and better dispersity in grain morphology.     

Comparative analysis by simulating and testing pole impact for hot stamping front crossbeam of automobile

Hot stamping 22MnB5 steel plate with ultra-high strength has been widely used for body structural members in consideration of automobile safety and lightweight.This paper presents a verification program of simulating and testing pole impact in order to verify if the front crossbeam reinforcement assembly can meet the design requirements,reduce the overall vehicle simulation and test cost and shorten the operation period.In the same condition,the simulation proved conforming to the design requirements;however,the bumper cracked at the impacting point in the course of pole impact test.The analysis of the crack by optical microscope,Vickers and scanning electron microscope indicates that mixture of ferrite,bainite and martensite was produced in the weld heat-affected zone of the 340/590DP tow hook holder and the 22MnB5 front crossbeam;therefore,their hardness and mechanical property were reduced obviously,so that they fractured when impacted.No welding process with continuous weld but spot welding or other bonding method may be employed for the reason that the capacity of the 22MnB5 steel plate in the weld heat-affected zone was reduced obviously.     

高效液相色谱法测定嘎日迪-5味丸中绿原酸的含量

目的：建立测定蒙药嘎日迪-5味丸中绿原酸含量的反相高效液相色谱法．方法：用ODS C18色谱柱,流动相为乙腈-水-冰醋酸（11．5：88．5：2）,检测波长318nm,流速为1ml／min．以外标法测定了嘎日迪-5味丸中绿原酸的含量．结果：绿原酸在4．5～22．5μg/ml浓度范围内呈良好的线性关系．平均回收率为98．1％,RSD=2．2％（n=5）．结论：本法简便,可靠,可作为蒙药嘎日迪-5味丸的含量测定方法．     

乌苏里蝮消化道5-羟色胺免疫活性细胞的分布与形态学观察

应用5—羟色胺特异性抗血清，对乌苏里蝮(Gloydius ussuriensis)消化道内分泌细胞进行了免疫组织化学定位。结果表明：5—羟色胺(5—HT)免疫活性细胞在乌苏里蝮消化道各段都有分布，其中幽门部5—HT免疫活性细胞分布密度为最高，食管部最低，同时对其分布型的原因、形态和功能相适应的特点进行了讨论。     

人纤溶酶原kringle5功能区基因在大肠杆菌中的表达

将人纤溶酶原kringle5功能区基因插入融合基因表达载体pET17bBamHⅠ位点,构建成重组质粒pETK23,转化大肠杆菌BL21(DE3),在IPTG诱导下,纤溶酶原kringle5功能区基因在重组转化菌株BL21(DE3,pETK23)中获得高效表达,表达产物以可溶性蛋白形式存在,表达量占菌体总蛋白的528%.     

长庆气田储层的高频层序地层学分析

鄂尔多斯盆地长庆气田的主力储层为下奥陶统上马家沟组的马五段,属蒸发边缘海相沉积,由鲕云岩、颗粒云岩、藻云岩、泥层岩、含膏云岩和膏云岩等组成,其中高泥质的泥云岩和云泥岩以至含云泥岩,代表了洪泛沉积,在区内分布广泛而稳定,是建立高频层序的标志层。为此,将自然伽玛测井曲线进行频谱工出其主频系列,经转换得到泥质含量的周期系列,从而得出马五１的高频沉积层序符合米兰科维奇周期的结邓储层马五１的高频沉积旋回是由     

绿豆下胚轴原生质体的培养

绿豆下胚轴原生质体的培养陈汝民，龙程，王小菁（华南师范大学生物学系广州５１０６３１）关键词绿豆下胚轴；原生质体；Ｂ５Ｐ１培养基；愈伤组织中图分类号Ｑ９４４．４６豆科植物在国民经济生活中占有重要位置，１９８０年高国输等人首先从豆科植物首清的叶片中分离和...     

Microstructure and optical properties of Ag5In5Te47Sb33 phase change thin films with high reflection in thermal annealing process

The microstructure and optical properties of Ag-5In-5Te 47Sb 33 phase change films with high reflection in the thermal annealing process were systematically reported. The as_deposited film is amorphous and its crystalline temperature is 160℃. The annealed films are crystalline. The crystalline phases are AgInTe-2, AgSbTe-2 and Sb when annealed at low temperature. When annealed at 220℃, the AgInTe-2 phase disappears and the amount of AgSbTe-2 is the largest. The research of electronic transmission microscopy shows that the morphology of AgSbTe 2 is sphere and that of Sb is bludgeon. The reflection of the annealed films is higher and reaches its peak value at 220℃.     

退火温度对5A06挤压型材组织及性能的影响

通过对型材微观组织的观察及维氏硬度、晶间腐蚀和剥落腐蚀等的测试,研究了退火温度对5A06挤压型材组织及性能的影响。结果表明,随着退火温度的升高,晶粒发生了回复、再结晶和晶粒长大三个阶段。当退火温度达到175 ℃时,型材发生低温回复,硬度变化不大,耐蚀性较差;在225～325 ℃退火,型材发生完全再结晶,硬度变化较明显,耐蚀性得到改善;当退火温度高于325 ℃时,晶粒长大,硬度略降低,耐蚀性变差。结合5A06挤压型材组织及性能研究可知,确定退火温度为225～325 ℃。     

三维五向管状编织物的几何建模及纤维体积百分含量预测

基于编织物的对称性,建立了简化单胞几何模型来描述三维五向圆型编织物的几何特性。通过对三维五向圆型编织物的结构单胞形态及单胞的分布方式进行研究,推导了单胞几何结构与编织工艺参数之间的理论公式,详细分析了各个参数之间的变化关系。并通过预测单胞的纤维体积百分含量,研究了编织工艺对该编织复合材料纱线体积百分含量的影响。