平面汞膜电极恒电位阳极溶出极限电流方程式的推导和实验验证

本文推导出膜电极恒电位阳极溶出极限电流方程式,以平面厚汞膜电极对该式进行了实验验证。实验结果与理论式基本相符。     

新型全固态铁离子敏感电极研究

采用稀土电极材料六硼化镧制备了一种新的全固态铁离子敏感电极。研究了该敏感电极在常见介质中对Ｆｅ３＋的响应行为。结果表明，该铁离子敏感电极在１．５ｍｏｌ／ＬＨ３ＰＯ４介质中的线性响应范围、检测下限和响应斜率分别为１．０×１０－５～１．０×１０－１ｍｏｌ／ＬＦｅ３＋，６．０×１０－６ｍｏｌ／ＬＦｅ３＋和６０ｍＶ／ｐＣ，且具有较好的选择性。     

Studies of Several Systems with Air Electrode Electro-Synthesizing H2O2 on the Spot for Degrading Aniline in Aqueous

A gas diffusion electrode (air electrode) with a high current efficiency of electro-synthesizing H2O2 using O2 in air was prepared. The several systems with air electrode as cathode of electro-synthesizing H2O2 on the reaction spot for degrading aniline in aqueous--electro-Fenton system, photo-excitation electro-H2O2 system and photo-electro-Fenton system, were developed. The rates of decomposition of H2O2 and mineralization of aniline were experimentally measured respectively under different conditions, and the results indicated there has an excellent parallel relation between decomposition rate of H2O2 and mineralization rate of aniline. Especially, photo-electro-Fenton system, where H2O2 is decomposed the fastest, is the best system of oxidizing and degrading organic toxicants. Compared photo-electro-Fenton system with photo-Fenton system, important role is revealed in the interface of air electrode. In this paper, the mineralization mechanism of aniline in the photo-electro-Fenton system was also discussed.     

利用单元状态的改变模拟采场破坏规律

采用能较好反映混凝土等脆性材料破坏特征的五参数Wilianm-Warnke强度准则破坏模型，利用有限单元法单元“处死”的功能模拟回采过程和相似材料模拟试验研究，初步总结出缓倾斜厚煤层悬移支架放顶煤顶板活动及矿压显现规律，为缓倾斜厚煤层悬移支架放顶煤制定较为合理的方案、安全技术措施等提供重要的依据和指导作用。     

低剂量汞元素的毒性作用机理

低剂量汞毒性作用机理研究是当前毒理学研究的热点之一．着眼于低剂量汞元素毒性作用的特点，就其对蛋白质、脂类、遗传物质等的影响多个方面，对汞毒性作用机理的近期研究进展进行综述，并对该领域深入研究的方向提出了几点看法．     

L-半胱胺酸自组膜修饰电极的制备及其电化学行为的研究

将L-半胱胺酸修饰到金电极表面,通过循环伏安法、阻抗法进行表征。在pH低时,高频部分的半圆的半径较pH高时的要大,其原因可能跟探针离子与L-半胱胺酸的静电作用有关。     

负极添加剂CoO对储氢合金电极性能的影响

负极添加剂CoO在储氢金合金颗粒表面形成的Co膜有助于抑制合金粉的表面氧化和成分的偏析，进而减少电解液的损耗，因而有助于储氢合金负极和电池性能的提高。本文从电池内阻和容量衰减角度考察了CoO对电池循环寿命的影响。并以溶解——沉积理论为基础，利用循环伏安研究分析了CoO对储氢合金的保护机理。