卟啉修饰电极的制备及金属离子的电位溶出行为

目的 :将修饰电极应用于电位溶出分析 .方法 :采用化学吸附法制备出meso -四 (对 -乙基苯基 )卟啉和meso -四 (对 -甲氧基苯基 )卟啉修饰玻碳电极 .研究Zn(Ⅱ ) ,Cu(Ⅱ ) ,Cd(Ⅱ )和Pb(Ⅱ )金属离子在该电极上的电位溶出行为 ,并与预镀汞膜玻碳电极、玻碳电极的电位溶出行为进行了比较 .结果 :溶出时间 (τ)与金属离子浓度均有良好的线性关系 ,最适宜分析的浓度范围是Zn(Ⅱ ) :1× 10 - 7～ 5× 10 - 5mol/L ;Cd(Ⅱ )和Pb(Ⅱ ) :6× 10 - 7～ 5× 10 - 5mol/L ;Cu(Ⅱ ) :5× 10 - 8～2× 10 - 5mol/L .微分电位溶出分析时灵敏度提高一个数量级 ,相对标准偏差为 0 .90 %～ 2 .3% (n=15) .结论 :使用卟啉修饰电极进行电位溶出分析可获得好的重现性和满意的灵敏度     

无抽搐电休克治疗后患者发热的分析

目的就无抽搐电休克治疗（MECT）后的发热现象进行初步分析，以供临床参考。方法回顾性调查2007年在本院接受MECT的全部患者的病历资料，总计124例，以是否在MECT后出现发热进行分组，最后将数据进行进行卡方（x^2）检验或t检验。结果发热组和无发热组在年龄、性别、病程、MECT次数等因素的差异无统计学意义；MECT后有56例（占总数的45．16％）病人出现发热现象，其中有42例（75％）为低热，43例（76．8％）发热为1-2次，48例（85．7％）为接受MECT1-2次后出现发热。结论发热是MECT后常见的副作用，一般不会继发更严重的后果，但在临床上应重视。     

任意形状坯料反挤流变成形内圆筒上限单元技术的改善分析

提出了对任意形状坯料的反挤流变成形内圆筒的运动许可速度场改善．在以前各种著作中出现的速度场不满足在模具和材料接触面的法线速度必须为零的条件，而且忽略了冲头下面的材料旋转．同时对前者进行了修正，对后者以一种新的速度场进行了改进．得出的挤压载荷的理论计算值比文献中出现的低，且更接受实验结果，同时平均挤压高度与实际情况相吻合．     

Design of Flexible Electronic Shogging System for High-Speed Warp-Knitting Machine

A flexible electronic shogging system was presented based on rotary type servo motor,which aimed to improve the dynamic response of the shogging drive and decrease the impact of the guide bar during the higher speed running of warp-knitting machine.In this system,the speed control mode,faster response servo motor,no-flat modified trapezoid motion law,and its electronic cam were chosen;the realization standard and method were also introduced in details.The speed response curves of loaded motor indicated that the system could satisfy the technology requirements of high-speed warpknitting machine which run at the speed of 1000 r/min in the experiments,and the vibration curves showed that the guide bar had weaker mechanical impact and higher dynamic response characteristics.The results indicated that the flexible electronic shogging system designed following the previous step was successful,and the design principle of the electronic shogging was testified validly.     

基于SBS的沥青混凝土路面改造技术实现方案

SBS为苯乙烯-丁二烯-苯乙烯嵌段共聚物,兼具橡胶和热塑性塑料特性,将此材料改性沥青混凝土并用于枞阳县金山路综合改造工程。为确保工程质量,从热拌改性沥青混合料、基层处理、面层铺压等三个方面详细介绍了路面改造的技术实现方案。     

Electrochemical behavior of adriamycin at a cobalt ion implantation modified electrode

With Co/GCE in 0.005 mol Tris/L/0.05 mol/L NaCl solution (pH 7.1), a sensitive reductive peak of adriamgcin (ADM) was obtained by the linear scan voltammetry. The peak potential is ?0.62 V (vs. SCE). The peak current is proportional to the concentration of ADM. The electrochemical behavior of the system was studied by the linear-sweep and cyclic voltammetry. The experiments showed that the reduction at Co/GCE is a quasi-reversible process with adsorption. According to Laviron’s theory, the electrode reaction rate constant k₀ and the electron transfer coefficient a are determined to be 2.15 s^-1 and 0.62, respectively. The composition of the surface, valence state of elements and depth distribution of elements on the surfaces of Co/GCE were determined by the X-ray photoelectron spectroscopy and Auger electron spectroscopy. The experiments showed that Co was surely implanted into the surface of GCE. The implanted Co element in the form of Co-C catalyzed the reduction of ADM.     

双圆弧齿轮齿形参数的研究

本文用三维有限单元法对分阶式双圆弧齿轮齿形的三个主要参数——法向压力角α_n、齿厚比K和齿顶高系数h_a~*,按正交试验表L_(16)(4~5)进行计算,得到了轮齿的应力与α_n,K和h_a~*的变化关系。增大压力角会使齿根应力下降,减小齿厚比会使齿腰处的应力下降,增加齿高则齿腰和齿根处的应力均下降。然后从强度、制造和使用等方面考虑,提出一种改进齿形。为了验证有限元模型的准确性和改进齿形的正确性,又做了电测实验。通过对通用齿形和改进齿形的对比实验和计算,证实了有限元方法是较准确的,改进齿形无论在齿腰还是在齿根的应力都低于通用齿形。     

等距基点线性最小二乘法的改进

本文对等距基点线性最小二乘法作了修改,使得问题简化,便于实际计算与应用.     

卡尔曼滤波伏安法同时测量显影废水中米吐尔和对苯二酚的研究

用自制蒙脱石—石墨—聚氯乙烯复合电极做工作电极。溶液的pH=5．0时。米吐尔的氧化峰电位为310mV。浓度在4．0～32．0μg．mL^-1范围时。峰电流与浓度有良好的线性关系(J=0．0057 0．6398c，γ=0．999)；对苯二酚的氧化峰的峰电位为320mV。浓度在4．0～32．0μg．mL^-1范围时。峰电流与浓度有良好的线性关系(I=-0．0164 0．9747c，γ=0．999)．用卡尔曼滤波伏安法对显影废水中米吐尔和对苯二酚进行了同时测定，米吐尔的平均回收率为99．47％，对苯二酚的平均回收率为100．06％。     

改性聚苯醚层压式高频覆铜板的研制

为了实现高频信号传输高速化,进行了低介电常数层压式高频覆铜板基材的研制.通过选择低介电常数的树脂材料和低ε的纤维作为增强材料,优化了基材的配方和成型工艺,解决了高性能低介电高频高速层压式覆铜板制备的技术关键,采用这一工艺研制的改性聚苯醚层压式高频覆铜板介电性能较理想.