Assembling Zwitterionic, Water-Soluble Porphyrin and Its Biological Studies

A kind of zwitterionic water-soluble porphyrin 5-(N-trimethyl-4-aminiumphenyl)-10, 15, 20-tri (4-sulfonatephenyl) porphyrin trisammonium salt, has been synthesized. Its biological studies, interactions with DNA and bacteria cells, were investigated. The damage to the cell wall of bacteria E. coli were observed firstly by AFM (Atomic Force Microscope).     

Dispatch Liquidity Theory in a Deregulated Environment

Power system security and reliability are more complex issues in a deregulated environment.Various criteria have been considered for power system reliability. In the day-ahead market, a successful trade schedule should be able to accept various disturbances with sufficient flexibility to be adjusted during the re-dispatch process. This paper describes the dispatch liquidity theory and some liquidity indices. The liquidity indices evaluate the effective operating reserves with the network constraints taken into consideration. A model is presented to calculate the liquidity index. An extended trade scheduling model with minimum liquidity index constraints is presented that considers the distribution requirements of the operating reserves. The liquidity indices could also be used to coordinate the security and reliability between multistage markets and for contingency selection. The algorithms were tested with real power system data. The results show that the dispatch liquidity theory is reasonable and the algorithms are effective.     

Na(THF)2(μ2-η5-Cp)(η5,η5,η1-Cp3Yb)(THF)]n: The synthesis and X-ray structure of an anionic organolanthanidepolymer formed via self-assembly

Cp2Yb·2THF reacts with CpNa in 1：1 molar ratio in THF at 40℃ for 2 h, and the in situ generated anionic divalent complex NaYbCp3（THF）n reacts further with an excess of CpH at 40℃ for 48h, after work-up, affording the trivalent anionic ytterbium complex[Na（THF）2（μ2-η^5-Cp） （η^5, η^5,η^1-Cp3Yb）（THF）]n：（1） by oxidation reaction of Cp2Yb with CpH. Crystal structure determination reveals that complex 1 has one-dimension polymeric chains of distinct Na（THF）2（μ2-η^5-Cp） （η^5, η^5,η^1-Cp3Yb）（THF） units, which were formed by the coordination of the bridging Cp ligand with Cp3Yb＇THF and Na（THF）2 in η^5,η^5 mode via self-assembly.     

Effect of density of hydrogen-bonding donor on hydrogen-bonded multilayer buildup

The effect of density of hydrogen-bonding donor （HBD） on the formation of layer-by-layer assemblies of poly（4-vinylpyridine） and poly（4-vinylphenol） was investigated. For this purpose, a series of ethyl-substituted poly（4-vinylphenol） （EsPVPhf） with variable ethyl substitute percentage was synthesized by grafting the phenol moiety along the poly（4-vinylphenol） backbone with 1-bromoethane. UV-vis spectroscopy revealed a uniform deposition process of the hydrogen-bonded multilayer consisting of poly（4- vinylpyridine） （PVPy） and EsPVPhf with variable density of HBD. Notably, it was found that increasing the HBD density of EsPVPhf resulted in a marked decrease of both amount of polymers adsorbed and film thickness, which should be related to the EsPVPhf conformation change from coiled state to extended conformation in ethanol solution. Compared with the effect of charge density in polyelectrolyte multUayer, however, there does not exist a critical density of HBD in our case of hydrogen-bonded multilayer assembly. In addition, surface structures of PVPy/EsPVPhf multilayer films also can be tailored controllably by adjusting HBD density of EsPVPhf. As a result, a new method for tuning the structure of hydrogen-bonding-directed multilayer films was developed.     

Progress in non-viral gene delivery systems fabricated via supramolecular assembly

Gene delivery systems are one of key issues that limit the development of gene therapy. The novel non-viral gene delivery systems fabricated via supramolecular assembly have begun to show increasing promising and applications in gene therapy due to its suitable nanometric size,controllable structure and excellent biocompatibility. In this review, the fundamental and recent progress of non-viral gene supramolecular assembly is reviewed. Artificial viruses the future direction of non-viral gene delivery systems are also described.     

关于图运算的测地数

对于图G(或有向图D)内的任意两点u和v,u-v测地线是指在u和v之间(或从u到v)的最短路.I(u;v)表示位于u-v测地线上所有点的集合,对于SV(G)(或V(D)),I(S)表示所有I(u,v)的并,这里u,v∈S.G(或D)的测地数g(G)(或g(D))是使I(S)=V(G)(或I(S)=V(D))的点集S的最小基数.G的下测地数g-(G)=min狖g(D):D是G的定向图狚,G的上测地数g+(G)=max狖g(D):D是G的定向图狚.对于两个图G和H,u∈V(G)和v∈V(H),在u和v之间加一条边,然后再收缩这条边uv所得的图,记为GuHv.本文主要研究图GuHv的测地数和上(下)测地数.     

东昌湖生态保护区生态旅游资源模糊评价

目的以东昌湖生态保护区为实例,探讨保护区生态旅游发展模式。方法依据实地调查资料,运用模糊数学的理论与多级模糊综合评价方法。结果通过对保护生态旅游资源进行多级模糊综合评价,得出东昌湖风景名胜区在4景区中的综合分值最高,为0．72;其次为凤凰苑农业科技园,其综合分值为0．69;最后为姜堤乐园及梦幻乐园,分值均为0．56。结论根据实际评价结果, 认为单体发展模式与整体发展模式相结合是促进保护区生态旅游持续发展的关键。     

基于软件协作的多级液压缸起竖系统建模与仿真研究

提出了基于软件协作技术的多级液压缸起竖系统的建模与仿真方法。运用ADAMS软件建立了考虑碰撞的起竖系统多刚体动力学可视化虚拟样机模型,探讨了基于Simulink的多级液压缸仿真模型的建立方法,给出了起竖液压系统的AMESim仿真模型,分析了机械、液压系统的参数关联关系,讨论了基于接口的多领域软件协作仿真方法,实现了多级液压缸起竖的全过程仿真,为多级液压缸系统的仿真研究提供一个新的可靠的技术途径。     

A New Digital Multilevel Proxy Signature Scheme Based on Elliptic Curve Cryptography

Based on the analysis of elliptic curve digital signature algorithm（ECDSA）,aiming at multilevel proxy signature in which the original signer delegates the digital signature authority to several proxies and its security demands, a new multilevel proxy signature scheme based on elliptic curve discrete logarithm problem （ECDLP） is presented and its security are proved.     

非阻塞模式LCD多级菜单的设计及其数据结构

提出一种非阻塞模式LCD多级菜单的设计,分析了菜单的树形结构,给出了菜单的状态转换模型及其菜单的核心数据结构.并分析菜单实现算法的较小空间复杂度和给出了其数据结构的C51的实现.