Anion-exchangeable inorganic-organic hybrid materials synthesized without using templates

Inorganic-organic hybrid materials have been obtained at room temperature in aqueous solution without using the templates of surfactants. The materials are carefully characterized by anion-exchange measurement, elements analysis, X-ray diffraction, and infrared spectroscopy. Notably, the anion-exchange capacity of the samples (3.9mmol.g^-1) is even higher than anion-exchangeable resins. Interestingly, both small and large anions could be easily exchanged into the samples due to the plasticity of the samples, along with the phase transition.     

Permeation study of the potassium channel from streptomyces Lividans

A three-state hopping model is established according to experiments to study permeation of an open-state potassium channel from Streptomyces Lividans (KcsA potassium channel). The master equations are used to characterize the dynamics of the system. In this model, ion conduction involves transitions of three states, with one three-ion state and two two-ion states in the selectivity filter respectively. In equilibrium, the well-known Nernst equation is deduced. It is further shown that the current follows Michaelis-Menten kinetics in steady state. According to the parameters provided by Nelson, the current-voltage relationship is proved to be ohmic and the current-concentration relationship is also obtained reasonably. Additional validation of the model in the characteristic time to reach the steady state for the potassium channel is also discussed. This model lays a possible physical basis for the permeation of ion channel, and opens an avenue for further research.     

Effective stress law for anisotropic double porous media

An effective stress law is derived analytically to describe the effect of pore (fracture pore and matrix-block pore) fluid pressure on the linearly elastic response of anisotropic saturated dual-porous rocks, which exhibit anisotropy. For general anisotropy the difference between the effective stress and the applied stress is not hydrostatic simply multiplied by Biot coefficient. The effective stress law involves four constants for transversely isotropic response;these constants can be expressed in terms of the moduli of the single porous material, double porous material and of the solid material. These expressions are simplified considerably when the anisotropy is structural rather than intrinsic, i.e. in the case of an isotropic solid material with an anisotropic pore structure. In this case the effective stress law involves grain bulk modulus, four moduli and two compliances of the porous material for transverse isotropy. The law reduces, in the case of isotropic response, to that suggested by Li Shuiquan (2001). And reduction to the single-porosity (derived analytically by Carroll (1979)) is presented to demonstrate the conceptual consistency of the proposed law.     

Improved production of spiramycin by mutant Streptomyces ambofaciens

Strain improvement and medium optimization to increase the productivity of spiramycin were carried out. Of oil tolerant mutant strains screened, one mutant, Streptomyces ambofaciens XC 2-37, produced 9% more spiramycin than the parent strain S. ambofaciens XC 1-29. The effects of soybean oil and propyl alcohol on spiramycin production with S.ambofaciens XC 2-37 were studied. The potency orS. ambofaciens XC 2-37 was improved by 61.8% with addition of 2% soybean oil in the fermentation medium and 0.4% propyl alcohol at 24 hours after incubation. The suitable time for feeding propyl alcohol is at 24 hours after incubation in flask fermentation and at 20 hours after incubation in fermentor fermentation The new process with S. ambofaciens XC 2-37 was scaled up for industrial scale production of spiramycin in a 60 m^3 fermentor in Xinchang Pharmaceutical Factory, Zhejiang Medicine Company, Ltd., China, and the potency and productivity of fermentation were improved by 42.9%.     

高应力软岩巷道壁后充填支护研究

高应力软岩巷道属非线性大变形问题,巷道支护必须满足其变形要求。总结了白皎煤矿高应力软岩砌碹巷道变形破坏特征,分析了砌碹巷道破坏机理,并对碹体壁后充填粉煤灰基材料改善"支护-围岩"关系的作用机理进行了分析,最后得到了现场验证。     

A novel long-chain acyl-derivative of epigallocatechin-3-O-gallate prepared and purified from green tea polyphenols

Lipophilic tea polyphenols (LTP) were prepared by catalytic esterifieation of green tea polyphenols (GRIP) with hexadeeanoyl chloride. A novel long-chain aeyl-derivative of epigalloeateehin-3-o-gallate(EGCG) was first isolated from purification of LTP by high-speed eountereurrent ehromatography (HSCCC)using a solvent system composed of n-hexane-ethyl acetate-methanol-water ( 1 : 1 : 1 : 1, v/v) . The moleeularstructure of the acyl-derivative, Epigallocatechin-3-O-gallate-4‘-O-hexadeeanate , was elucidated by meansof elemental analysis, IR, 1H-NMR and MS spectra.     

一种小额支付协议的研究与设计

分析了PayWord这种小额支付协议,针对PayWord的一些关于交易原子性的局限性,提出了一种新的支付协议--CertWord,此协议沿用PayWord协议的Payword链来表示货币,充分利用交易证书对交易信息进行签名,并记录交易步骤的状态,从流程上保证交易的原子性。     

混凝土多轴性能试验装置

在5000kN压力机的基础上研制了一套混凝土多轴性能试验装置。该装置可进行平面应力平面应变以及一般三轴荷载等不同应力组合的混凝土强度和变形试验,并可适应多种试件形式。     

Homocysteine increases the synthesis of adrenomedullin in vascular fibroblasts of rats

Homocysteine (Hcy), a highly reactive sulfur- containing amino acid, is an intermediate product of methionine metabolism. Elevation of plasma Hcy has been widely studied as an independent risk factor for many cardiovascular diseases such as atherosclerosis, thrombosis, etc.[1]. Inherited hyperhomocysteinemia cases usually suffer from occlusion or thrombosis in arteries and large veins before the age of 20. Hyperhomocysteinemia significantly reduces the survival rate[2] and dilatation functi…     

库车盆地-天山边界的晚第三纪断层活动性质与应力状态

对库车盆地-天山边界的野外考察表明, 以羊布拉克为界, 西部见中生界不整合在古生界岩层上, 三叠系底部不整合面上下发育了向盆地方向倾斜的正断层; 羊布拉克以东, 见第三系与古生界被断层隔开. 对盆山边界上发育的带擦痕断层的构造要素进行了观测和研究, 获得了25组360条有效数据, 古应力状态反演计算结果表明, 晚第三纪时盆山边界的总体应力状态以伸展为主, 局部叠加了走滑断层的影响. 盆山边界处的变形特征可归因于天山垂向隆升的结果.