CO adsorption on electrode of Pt nanoparticles investigated by cyclic voltammetry and <Emphasis Type="Italic">in situ</Emphasis> FTIR spectroscopy

Pt nanoparticles were prepared by the chemical reduction method.The average diameter of Pt nanoparticles was determined to be 2.5nm by TEM.The electrochemical propertis of Pt nanoparticles were studied by cyclic voltammetry,In comparison with massive Pt,the oxidation current peak of CO adsorbed on Pt nanoparticles in broader.Twin adsorbates of CO on Pt nanoparticles were determined by in situ FTIRS for the first time.It has revealed that the linear and twin-bonded CO can be converted into bridge-bonded CO with the variation of electrode potential.A series of special properties of Pt nanoparticles,such as enhanced IR absorption of CO adsorbates,were also observed.     

二值点阵图像的放大与缩小方法研究

着重研究了二值点阵图像的放大、缩小方法，针对二值点阵灰度图和工程图现有的缩小和放大算法及存在的问题，提出了基于区域特征的图像变换思想，以图块为单位进行图像的放大、缩小．据此，提出了对二值灰度图和工程图进行放大、缩小的改进算法并进行分析。     

应用马尔可夫理论对市场进行预测与决策

阐述了马尔可夫决策理论中的最基本分析方法——系统状态转移概率矩阵决策法 ,指出这种决策分析法能有效地对市场作出预测与决策 ,特别对于某些预测问题 ,应用此法的效果比用其他一些经典预测法所得的结果更优 .对美国柯达、日本富士、中国乐凯三家公司的产品占有率进行了预测与决策     

关于建立区域施工平面控制网几个问题的探讨

文中就施工平面控制网的等级确定 ,以及如何选择合适的高程抵偿面使投影变形值最小 ,进行细致的分析与探讨 ,总结出各类工程建筑限差与拟建网的精度配比关系 ,推证出最佳抵偿高程面之高程 ,对于工程建网具有一定的指导意义。     

Late Cretaceous-Cenozoic exhumation history of Tiantangzhai region of Dabieshan Orogen： Constraints from （U-Th）／He and fission track analysis

Integrated fission track and (U-Th)/He analysis is carried out on 6 apatite and 6 zircon samples from a near vertical section in The Tiantangzhai region at the core of the present Dabieshan orogen. The result shows that the region experienced cooling/exhumation during the Late Cretaceousand Early Tertiary period. Age-elevation relationships for different dating systems and different minerals suggest a pulse of rapid exhumation at ～110 Ma before present, preserved in the structurally highest samples. At lower elevations, ages begin to decrease with decreasing elevation, suggesting lower exhumation rates since 90 Ma. Two periods of different exhumation rates are identified since 90 Ma. The average apparent exhumation rate for the period of 43.4—22.5 is 0.062 km/Ma, whereas that for the period of 76.4—47.4 Ma is 0.039 km/Ma.     

Receptive field plasticity of neurons in rat auditory cortex

Using conventional electrophysiological technique, we investigated the plasticity of the frequency receptive fields (RF) of auditory cortex (AC) neurons in rats. In the AC, when the frequency difference between conditioning stimulus frequency (CSF) and the best frequency (BF) was in the range of 1--4 kHz, the frequency RF of AC neurons shifted. The smaller the differences between CSF and BF, the higher the probability of the RF shift and the greater the degree of the RF shift. To some extent, the plasticity of RF was dependent on the duration of the session of conditioning stimulus (CS). When the frequency difference between CSF and BF was bigger, the duration of the CS session needed to induce the plasticity was longer. The recovery time course of the frequency RF showed opposite changes after CS cessation.The RF shift could be induced by the frequency that was either higher or lower than the control BF, demonstrating no clear directional preference. The frequency RF of some neurons showed bidirectional shift, and the RF of other neurons showed single directional shift. The results suggest that the frequency RF plasticity of AC neurons could be considered asan ideal model for studying plasticity mechanism. The present study also provides important evidence for further study of learning and memory in auditory system.     

A new puffing pattern induced by temperature shock and DNP in drosophila

Riassunto Si è notato che shocks di temperatura possono indurre una variazione di «puffing pattern» in ghiandole salivari di Drosophila. Tali «puffing» sono perfettamente reversibili e rappresentano zone di intensa sintesi di RNA. Si è notato che DNP e Na salicilato portano a simili variazioni di «puffing pattern».     

用菲和苯甲醛合成沥青树脂的反应机理

用苯甲醛 (BA)作为交联剂 ,菲 (Ph)作为纯芳烃原料 ,在对甲基苯磺酸 (PTS)的催化作用下 ,合成出B阶沥青树脂。根据产物的核磁和红外分析结果 ,推断出该反应属质子催化下阳离子型缩聚反应。在质子催化下 ,苯甲醛的醛基打开而产生碳正离子 ,作为双官能团的 3种取代方式连接菲的两个芳环 ,生成具有三芳基甲烷结构的长链沥青树脂。     

Preparation and characterization of doubly substituted microwave absorbing material by sol-gel technique for super high frequency applications

Rare earth Dy~(3+)and divalent Mn~(2+)elements substituting W-type hexagonal ferrites Ba_(1-x)Dy_xZn_2Fe_(16-y)Mn_yO_(27)(x=0,0.02,0.06,0.1 and y=0,0.1,0.3,0.5)were prepared by sol-gel method.The thermo-gravimetric analysis(TGA)and differential scanning calorimetry(DSC)was carried out to find the temperature at which single phase can be obtained.XRD patterns indicate the presence of the single phase for all the synthesized samples with the absence of any extra peak due to unreacted material and secondary phases.The occurrence of absorption bands at low wave numbers(563 and 446 cm~(-1)),can be assigned to the stretching vibration of metal and oxygen ions in FTIR spectra,which also confirms the single hexagonal phase for prepared material.The grains are of platelet like structure,which enhances the microwave absorption properties of hexagonal ferrites.The synthesized material exhibits the minimum reflection loss of-20.9 dB at 11.8 GHz frequency,which reflects the applications of this material in super high frequency devices.The microwave conductivity of the material increases with frequency.     

工业烟气脱硫同时制取硫化氢的初步研究

提出一种无废烟气脱硫新方法。用硫化钠溶液洗脱工业烟气中二氧化硫，同时生成硫化氢。后者用Ｃｌａｕｓ反应可制取元素硫。反应过程为三阶段模式。第一阶段发生二氧化硫溶解和硫离子向硫氢根离子转变；第二阶段主要发生硫氢根离子向硫化氢转变同时吸收二氧化硫；第三阶段，溶液逐渐失去脱除ＳＯ２的能力。提高硫化钠初始浓度和反应温度或降低进气中二氧化硫含量，于提高Ｈ２Ｓ转化率有利。进气中二氧化硫分压增大，各阶段周期缩短。